Formant frequency discrimination by Japanese macaques (Macaca fuscata).

These studies investigated formant frequency discrimination by Japanese macaques (Macaca fuscata) using an AX discrimination procedure and techniques of operant conditioning. Nonhuman subjects were significantly more sensitive to increments in the center frequency of either the first (F1) or second (F2) formant of single-formant complexes than to corresponding pure-tone frequency shifts. Furthermore, difference limens (DLs) for multiformant signals were not significantly different than those for single-formant stimuli. These results suggest that Japanese monkeys process formant and pure-tone frequency increments differentially and that the same mechanisms mediate formant frequency discrimination in single-formant and vowel-like complexes. The importance of two of the cues available to mediate formant frequency discrimination, changes in the phase and the amplitude spectra of the signals, was investigated by independently manipulating these two parameters. Results of the studies indicated that phase cues were not a significant feature of formant frequency discrimination by Japanese macaques. Rather, subjects attended to relative level changes in harmonics within a narrow frequency range near F1 and F2 to detect formant frequency increments. These findings are compared to human formant discrimination data and suggest that both species rely on detecting alterations in spectral shape to discriminate formant frequency shifts. Implications of the results for animal models of speech perception are discussed.     

Mössbauer and infrared spectroscopic studies of novel mixed valence states in cobaltous ferrocyanides and ferricyanides

Novel mixed valence states have been obtained by the treatment of cobaltous ferrocyanides (Co⁺²Fe^II) and ferricyanides (Co⁺²Fe^III) in an ozone flow. The CN stretching bands occur at 2085 cm^–1 for Co⁺²Fe^II and at 2160 cm^–1 for Co⁺²Fe^III. After the ozonization process of Co⁺²Fe^II, an intense band approximately at 2125 cm^–1 is detected. This intermediate band must correspond to a mixed valence state of the type: Fe^II–CN–Co²⁺–NC–Fe^III Mössbauer spectra recorded in situ during the ozonization of Co⁺²Fe^II show the presence of two components: a doublet with isomer shift and quadrupole splitting values close to the cobalti ferricyanide and a very broad line for the mixed valence state. From the Mössbauer and infrared spectra of the aged samples of the Co⁺²Fe^II after ozonization, a relaxation process to the initial state of the samples is observed but the mixed valence state is stable.