全文获取类型
收费全文 | 787篇 |
免费 | 37篇 |
国内免费 | 5篇 |
专业分类
化学 | 427篇 |
晶体学 | 4篇 |
力学 | 22篇 |
数学 | 219篇 |
物理学 | 157篇 |
出版年
2023年 | 9篇 |
2022年 | 20篇 |
2021年 | 36篇 |
2020年 | 21篇 |
2019年 | 30篇 |
2018年 | 35篇 |
2017年 | 33篇 |
2016年 | 38篇 |
2015年 | 26篇 |
2014年 | 41篇 |
2013年 | 54篇 |
2012年 | 64篇 |
2011年 | 65篇 |
2010年 | 35篇 |
2009年 | 19篇 |
2008年 | 33篇 |
2007年 | 31篇 |
2006年 | 26篇 |
2005年 | 30篇 |
2004年 | 17篇 |
2003年 | 16篇 |
2002年 | 17篇 |
2001年 | 7篇 |
2000年 | 5篇 |
1999年 | 2篇 |
1998年 | 6篇 |
1997年 | 6篇 |
1996年 | 6篇 |
1995年 | 10篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1992年 | 6篇 |
1991年 | 7篇 |
1989年 | 6篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 2篇 |
排序方式: 共有829条查询结果,搜索用时 187 毫秒
1.
Giang Truong Nguyen Prof. Dr. Liviu Ungur 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(30):e202200227
Employing radical bridges between anisotropic metal ions has been a viable route to achieve high-performance single-molecule magnets (SMMs). While the bridges have been mainly considered for their ability to promote exchange interactions, the crystal-field effect arising from them has not been taken into account explicitly. This lack of consideration may distort the understanding and limit the development of the entire family. To shed light on this aspect, herein we report a theoretical investigation of a series of N -radical-bridged diterbium complexes. It is found that while promoting strong exchange coupling between the terbium ions, the N -radical induces a crystal field that interferes destructively with that of the outer ligands, and thus reduces the overall SMM behavior. Based on the theoretical results, we conclude that the SMM behavior in this series could be further maximized if the crystal field of the outer ligands is designed to be collinear with that of the radical bridge. This conclusion can be generalized to all exchange-coupled SMMs. 相似文献
2.
3.
Applying tight-binding approximation and spin pairing of like charge carriers in a pair of excitons created in a lattice, the possibility of forming a bound exciton-exciton state is studied. It is found that, provided there exists strong exciton-lattice interaction, such a bound state may be formed and its energy may lie within the valence band deforming the material into a crystalline solid with no energy gap. Lowering of the energy is calculated in naphthalene and anthracene crystals where some experimental results are known. The excess energy released after the formation of such bound state can be adequate, depending on the material, to desorb neutral atoms or eject of electrons from surfaces. 相似文献
4.
5.
I. M. Lavit Nguyen Viet Trung 《Journal of Applied Mechanics and Technical Physics》2008,49(3):491-499
The thermoelastoplastic fracture mechanics problem of a thick-walled cylinder subjected to internal pressure and a nonuniform
temperature field is solved by the method of elastic solutions combined with the finite-element method. The correctness of
the solution is provided by using the Barenblatt crack model, in which the stress and strain fields are regular. The elastoplastic
problem of a cracked cylinder subjected to internal pressure and a nonuniform temperature field are solved. The calculation
results are compared with available data.
__________
Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 49, No. 3, pp. 173–183, May–June, 2008. 相似文献
6.
7.
S. Franchoo F. Ibrahim F. Le Blanc M. Lebois A. Olivier C. Phan Viet B. Roussière R. Sifi D. Verney 《Hyperfine Interactions》2006,171(1-3):117-119
The availability of both a tandem deuteron beam and a linac electron beam, the latter converted into Bremsstrahlung, at the
new ALTO facility at IPN-Orsay offers a unique opportunity to compare the performance of a laser ion guide under different
regimes. The ALTO accelerator has delivered its first electron beam at the end of 2005 and a design for a gas-cell prototype
is being studied. 相似文献
8.
9.
Five new natural labdane-type diterpenoids (5-9), designated leoheteronins A-E, together with four known diterpenoids (1-4), two phytosterols as a mixture of beta-sitosterol and stigmasterol, and the flavone genkwanin (10) were isolated from the aerial parts of Leonurus heterophyllus SW. (Lamiaceae) collected in northern Vietnam. Compound 1 was isolated for the first time from a Leonurus species, and 10 is considered to be a chemotaxonomic marker of the Leonurus genus. Their structures were determined using spectroscopic analyses. 相似文献
10.