全文获取类型
收费全文 | 1329篇 |
免费 | 33篇 |
国内免费 | 5篇 |
专业分类
化学 | 898篇 |
晶体学 | 7篇 |
力学 | 21篇 |
数学 | 238篇 |
物理学 | 203篇 |
出版年
2023年 | 11篇 |
2022年 | 10篇 |
2021年 | 32篇 |
2020年 | 14篇 |
2019年 | 40篇 |
2018年 | 27篇 |
2017年 | 33篇 |
2016年 | 43篇 |
2015年 | 45篇 |
2014年 | 47篇 |
2013年 | 94篇 |
2012年 | 71篇 |
2011年 | 80篇 |
2010年 | 59篇 |
2009年 | 71篇 |
2008年 | 79篇 |
2007年 | 86篇 |
2006年 | 51篇 |
2005年 | 42篇 |
2004年 | 42篇 |
2003年 | 42篇 |
2002年 | 45篇 |
2001年 | 19篇 |
2000年 | 19篇 |
1999年 | 18篇 |
1998年 | 13篇 |
1997年 | 10篇 |
1996年 | 20篇 |
1995年 | 11篇 |
1994年 | 9篇 |
1993年 | 6篇 |
1992年 | 11篇 |
1991年 | 5篇 |
1990年 | 10篇 |
1989年 | 8篇 |
1988年 | 8篇 |
1987年 | 4篇 |
1986年 | 14篇 |
1985年 | 12篇 |
1984年 | 8篇 |
1983年 | 13篇 |
1982年 | 7篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1978年 | 7篇 |
1976年 | 6篇 |
1975年 | 5篇 |
1974年 | 6篇 |
1973年 | 13篇 |
1965年 | 4篇 |
排序方式: 共有1367条查询结果,搜索用时 672 毫秒
1.
2.
3.
4.
In this work we study nonnegativity and positivity of a discrete quadratic functional with separately varying endpoints. We introduce a notion of an interval coupled with 0, and hence, extend the notion of conjugate interval to 0 from the case of fixed to variable endpoint(s). We show that the nonnegativity of the discrete quadratic functional is equivalent to each of the following conditions: The nonexistence of intervals coupled with 0, the existence of a solution to Riccati matrix equation and its boundary conditions. Natural strengthening of each of these conditions yields a characterization of the positivity of the discrete quadratic functional. Since the quadratic functional under consideration could be a second variation of a discrete calculus of variations problem with varying endpoints, we apply our results to obtain necessary and sufficient optimality conditions for such problems. This paper generalizes our recent work in [R. Hilscher, V. Zeidan, Comput. Math. Appl., to appear], where the right endpoint is fixed. 相似文献
5.
Viviane Van Hoof Hugo Cluckers Vera Verhaeghe An Hennebel Marleen Truyens Edith Van Loock Pierre Rombouts Dirk Maes Jan Van Elven Katrien Lesage Mark Flothmann Lieve Nijs Filip Colpaert Werner Vercammen Dominique Bolain 《Accreditation and quality assurance》2004,10(1-2):55-59
In response to a change of the Belgian National Directives whereby hospital laboratories became responsible for all point-of-care testing (POCT) performed within hospital walls a standardized and automated POC glucose-testing system was implemented in our hospital. The system consists of 50 AccuCheck Inform instruments (Roche Diagnostics, Vilvoorde, Belgium), 50 docking stations, a DataCare Server, and connections to the medical laboratory information system (MOLIS, Sysmex, Barchon, Belgium) and to the hospital information system. Implementation involved many parties and extensive preparation and communication. Key issues were bar-coded patient and user identification, training, and responsibilities. One year after the hospital wide implementation of this system the quality of POC glucose testing has significantly increased, thereby improving patient safety. This study describes a stepwise change over involving the medical laboratory and with a focus on hands-on quality.Presented at the ninth conference on Quality in the Spotlight, 18–19 March 2004, Antwerp, Belgium. 相似文献
6.
V. A. Burov I. M. Grishina O. I. Lapshenkina S. A. Morozov O. D. Rumyantseva E. G. Sukhov 《Acoustical Physics》2003,49(6):627-637
In the ultrasonic diagnostics of small-size neoplasms of biological tissues at the earliest stage of their development, an efficient way to eliminate the distorting influence of high-contrast or large inhomogeneities of the biological medium is to apply the iterative technique. A simple approach is proposed, which makes it possible with only two iteration steps to achieve an efficient focusing of the tomograph array. At the first step, the unknown distribution of the large-scale inhomogeneities of sound velocity and absorption over the scatterer is reconstructed, where the large-scale inhomogeneities are those whose size exceeds several wavelengths. At the second step, the fine structure of the scatterer is reconstructed against the large-scale background, which can be performed with a high accuracy owing to the evaluation of the background at the first step. The possibility of simultaneous reconstruction of the large-scale and fine structures by the noniterative Grinevich-Novikov algorithm is considered as an alternative. This algorithm reconstructs in an explicit form two-dimensional refractive-absorbing acoustic scatterers of almost arbitrary shape and strength. Taking into account the effects of multiple scattering, this algorithm provides resolution of the fine structure almost as good as that achieved in reconstructing the same structure against an undistorting homogeneous background. The results of numerical simulations of both algorithms are presented. 相似文献
7.
8.
V. A. Potemkin M. A. Grishina E. V. Bartashevich 《Journal of Structural Chemistry》2007,48(1):155-160
The BiS algorithm is suggested for modeling the drug molecule orientation within a receptor cavity. It is based on the assumption of complementarity of the field created by biologically active compounds and the field of the responsive receptor. The comparison of predicted orientations of various biologically active compounds on the relevant receptors with the data of X-ray structural studies (Protein Data Bank) reveals that the results obtained with this approach surpasses those reported in the literature. The suggested technique made it possible to elucidate the details of the action mechanism of DNA antimetabolites, dihydrofolate reductase inhibitors. The dependence of the activity on the structural parameters of “ligand-receptor” complexes is determined. 相似文献
9.
Dmitry V. Moiseev Vera A. Morugova Andrey S. Shavirin Victor A. Dodonov 《Journal of organometallic chemistry》2004,689(4):731-737
Tetraphenylantimony(V) carboxylates have been used in the palladium-catalyzed C-phenylation reaction of methyl acrylate in the presence of (PhCO2)2 or t-BuOOH under mild conditions (50 °C). The peroxides promote a cascade participation of the organoantimony compound and result in the transfer of three phenyl groups. Organoantimony intermediates have been isolated from the reaction. 相似文献
10.
The interaction of comenic acid with cetylpyridinium chloride in aqueous solutions was studied by spectrophotometry. Compositions of ionic associates formed depending on cetylpyridinum chloride concentration were found, and logarithms of equilibrium constants of corresponding association reactions were determined. 相似文献