A critical survey of approximate scattering wave theories from random rough surfaces

This review is intended to provide a critical and up-to-date survey of the analytical approximate methods that are encountered in scattering from random rough surfaces. The underlying principles of the different methods are evidenced and the functional form of the corresponding scattering amplitude or cross-section is given. The reader is referred to the original papers in order to obtain the explicit expressions of the coefficients and kernels. We have tried to identify the main strengths and weaknesses of the various theories. We provide synthetic tables of their respective performances, according to a dozen important requirements a valuable method should meet. Both scalar acoustic and vector electromagnetic theories are equally addressed.     

Analytical comparison between the surface current integral equation and the second-order small-slope approximation

This paper is the third in a series discussing a new approximate bistatic model for electromagnetic scattering from perfectly conducting rough surfaces. Our previous approach supplemented the Kirchhoff model through the addition of new terms involving linear orders in slope and surface elevation differences that arise naturally from a second iteration of the surface current integral equation. This completion of the Kirchhoff was shown to provide the correct first-order small perturbation method (SPM-1) in the general bistatic context. The agreement with SPM-1 was achieved because differences of surface heights are no longer expanded in powers of surface slope. While consistent with SPM, our previous formulation fails to reconverge toward the Kirchhoff model, at some incidence and scattered angles, when the illuminated surface satisfies the high frequency roughness condition. This weakness is also shared with the first-order small slope approximation (SSA-1) which is structurally equivalent to our previous formulation where the polarization is independent of surface roughness. The second-order small slope approximation (SSA-2), which satisfies the SPM-1 and second-order small perturbation method (SPM-2) limits by construction, was shown by Voronovich to converge toward the tangent plane approximation of the Kirchhoff model under high frequency conditions. In the present paper, we show that, in addition to the linear orders in our previous model, one must now include cross-terms between slope and surface elevation to ensure convergence toward both high frequency and small perturbation limits. With the inclusion of these terms, our new formulation becomes comparable to the SSA-2 (second-order kernel) without the need to evaluate all the quadratic order slope and elevations terms. SSA-2 is more complete, however, in the sense that it guarantees convergence toward the second-order Bragg limit (SPM-2) in the fully dielectric case in addition to both SPM-1 and Kirchhoff. Our new generalization is shown to explain correctly extra depolarization in specular conditions to be caused by surface curvature and surface autocorrelation for incoherent and coherent scattering, respectively. This result will have large repercussions on the interpretation of bistatically reflected signals such as those from GPS.     

Dioxygen Binding in the Active Site of Histone Demethylase JMJD2A and the Role of the Protein Environment

JMJD2A catalyses the demethylation of di‐ and trimethylated lysine residues in histone tails and is a target for the development of new anticancer medicines. Mechanistic details of demethylation are yet to be elucidated and are important for the understanding of epigenetic processes. We have evaluated the initial step of histone demethylation by JMJD2A and demonstrate the dramatic effect of the protein environment upon oxygen binding using quantum mechanics/molecular mechanics (QM/MM) calculations. The changes in electronic structure have been studied for possible spin states and different conformations of O₂, using a combination of quantum and classical simulations. O₂ binding to this histone demethylase is computed to occur preferentially as an end‐on superoxo radical bound to a high‐spin ferric centre, yielding an overall quintet ground state. The favourability of binding is strongly influenced by the surrounding protein: we have quantified this effect using an energy decomposition scheme into electrostatic and dispersion contributions. His182 and the methylated lysine assist while Glu184 and the oxoglutarate cofactor are deleterious for O₂ binding. Charge separation in the superoxo‐intermediate benefits from the electrostatic stabilization provided by the surrounding residues, stabilizing the binding process significantly. This work demonstrates the importance of the extended protein environment in oxygen binding, and the role of energy decomposition in understanding the physical origin of binding/recognition.     

Extension of the local curvature approximation to third order and improved tilt invariance

The second-order local curvature approximation (LCA2) is a theory of rough surface scattering that reproduces fundamental low and high frequency limits in a tilted frame of reference. Although the existing LCA2 model provides agreement with the first order small perturbation method up to the first order in surface tilt, results reported in this paper produce a new formulation of the model that achieves consistency with perturbation theory to first order in surface height and arbitrary order in surface tilt. In addition, extension of the modified LCA to third order is presented, and allows the theory to match the second-order small perturbation method to arbitrary order in surface tilt. Crucial to the development of the theory are a set of identities involving relationships among the small perturbation method (i.e. low frequency) and Kirchhoff approximation (i.e. high frequency) kernels; a set of new identities obtained in our derivations is also presented. Sample results involving 3D electromagnetic scattering from penetrable rough surfaces, as well as 2D scattering from Dirichlet sinusoidal gratings, are provided to compare the new results with the existing LCA2 model and with other rough surface scattering theories.     

