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Harry Adams Sarah A Morris Jeffrey C Motley 《Journal of organometallic chemistry》2004,689(3):522-527
Transfer of dithiolene ligands from [Ni(S2C2Ph2)2] to the dimolybdenum complex [Mo2(μ-C2R2)(CO)4Cp2] (R=CO2Me, Cp=η-C5H5) affords the first example of a dithiolene alkyne complex, [Mo2(μ-C2R2)(μ-S2C2Ph2)2Cp2], together with [Mo2(μ-SCRCR)(μ-SCPhCPh)Cp2] in which sulfur transfer from dithiolene to alkyne has occurred. 相似文献
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Let K be a field complete with respect to a real valuation v and not algebraically closed. We will show that every finite codimension subfield of K is closed in the v-adic topology if and only if the degree of imperfection of K is finite. It follows that there are incomplete finite codimension subfields of K when the degree of imperfection of K is infinite. These examples exhibit other interesting pathologies. We are able to give a necessary (and in the case of a discrete real valuation also sufficient) condition for a given finite codimension subfield to be complete. Finally, we give some applications to fields of Laurent series. Communicated by A. Prestel. 相似文献
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D. Michelle Motley Judith A. Walmsley Julio Zukerman-Schpector Edward R. T. Tiekink 《Journal of chemical crystallography》2009,39(5):364-367
Abstract The gold(III) atom in [Au(NH2CH2CH2NH2)Cl2]NO3 is chelated by the ethylenediamine (en) ligand and the approximately square planar geometry is completed by two chloride
atoms. Weak Au···O and Au···Cl contacts are noted above and below the square plane leading to a tetragonally distorted octahedron
for the gold(III) center. Extensive charge-assisted hydrogen bonding of the type N–H···O leads to the formation of a 2-D array
and layers are consolidated into a 3-D network via C–H···O and C–H···Cl contacts. The compound crystallizes in the orthorhombic
space group Pbca with a = 10.3380(11) ?, b = 8.2105(7) ?, c = 19.625(2) ?, and Z = 8.
Index Abstract Square planar complex cations form additional Au···O and Au···Cl interactions to form a tetragonally distorted octahedron
for gold. The ionic components are connected into a 2-D array via charge-assisted N–H···O hydrogen bonding interactions.
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Reflection of plane waves from the boundary of a pre-stressed compressible elastic half-space 总被引:2,自引:0,他引:2
The effect of pre-stress on the propagation and reflection ofplane waves in an incompressible isotropic elastic half-spacehas been examined recently by the authors (Ogden & Sotiropoulos,1997). In the present paper the corresponding analysis for compressiblematerials is detailed. In the two-dimensional context consideredfor incompressible materials the (homogeneous) plane waves werenecessarily shear waves. By contrast, in the compressible contextpure shear waves can propagate only in specific directions inthe considered principal plane and, in a general direction,a quasi-shear wave may be accompanied by a quasi-longitudinalwave, as is the case in the anisotropic linear theory. The dependenceof the (in-plane) slowness section on the pre-stress (and finitedeformation) and on the choice of constitutive law is elucidated.This information is used to determine the reflection coefficientsfor reflection of either a (quasi-) shear wave or a (quasi-)longitudinal wave from the boundary of the half-space and tocharacterize the different cases which arise depending on thegeometry of the slowness section. The theoretical results are illustrated by numerical calculationsfor the range of possible types of behaviour with referenceforms of strain-energy function and different states of finitedeformation and to the question of stability of the half-space. 相似文献