We report on measurements of the electrical resistivity and the superconducting transition temperature of amorphous La–Ag alloys (60–74 at % La) obtained by liquid quenching. The temperature coefficient of the resistivity is always slightly negativ, its value cannot be described well by existing theories.Tc depends linearly on the La content and seems to be not very sensitive to the second alloy constituent.Dedicated to Prof. Dr. W. Buckel on the occasion of his 60th birthday 相似文献
The preparation and properties as well as some reactions of a series of arylcarbonylbis(triphenylphosphine)iridium(I) complexes [Ir(Ar)(CO)(PPh3)2] (Ar = C6H5, C6F5, 2-C6H4CH3, 3-C6H4CH3, 4-C6H4CH3, 2-C6H4OCH3, 2,6-C6H3-(OCH3)2, 4-C6H4N(CH3)2, 3-C6H4Cl, 4-C6H4Cl, 4-C6H4Cl, 3-C6H4CF3, 4-C6H4CF3) are described, and the most important IR data as well as the 31P NMR parameters of these, without exception trans-planar, compounds are given.
Some of the complexes react with molecular oxygen to form well defined dioxygen adducts [Ir(Ar)(O2)(CO)(PPh3)2] (Ar = C6H5, 3-C6H4CH3, 4-C6H4CH3). Complexes with ortho-substituted aryl ligands are not oxygenated. This effect is referred to as a steric shielding of the metal center by the corresponding ortho-substituents. With SO2 the similar irreversible addition compound [Ir(4-C6H4CH3)-(SO2)(CO)(PPh3)2] is obtained. Sulfur dioxide insertion into the Ir---C bond cannot be observed.
The first step of the reaction between [Ir(4-C6H4CH3)(CO)(PPh3)2] and hydrogen chloride involves an oxidative addition of HCl to give [Ir(H)(Cl)(4-C6-H4CH3)(CO)(PPh3)2]. Ir---C bond cleavage by reductive elimination of toluene from the primary adduct does not occur except at elevated temperature. 相似文献
In this paper we extend the plane blow-up results of Grundy& McLaughlin (1997) to the three-dimensional Navier-Stokes equations.Using a solution structure originally due to Lin we first providenumerical evidence for the existence of blow-up solutions on- < x, z < , 0 y 1 with boundary conditions on y = 0and y = 1 involving derivatives of the velocity components.The formulation enables us to consider plane and radial flowas special cases. Various features of the computations are isolatedand are used to construct a formal asymptotic solution closeto blow-up. We show that the numerical and asymptotic analysesprovide a mutually consistent global picture which supportsthe conclusion that, for the family of problems we considerhere, blow-up in fact can take place in three dimensions butat an inverse linear rate rather than the faster inverse squareof the plane case. 相似文献
Ice nucleating-active Pseudomonas fluorescens F264C was fed to Colorado potato beetles to determine bacterial retentioin in the beetle gut and its effect on the cold hardiness of this insect pest. The bacrterium was present in beetles recovered after overwintering in the field, seven months after their exposure to P. fluorescens. Retention was evident not only in the detection of the P. fluorescens ice nucleating gene, inaW, in bacterial cultures from beetle guts but also in the elevated supercooling points of some treated beetles. 相似文献
In this article, our primary concern is the classical problem of minimizing globally a concave function over a compact polyhedron (Problem (P)). We present a new simplicial branch and bound approach, which combines triangulations of intersections of simplices with halfspaces and ideas from outer approximation in such a way, that a class of finite algorithms for solving (P) results. For arbitrary compact convex feasible sets one obtains a not necessarily finite but convergent algorithm. Theoretical investigations include determination of the number of simplices in each applied triangulation step and bounds on the number of iterations in the resulting algorithms. Preliminary numerical results are given, and additional applications are sketched. 相似文献
The sd-interacting boson approximation (sd-IBA) and the df-interacting boson approximation (df-IBA) can be related to each other and the states of the interacting boson approximation model can be identified with the fully symmetric states in the sdf interacting boson approximation model. A systematic study of the sdf-IBA model showed that the constructed Hamiltonian can successfully describe the strong octupole correlations in the deformed nuclei. We showed that the interacting boson approximation may account for many of these Kπ?=?0+ states. It was found that the calculated energy spectra of the gadolinium isotopes agree quite well with the experimental data. The observed B(E2) values were also calculated and compared with the experimental data. 相似文献
5-Geranoxypsoralen, commonly called bergamottin, a major furocoumarin contained in bergamot oil, is reported in vitro as a highly photoreactive psoralen. In ethanol, it exhibits quite a high triplet state quantum yield (approximately 0.37). The triplet state is involved in subsequent photochemistry which depends on the initial concentration and on the presence of oxygen. In contrast to most psoralens, absorption and fluorescence data suggest that 5-geranoxypsoralen does not interact with DNA in the dark. No UVA-induced interstrand cross-links in DNA were shown. 相似文献