全文获取类型
收费全文 | 2118篇 |
免费 | 120篇 |
国内免费 | 10篇 |
专业分类
化学 | 1412篇 |
晶体学 | 7篇 |
力学 | 51篇 |
数学 | 414篇 |
物理学 | 364篇 |
出版年
2024年 | 4篇 |
2023年 | 26篇 |
2022年 | 26篇 |
2021年 | 37篇 |
2020年 | 60篇 |
2019年 | 55篇 |
2018年 | 41篇 |
2017年 | 27篇 |
2016年 | 84篇 |
2015年 | 78篇 |
2014年 | 88篇 |
2013年 | 139篇 |
2012年 | 137篇 |
2011年 | 196篇 |
2010年 | 108篇 |
2009年 | 58篇 |
2008年 | 133篇 |
2007年 | 120篇 |
2006年 | 120篇 |
2005年 | 100篇 |
2004年 | 97篇 |
2003年 | 73篇 |
2002年 | 66篇 |
2001年 | 45篇 |
2000年 | 22篇 |
1999年 | 11篇 |
1998年 | 15篇 |
1997年 | 17篇 |
1996年 | 27篇 |
1995年 | 28篇 |
1994年 | 16篇 |
1993年 | 15篇 |
1992年 | 18篇 |
1991年 | 8篇 |
1990年 | 14篇 |
1989年 | 11篇 |
1988年 | 9篇 |
1987年 | 6篇 |
1986年 | 8篇 |
1985年 | 12篇 |
1984年 | 7篇 |
1983年 | 4篇 |
1982年 | 10篇 |
1981年 | 5篇 |
1979年 | 4篇 |
1978年 | 6篇 |
1968年 | 8篇 |
1967年 | 3篇 |
1966年 | 8篇 |
1915年 | 4篇 |
排序方式: 共有2248条查询结果,搜索用时 31 毫秒
2.
Lagrangian and Eulerian modelling approaches are compared for simulating turbulent dispersion and coalescence of droplets within a spray. Both models predict similar droplet dispersion rates and shifts in droplet size distribution due to coalescence within the spray, over a wide range of droplet and gas flows, and for sprays with different droplet-size distributions at the nozzle exit. The computer time required for simulating coalescence within a steady axisymmetric spray is of a similar order of magnitude regardless of which formulation, Eulerian or Lagrangian, is adopted. However, the Lagrangian formulation is more practical in terms of the range of applicability and ease of implementation. 相似文献
3.
4.
Laura Bader Nicola Durante Maska Law Guglielmo Lunardon Tim Penttila 《Designs, Codes and Cryptography》2003,29(1-3):41-50
We do the tentative beginnings of a study of BLT-sets of generalised quadrangles via their symmetries. In particular, the study of whorls about a line leads us to hyperbolic reflections preserving a BLT-set of Q(4, q). 相似文献
5.
6.
Jacquelyn A. Carioscia Lauren Schneidewind Casey O'Brien Robert Ely Caitlin Feeser Neil Cramer Christopher N. Bowman 《Journal of polymer science. Part A, Polymer chemistry》2007,45(23):5686-5696
The ability to prepare high Tg low shrinkage thiol–ene materials is attractive for applications such as coatings and dental restoratives. However, thiol and nonacrylated vinyl materials typically consist of a flexible backbone, limiting the utility of these polymers. Hence, it is of importance to synthesize and investigate thiol and vinyl materials of varying backbone chemistry and stiffness. Here, we investigate the effect of backbone chemistry and functionality of norbornene resins on polymerization kinetics and glass transition temperature (Tg) for several thiol–norbornene materials. Results indicate that Tgs as high as 94 °C are achievable in thiol–norbornene resins of appropriately controlled chemistry. Furthermore, both the backbone chemistry and the norbornene moiety are important factors in the development of high Tg materials. In particular, as much as a 70 °C increase in Tg was observed in a norbornene–thiol specimen when compared with a sample prepared using allyl ether monomer of analogous backbone chemistry. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5686–5696, 2007 相似文献
7.
8.
Allison K. O'Brien Neil B. Cramer Christopher N. Bowman 《Journal of polymer science. Part A, Polymer chemistry》2006,44(6):2007-2014
The overall effects of oxygen on thiol–acrylate photopolymerizations were characterized. Specially, the choice of thiol monomer chemistry, functionality, and concentration on the extent of oxygen inhibition were considered. As thiol concentration was increased, the degree of oxygen inhibition was greatly reduced because of chain transfer from the peroxy radical to the thiol. When comparing the copolymerization of 1,6‐hexanediol diacrylate with the alkane‐based thiol (1,6‐hexane dithiol) to the copolymerization with the propionate thiol (glycol dimercaptopropionate), it was found that the propionate system was much more reactive and polymerized to a greater extent in the presence of oxygen. In addition, the functionality was considered where the glycol dimercaptopropionate was compared to a tetrafunctional propionate of similar chemistry (pentaerythritol tetrakis(mercaptopropionate)). Given the same thiol concentration, the higher functionality thiol imparted a faster polymerization rate, due to the increased polymer system viscosity, which limited oxygen diffusion and decreased the extent of overall oxygen inhibition. Thus, preliminary insight is provided into how thiol monomer choice affects the extent of oxygen inhibition in thiol–acrylate photopolymerization. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2007–2014, 2006 相似文献
9.
Tim R. Dargaville Julie M. Elliott Mathew Celina 《Journal of Polymer Science.Polymer Physics》2006,44(22):3253-3264
Films of piezoelectric PVDF and P(VDF‐TrFE) were exposed to vacuum UV (115–300 nm VUV) and γ‐radiation to investigate how these two forms of radiation affect the chemical, morphological, and piezoelectric properties of the polymers. The extent of crosslinking was almost identical in both polymers after γ‐irradiation, but surprisingly, was significantly higher for the TrFE copolymer after VUV‐irradiation. Changes in the melting behavior were also more significant in the TrFE copolymer after VUV‐irradiation due to both surface and bulk crosslinking, compared with only surface crosslinking for the PVDF films. The piezoelectric properties (measured using d33 piezoelectric coefficients and D‐E hysteresis loops) were unchanged in the PVDF homopolymer, while the TrFE copolymer exhibited more narrow D‐E loops after exposure to either γ‐ or VUV‐radiation. The more severe damage to the TrFE copolymer in comparison with the PVDF homopolymer after VUV‐irradiation is explained by different energy deposition characteristics. The short wavelength, highly energetic photons are undoubtedly absorbed in the surface layers of both polymers, and we propose that while the longer wavelength components of the VUV‐radiation are absorbed by the bulk of the TrFE copolymer causing crosslinking, they are transmitted harmlessly in the PVDF homopolymer. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3253–3264, 2006 相似文献
10.
Tim Bedford 《Constructive Approximation》1989,5(1):33-48
We consider some self-affine fractal functions previously studied by Barnsleyet al. The graphs of these functions are invariant under certain affine scalings, and we extend their definition to allow the use of nonlinear scalings. The Hölder exponent,h, for these fractal functions is calculated and we show that there is a larger Hölder exponent,h
, defined at almost every point (with respect to Lebesgue measure). For a class of such functions defined using linear affinities these exponents are related to the box dimensionD
B of the graph byh2–D
Bh
.Communicated by Michael F. Barnsley. 相似文献