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Yannick Coffinier Gaëlle Piret Manash R. Das Rabah Boukherroub 《Comptes Rendus Chimie》2013,16(1):65-72
The article reports on the wetting properties of silicon-based materials as a function of their roughness and chemical composition. The investigated surfaces consist of hydrogen-terminated and chemically modified atomically flat crystalline silicon, porous silicon and silicon nanowires. The hydrogenated surfaces are functionalized with 1-octadecene or undecylenic acid under thermal conditions. The changes occurring upon surface functionalization are characterized using Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS) spectroscopy and water contact angle measurements. By increasing the surface roughness, the static water contact angle increases. The combination of high surface roughness with chemical functionalization with water repellent coating (1-octadecene) enables reaching superhydrophobicity (water contact angle greater than 150°) for silicon nanowires. 相似文献
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A cosmological scenario with two branes (A and B) moving in a 5-dimensional bulk is considered. As in the case of ecpyrotic and born-again braneworld models it is possible that the branes collide. The energy-momentum tensor is taken to describe a perfect barotropic fluid on the A-brane and a phenomenological time-dependent cosmological constant on the B-brane. The A-brane is identified with our Universe and its cosmological evolution in the approximation of a homogeneous and isotropic brane is analysed. The dynamics of the radion (a scalar field on the brane) contains information about the proper distance between the branes. It is demonstrated that the deSitter type solutions are obtained for late time evolution of the braneworld and accelerative behaviour is anticipated at the present time. 相似文献
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Fornberg Bengt; Flyer Natasha; Hovde Susan; Piret Cecile 《IMA Journal of Numerical Analysis》2008,28(1):121-142
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An efficient and general approach for the synthesis of amphiphilic 1,2-amino alcohols is reported. The use of N-benzyl protecting groups is essential for obtaining good yields when opening a long-chain terminal epoxide with an amine. 相似文献
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Piret Kuusk 《General Relativity and Gravitation》1989,21(2):185-200
It is shown that the Wess-Zumino term of a heterotic superstring in aN = 1,D = 10 supergravity background can be given in terms of the torsion of the background in both versions (IA and IB) of theN = 1,D = 10 supergravity theory. The gauge degrees of freedom of the background are included according to the ideas of Kaluza and Klein. Explicit expressions for the vielbein, connection, torsion, and curvature of a space with 506 bosonic and 16 fermionic coordinates are given. 相似文献
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The asymmetric transfer hydrogenation of α-amido-β-keto esters to provide the corresponding anti-β-hydroxy-α-amido esters in good to excellent yields, diastereoselectivity, and enantioselectivity is reported. The procedure is operationally simple, and delicate handling of the catalyst is not necessary. 相似文献
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High sensitive matrix-free mass spectrometry analysis of peptides using silicon nanowires-based digital microfluidic device 总被引:1,自引:0,他引:1
Lapierre F Piret G Drobecq H Melnyk O Coffinier Y Thomy V Boukherroub R 《Lab on a chip》2011,11(9):1620-1628
We present for the first time an electrowetting on dielectric (EWOD) microfluidic system coupled to a surface-assisted laser desorption-ionization (SALDI) silicon nanowire-based interface for mass spectrometry (MS) analysis of small biomolecules. Here, the transfer of analytes has been achieved on specific locations on the SALDI interface followed by their subsequent mass spectrometry analysis without the use of an organic matrix. To achieve this purpose, a device comprising a digital microfluidic system and a patterned superhydrophobic/superhydrophilic silicon nanowire interface was developed. The digital microfluidic system serves for the displacement of the droplets containing analytes, via an electrowetting actuation, inside the superhydrophilic patterns. The nanostructured silicon interface acts as an inorganic target for matrix-free laser desorption-ionization mass spectrometry analysis of the dried analytes. The proposed device can be easily used to realize several basic operations of a Lab-on-Chip such as analyte displacement and rinsing prior to MS analysis. We have demonstrated that the analysis of low molecular weight compounds (700 m/z) can be achieved with a very high sensitivity (down to 10 fmol μL(-1)). 相似文献
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C. David D. Baeyens-Volant G. Delaunois Q. Lu Vinh W. Piret G. Geuskens 《European Polymer Journal》1978,14(7):501-507
Changes of molecular weight distribution resulting from vacuum photolysis and photo-oxidation of polystyrene have been determined by gel permeation chromatography. On irradiation at 253.7 nm, crosslinking is predominant in vacuo; in the presence of oxygen, crosslinking and main chain scission occur simultaneously because of light absorption by two or more different chromophores. Main chain scission is more important than crosslinking in the photolysis and photo-oxidation of polystyrene containing cumene hydroperoxide irradiated at 313 nm or containing benzophenone irradiated in the range 320–420 nm. In this last case, main chain scission and crosslinking are both strongly inhibited if the sample contains napthalene which acts as quencher of the excited triplet state of benzophenone. Only moderate inhibition is observed in the presence of 2,6-di-t-butyl-4 methylphenol. 相似文献
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