Modification of styrene-containing polymer with pinane. Possible applications of the product

The influence of high-temperature treatment on the properties of a styrene-containing polymer prepared from by-products of polybutadiene production was studied. The use of the products in production of emulsion rubbers and for protecting treatment of wood materials was examined. Original Russian Text S.S. Nikulin, O.N. Chernykh, 2006, published in Zhurnal Prikladnoi Khimii, 2006, Vol. 79, No. 11, pp. 1900–1905.     

Recovery of Butadiene-Styrene Rubber from Latex at Low Temperature with Various Coagulants

The influence of the charge of a metal cation and the nature of a coagulant on the recovery of butadiene-styrene rubber and properties of rubber stocks and vulcanizates was examined.     

Basic principles of technological shaping of optical properties and radiation hardness of PWO crystals

Technological conditions ensuring growth of optically homogeneous lead tungstate (PWO) crystals are reported. It is shown that the basic scintillator characteristics of PWO grown from highly purified raw material and properly doped with lanthanides are mainly determined by inclusions of oxides W_1−yL_yO_3−x (L=Y, La, Gd; 0<x<0.3). Moreover, surface-located inclusions with structure close to tungstenite may also be of importance. It is demonstrated that the scintillation properties can be intentionally designed by varying the oxygen content in the inclusions x and the surface structure. The optimal value for x and the most favorable surface structure are achieved by proper thermal regimes and environment content during the crystal annealing. The results enabled low-cost fabrication of PWO scintillators with steady and reproducible characteristics acceptable for the CERN project ALICE and ensured production of PWO on an industrial scale by “North Crystals” company at a rate of 125–135 crystals per year from every growth apparatus.     

Generation of a homogeneous plasma and wide ion beams in a penning system with a nonequipotential cathode

A study is made of the possibility of controlling the spatial distribution of the degree of ionization in a modified Penning cell with a cathode divided into several sections that are at different potentials. It is shown that an almost uniform plasma can be produced when applying an optimal potential of the control electrode. This enables the generation of wide ion beams in this system. An ion extraction efficiency of several tens of percent is achieved, which is substantially higher than in conventional ion sources.     

Experimental investigation of population inversion of oxygen K-ion levels

Experimental results are reported of investigations of the optical properties of the plasma produced when an AI₂O₃ target is irradiated in vacuum by a high-power neodymiunr-glass laser system. It is shown that a number of 0 VIII and 0 VII ion levels with principal quantum numbers n = 2, 3, 4 are inversely populated. The gain at the wavelength 29 nm (4 3 transition, O VIII) under the experimental conditions is of the order of 0.01 cm^-1. For the heliumlike ions O VII, in a transition with the same principal quantum numbers (ls4p¹P₁ ls3s¹S₀, 36.9 nm), the gain is of the order of 10^-2–10^-1 cm^-1, depending on the electron density.Translated from Lazernye Sistemy, pp. 5–14 1982.     

Decay of atomic systems in a strong electric field. Negative ion and hydrogen atom

An exact transcendental equation was obtained determining the energy levels of a particle bound by a short-range force and placed in uniform electric field. At high intensities there is a considerable difference between the values of decay probabilities calculated by previous theory and by this one. The results obtained were used to determine the electron binding energy and the polarizability of negative ions by employing experimental data on ion decay during a flight through the field region. Concrete calculations were carried out for the C^? ion.The calculation of the resonance energy E_r and the decay probability 2Γ of the quasistationary state n = S, n₁ = 3, n₂ = 0, and m = 1 of the hydrogen atom in a uniform electric field was performed by means of the direct integration of the time-independent Schrödinger equation for field intensities ranging from 0.8 × 10⁶V/cm to 1.7 × 10⁶V/cm. The calculated values fo E_r perfectly agree with those of the Rayleigh—Schrödinger perturbation energies calculated up to the fourth power in the field strength and differ substantially from the resonance energies obtained earlier by Hirschfelder and Curtiss. Our results concerning the rate of spontaneous ionization also differ substantially from the results of Hirschfelder and Curtiss and agree rather well with the results of Bailey, Hiskes and Riviere who used the general WKB method of Rice and Good.