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Sear RP 《Physical review letters》1996,76(13):2310-2313
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The imine 1 was converted via an indole-2,3-quinodimethane cyclization to the hexahydroindolocarbazole 7, which was further converted to the N-carbomethoxy derivative of staurosporinone 2. 相似文献
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Sear RP 《The journal of physical chemistry. B》2006,110(10):4985-4989
We use computer simulation to calculate the rates of both homogeneous nucleation and heterogeneous nucleation on microscopic impurities. We do so in perhaps the simplest model of fluids and magnets: the two-dimensional Ising model. We expect our results to be qualitatively applicable to many simple and complex fluids. We find that heterogeneous nucleation on an impurity that is not only microscopic but also as small as possible, that is, a single fixed spin, is more than four orders of magnitude faster than homogeneous nucleation. The rate of heterogeneous nucleation then increases by a factor of approximately five for each additional fixed spin in the impurity. These results suggest that impurities as small as single molecules can result in homogeneous nucleation being irrelevant due to heterogeneous nucleation on these microscopic impurities being much faster. 相似文献
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E. Mylius Hager Scheibe Rödiger Wilhelm De la Souchère C. Widemann E. J. Maumené A. Wynter Blyth Fr. Sear Oskar Hausamann und Leopold Brühl 《Fresenius' Journal of Analytical Chemistry》1882,21(1):444-448
Ohne Zusammenfassung 相似文献
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Izabela Jurewicz Alice A. K. King Patnarin Worajittiphon Piyapong Asanithi Eric W. Brunner Richard P. Sear Thomas J. C. Hosea Joseph L. Keddie Alan B. Dalton 《Macromolecular rapid communications》2010,31(7):609-615
Natural materials, such as bone and spider silk, possess remarkable properties as a result of sophisticated nanoscale structuring. They have inspired the design of synthetic materials whose structure at the nanoscale is carefully engineered or where nanoparticles, such as rods or wires, are self‐assembled. Although much work has been done in recent years to create ordered structures using diblock copolymers and template‐assisted assembly, no reports describe highly ordered, three‐dimensional nanotube arrays within a polymeric material. There are only reports of two‐dimensional network structures and structures on micrometer‐size scales. Here, we describe an approach that uses plasticized colloidal particles as a template for the self‐assembly of carbon nanotubes (CNTs) into ordered, three‐dimensional networks. The nanocomposites can be strained by over 200% and still retain high conductivity when relaxed. The method is potentially general and so may find applications in areas such as sensing, photonics, and functional composites.
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Sear RP Chung SW Markovich G Gelbart WM Heath JR 《Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics》1999,59(6):R6255-R6258
Nanoparticles deposited at the air-water interface are observed to form circular domains at low density and stripes at higher density. We interpret these patterns as equilibrium phenomena produced by a competition between an attraction and a longer-ranged repulsion. Computer simulations of a generic pair potential with attractive and repulsive parts of this kind, reproduce both the circular and stripe patterns. Such patterns have a potential use in nanoelectronic applications. 相似文献