Fluorescence quenching using plasmonic gold nanoparticles

This communication describes the study of fluorescence quenching in a new fluorescent laser dye ADS680HO is attached to gold nanoparticles of size 4-12 nm. Photo physical properties confirms that it is due to size, shape, coupling between nanoparticles with laser dye ADS680HO, and energy transfer between dye and nanoparticles. Fluorescence quenching leads to advancement in biomolecular labeling and fluorescence patterning.     

Solvent effects on the absorption and fluorescence spectra of coumarins 6 and 7 molecules: determination of ground and excited state dipole moment

Absorption and fluorescence emission spectra of coumarins 6 and 7 were recorded in solvents with different solvent parameters, viz., dielectric constant epsilon and refractive index n. The fluorescence lifetime of these dyes were measured in butanol at higher values of viscosity over temperature. Experimental ground and excited state dipole moments are determined by means of solvatochromic shift method and also the excited state dipole moments are determined in combination with ground state dipole moments. It was determined that dipole moments of the excited state were higher than those of the ground state in both the molecules.     

Topological structures of complex belief systems (II): Textual materialization

Mythical and religious belief systems in a social context can be regarded as a conglomeration of sacrosanct rites, which revolve around substantive values that involve an element of faith. Moreover, we can conclude that ideologies, myths and beliefs can all be analyzed in terms of systems within a cultural context. The significance of being able to define ideologies, myths and beliefs as systems is that they can figure in cultural explanations. This, in turn, means that such systems can figure in logic‐mathematical analyses. © 2013 Wiley Periodicals, Inc. Complexity 19: 50–62, 2013     

Flow property and self-similarity in steady hydraulic jumps

The flow structure in a steady hydraulic jump in both the non-aerated and aerated regions was measured using the image-based particle image velocimetry and bubble image velocimetry techniques, respectively. Three highly aerated steady jumps with Froude numbers varying from 4.51 to 5.35 were tested, and a weak jump with a Froude number of 2.43 was generated for comparison. Mean velocities and turbulence statistics were obtained by ensemble averaging the repeated velocity measurements. Based on the mean velocities, the flow structure in the steady jumps was classified into four regions to distinguish their distinct flow behaviors; they are the potential core region, the boundary layer region, the mixing layer region, and the recirculation region. The flow structure in the weak jump features only three regions without the recirculation region. In addition, spatial variations of mean velocities, turbulence intensity, and Reynolds stresses were also presented. It was observed that the maximum horizontal bubble velocity and maximum horizontal water velocity occur at the same location in the overlapping regions of potential core and mixing layer. The ratio between the maximum horizontal bubble velocity and maximum horizontal water velocity is between 0.6 and 0.8, depending on the Froude number. Examining the mean horizontal bubble velocities in the mixing layer, a similarity profile was revealed with representative mixing layer thickness as the characteristic length scale and the difference between the maximum positive and maximum negative velocities as the characteristic velocity scale. It was also found that the mean horizontal water velocities in the near-wall region are self-similar and behave like a wall jet. Further analyzing autocorrelation functions and energy spectra of the water and bubble velocity fluctuations found that the energy spectra in the water region follow the ?5/3 slope, whereas the spectra in the bubble region follow a ?2/5 slope. In addition, the integral length scale of bubbles is one order of magnitude shorter than that of water.     

Modular strategy for the synthesis of functionalized aryl-fused azabicyclo[2.2.2]octanes via radical-mediated cascade cyclization

A two-step synthesis of rare 2-azabicyclo[2.2.2]octanes is described. N-propargyl amides obtained via Cu(I)-catalyzed three-component coupling, underwent radical-mediated cascade cyclization to afford 5,6-aryl-fused 2-azabicyclo[2.2.2]octanes with arylidene functionality on the two-carbon bridge in 43–62% yields. Phenylidene and 1-naphtylidene derivatives were obtained exclusively as Z diastereomers, whereas electron rich groups in the arylidene substituent afforded product mixtures favoring the Z diastereomer by 2.3:1 M ratio.     

Rotational diffusion of coumarin laser dye studied by fluorescence depolarization technique

Solute-solvent interactions play a major role in determining the physiochemical properties of solutions. Yet our understanding of this subject is far from complete. Rotational diffusion studies of medium-sized molecules provide a useful means to probe these interactions. The rate of diffusion is sensitive to the shape of the molecule and interaction between the solute and solvent molecules. Because of continuous interactions with their neighbours, molecules rotating in liquid, experience friction. By modeling this friction using various continuum-based theories, we can get better insight into the nature of the solute-solvent interactions. In the present work steady-state and time-resolved fluorescence polarization studies have been carried out with coumarin 30. The rotational reorientation of this probe has been measured in butanol at higher values of viscosity over temperature. However, it was found that coumarin 30 rotates faster in butanol compared to n-octanenitrile.     

A simple strategy for the synthesis of optically pure trans-hydrindane systems

A new strategy for the synthesis of optically pure trans-hydrindane systems is reported from an easily available starting material.     

Complexation and extraction of non-ferrous metals by calix[n]arene phosphine oxides

The extraction of non-ferrous metal (M²⁺) nitrates by the calix[4,6]arenes (L), bearing four or six phosphine oxide donor groups at the upper or at the lower rim, was quantitatively described in the form of [M_n(NO₃)_2nL] (n = 1, 2) complexes. The extraction constants (Zn²⁺ > Cu²⁺ > Co²⁺ > Ni²⁺) for the both types of L coincide with Irving-Williams sequence. Calix[4]arenes, phosphorylated at the lower (narrow) rim, provide better stability of ML complexes because of the best spatial fitting of M²⁺ by the donor groups. For the upper (wide) rim phosphorylated calix[4]arenes M₂L and ML₂ complexes are more stable. Unusual zwitterionic [Co₂(NO₃)₄L] complex of the lower rim tetraphosphorylated calix[4]arene 1 was determined by X-ray structural analysis.