全文获取类型
收费全文 | 130篇 |
免费 | 1篇 |
国内免费 | 2篇 |
专业分类
化学 | 77篇 |
晶体学 | 1篇 |
数学 | 25篇 |
物理学 | 30篇 |
出版年
2023年 | 1篇 |
2021年 | 1篇 |
2020年 | 5篇 |
2019年 | 3篇 |
2017年 | 2篇 |
2015年 | 1篇 |
2014年 | 2篇 |
2013年 | 7篇 |
2012年 | 6篇 |
2011年 | 10篇 |
2010年 | 5篇 |
2009年 | 4篇 |
2008年 | 7篇 |
2007年 | 9篇 |
2006年 | 7篇 |
2005年 | 8篇 |
2004年 | 9篇 |
2003年 | 4篇 |
2002年 | 3篇 |
2001年 | 2篇 |
1999年 | 3篇 |
1998年 | 7篇 |
1997年 | 3篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1991年 | 4篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有133条查询结果,搜索用时 62 毫秒
1.
We consider the scalar field φ
t
with a reversible stochastic dynamics which is defined by the standard Dirichlet form relative to the Gibbs measure with
formal energy . The potential V is even and strictly convex. We prove that under a suitable large scale limit the φ
t
-field becomes deterministic such that locally its normal velocity is proportional to its mean curvature, except for some
anisotropy effects. As an essential input we prove that for every tilt there is a unique shift invariant, ergodic Gibbs measure
for the -field.
Received: 1 February 1996 / Accepted: 2 July 1996 相似文献
2.
Takeshi Shimomura Tatsuya Funaki Kohzo Ito Byoung-Ki Choi Tomihiro Hashizume 《Journal of inclusion phenomena and macrocyclic chemistry》2002,44(1-4):275-278
We have investigated the inclusion properties of molecular nanotubes composed ofcrosslinked -cyclodextrin. Induced circular dichroism was used to probe theformation and dissociation of complexes between the nanotubes and azobenzenemodified linear polymers. The polymer was poly(ethylene glycol) (PEG), either withor without a hydrophobic alkyl chain.It was found that the inclusion complex betweenthe nanotubes and polymers formed at room temperature, and that the polymers dissociated from the nanotubes with increasing temperature. Further, the polymer with hydrophobic alkyl chain was bound inside the nanotube more strongly and dissociated more abruptly with increasing temperature than its hydrophilic counterpart as expected theoretically. 相似文献
3.
Etsu Yamada Sinichi Funoki Yuko Abe Shigekazu Umemura Daisuke Yamaguchi Yasuro Fuse 《Analytical sciences》2005,21(2):89-94
Ambient particulate matter and gas in Kyoto were investigated by gravimetric analysis, X-ray fluorescence spectrometry, and ion chromatography in order to clarify their behavior and origin. The size distribution and characteristics of the chemical components in ambient particulates collected on PTFE membrane filters using an Andersen air sampler were examined from August 2001 to April 2004. A four-stage filter pack method was used to sample the atmosphere for the determination of gas (SO2, HNO3, HCl, NH3) and particulate matter (SO42, NO3, Cl-, Na+, K+, Ca2+, Mg2+, NH4+) concentrations from October 2002 to April 2004. The concentration of SPM mass was in the range of 6.7 - 80.2 microg/m3. The size distributions of SPM mass were bimodal, peaking at around 0.65 - 1.1 and 3.3 - 4.7 microm, and 40 - 85% of SPM mass was fine particles (< 2.1 microm). Na, Mg, Al, Si, Ca, Cl, and Fe were mainly present in coarse particles (2.1 to 11.0 microm), while S was present in fine particles. The concentrations of Al, Si, Ca, Mg, and Fe in fine particles increased from March to April in 2002, and those in coarse particulates increased in November 2002 and from March to April in 2004. This may be the effect of the continental yellow sand "Kosa." The differences in the size distributions of Al, Si, Ca, Mg, and Fe in particles may depend on differences in their place of occurrence and course of transport from China to Japan. The concentration of HCl gas was higher than that of particulate chloride ion in summer. Nitric acid gas existed at higher concentrations in summer, but fine particulate nitrate ion was observed in winter. The gaseous-to-fine aerosol nitrate fraction became higher at warmer temperatures. Coarse sulfate was below 10%, and SO2 gas and fine particulate sulfate were above 90%. 相似文献
4.