A practical second-order electromagnetic model in the quasi-specular regime based on the curvature of a 'good-conducting' scattering surface

This letter presents an approximate second-order electromagnetic model where polarization coefficients are surface dependent up to the curvature order in the quasi-specular regime. The scattering surface is considered 'good-conducting' as opposed to the case for our previous derivation where perfect conductivity was assumed. The model reproduces dynamically, depending on the properties of the scattering surface, the tangent-plane (Kirchhoff) or the first-order small-perturbation (Bragg) limits. The convergence is assumed to be ensured by the surface curvature alone. This second-order model is shown to be consistent with the small-slope approximation of Voronovich (SSA-1+SSA-2) for perfectly conducting surfaces. Our model differs from SSA-1 + SSA-2 in its dielectric expression, to correct for a full convergence toward the tangent-plane limit under the 'good-conducting' approximation. This new second-order formulation is simple because it involves a single integral over the scattering surface and therefore it is suitable for a vast array of analytical and numerical applications in quasi-specular applications.     

Rayleigh's hypothesis and the geometrical optics limit

The Rayleigh hypothesis (RH) is often invoked in the theoretical and numerical treatment of rough surface scattering in order to decouple the analytical form of the scattered field. The hypothesis stipulates that the scattered field away from the surface can be extended down onto the rough surface even though it is formed by solely up-going waves. Traditionally this hypothesis is systematically used to derive the Volterra series under the small perturbation method which is equivalent to the low-frequency limit. In this Letter we demonstrate that the RH also carries the high-frequency or the geometrical optics limit, at least to first order. This finding has never been explicitly derived in the literature. Our result comforts the idea that the RH might be an exact solution under some constraints in the general case of random rough surfaces and not only in the case of small-slope deterministic periodic gratings.     

A new bistatic model for electromagnetic scattering from perfectly conducting random surfaces

In this paper, we extend the Kirchhoff approach, which is widely used for near-nadir backscattering calculations, to include the proper polarization sensitivity for general bistatic scattering from gently sloping, perfectly conducting surfaces. Previously, Holliday has shown how the inclusion of terms from the second iteration of the surface-current integral equation is required to obtain agreement with the small perturbation method for backscattering conditions. Here we employ a similar approach by retaining all terms in this iterative expansion through first order in the surface slope to derive expressions for the standard Kirchhoff field as well as for a supplementary field that contains the polarization sensitivity. A polarization vector notation is introduced to simplify the inclusion of tilting effects from larger-scale features on the scattering surface. In connection with this latter development, we provide a clarification of the earlier work by Valenzuela on this topic together with an extension to the bistatic problem. These extensions to the standard Kirchhoff approach form the basis for our composite bistatic scattering model which should provide a convenient and powerful tool for calculations involving passive as well as active microwave scattering from random surfaces.     

Two families of non-local scattering models and the weighted curvature approximation

There are several nonlocal scattering models available in the literature. Most of them are given with little or no mention of their expected accuracy. Moreover, high- and low-frequency limits are rarely tested. The most important limits are the low-frequency or the small perturbation method (SPM) and the high-frequency Kirchhoff approximation (KA) or the geometric optics (GO). We are interested in providing some insight into two families of non-local scattering models. The first family of models is based on the Meecham-Lysanov ansatz (MLA). This ansatz includes the non-local small slope approximation (NLSSA) by Voronovich and the operator expansion method by Milder (OEM). A quick review of this first family of models is given along with a novel derivation of a series of kernels which extend the existing models to include some more fundamental properties and limits. The second family is derived from formal iterations of geometric optics which we call the ray tracing ansatz (RTA). For this family we consider two possible kernels. The first is obtained from iteration of the high-frequency Kirchhoff approximation, while the second is an iteration of the weighted curvature approximation (WCA). In the latter case we find that most of the required limits and fundamental conditions are fulfilled, including tilt invariance and reciprocity. A study of scattering from Dirichlet sinusoidal gratings is then provided to further illustrate the performance of the models considered.     

Analysis of random nonlinear water waves: the Stokes–Woodward techniqueLa technique de Stokes–Woodward pour l'analyse de vagues aléatoires non linéaires

A generalization of the Woodward's theorem is applied to the case of random signals jointly modulated in amplitude and frequency. This yields the signal spectrum and a rather robust estimate of the bispectrum. Furthermore, higher order statistics that quantify the amount of energy in the signal due to nonlinearities, e.g., wave–wave interaction in the case of water waves, can be inferred. Considering laboratory wind generated water waves, comparisons between the presented generalization and more standard techniques allow to extract the spectral energy due to nonlinear wave–wave interactions. It is shown that our analysis extends the domain of standard spectral estimation techniques from narrow-band to broad-band processes. To cite this article: T. Elfouhaily et al., C. R. Mecanique 331 (2003).