Yoshimasa Hama Kazuya Hosono Yasuro Furui Kenichi Shinohara 《Journal of polymer science. Part A, Polymer chemistry》1971,9(5):1411-1419
ESR studies of ultraviolet-irradiated polyethylene (PE) were carried out. Irradiation effects different from those of high-energy radiation are observed. Ultraviolet radiation is absorbed selectively, and especially in carbonyl groups in PE produced by oxidation. Radicals produced were identified as \documentclass{article}\pagestyle{empty}\begin{document}$ \hbox{---} {\rm CH}_2 \hbox{---} {\dot {\rm C}} {\rm H} \hbox{---}{\rm CHO}$\end{document} and \documentclass{article}\pagestyle{empty}\begin{document}$ \hbox{---} {\rm CH}_2 \hbox{---} {\dot {\rm C}} {\rm H} \hbox{---}{\rm CH}_2 \hbox{---}$\end{document}. Some radicals giving a quintet signal stable at room temperature were also observed but remained unidentified. The radical \documentclass{article}\pagestyle{empty}\begin{document}$ \hbox{---} {\rm CH}_2 \hbox{---} {\dot {\rm C}} {\rm H} \hbox{---}{\rm CHO}$\end{document} undergoes a mutual conversion with the acyl radical: 相似文献
5.
Understanding the quantitative analysis of the transition adsorption structures of molecules on single‐walled carbon nanotubes (SWNTs) is of importance from the point of view of both fundamental science and applications of nanotubes. Absorption spectroscopy reveals that two different equilibrium states are existent for the exchange reaction of sodium cholate (SC) and oligo‐DNA (single‐stranded 20‐mer cytosine) on SWNTs. This is derived from the transitions of the adsorption structures of different chirality‐types of SWNTs and SC/DNA at certain SC concentrations below the critical micelle concentration of SC. 相似文献
6.
M. Yoneda Y. Yamato M. Tsuyumoto Y. Funaki K. Hatanaka J. Hobley H. Fukumura 《Applied Physics A: Materials Science & Processing》2004,79(4-6):845-848
We have developed laser-ignitable gas generating films to control a liquid stream for use in micro processing that can be ignited with both continous wave (CW) and pulsed lasers. Films of 100 m thick polyethylene terephthalate (PET) were coated with mixtures of nitrocellulose, trimethylolethanetrinitrate, and carbon black. A light beam from a Nd:YAG laser diode, or an Ar+ laser was focused onto the nitrocellulose layer through the PET substrate to ignite the layer. In the case of CW irradiation the delay time between the onset of irradiation and the ignition of the films was established by measuring the transmission of the laser light passing through the films. Gas generation dynamics were studied as a function of film thickness and irradiation conditions. In the case of pulsed laser irradiation, the dynamics were followed by imaging using a conventional double pulse pump-probe technique, with which it was possible to observe material ejection and the transient disturbance of a micro liquid stream in the path of emitted debris.PACS 79.20.Ds; 41.75.Jv; 61.80.Ba 相似文献
7.
8.
In this paper, we study the Ruelle zeta function and the Selberg zeta functions attached to the fundamental representations
for real hyperbolic manifolds with cusps. In particular, we show that they have meromorphic extensions to
\mathbbC{\mathbb{C}} and satisfy functional equations. We also derive the order of the singularity of the Ruelle zeta function at the origin.
To prove these results, we completely analyze the weighted unipotent orbital integrals on the geometric side of the Selberg
trace formula when test functions are defined for the fundamental representations. 相似文献
9.
10.