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排序方式: 共有160条查询结果,搜索用时 15 毫秒
1.
Gürbüzbalaban Mert Ruszczyński Andrzej Zhu Landi 《Journal of Optimization Theory and Applications》2022,194(3):1014-1041
Journal of Optimization Theory and Applications - We consider a distributionally robust formulation of stochastic optimization problems arising in statistical learning, where robustness is with... 相似文献
2.
Gurkan Hizal Umit Tunca Sermin Aras Humeyra Mert 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):77-87
Copper‐catalyzed controlled/living radical polymerization (LRP) of styrene (St) was conducted using the silica gel‐supported CuCl2/N,N,N′,N′,N″‐pentamethyldiethylenetriamine (SG‐CuCl2/PMDETA) complex as catalyst at 110 °C in the presence of a definite amount of air. This novel approach is based on in situ generation and regeneration of Cu(I) via electron transfer reaction between phenols and Cu(II). Sodium phenoxide or p‐methoxyphenol was used as a reducing agent of Cu(II) complexes in LRP. The number–average molecular weight, Mn,GPC, increases linearly with monomer conversion and agrees well with the theoretical values up to 85% conversion The molecular weight distribution, Mw/Mn, decreases as the conversion increases and reaches values below 1.2. The catalyst was recovered in aerobic condition and reused in copper‐catalyzed LRP of St. For the second run, the number–average molecular weights increased with monomer conversion and the polydispersities decreased as the polymerization proceeded and reached to the value <1.3 at 81% conversion. The recycled catalyst retained 90% of its original activity in the subsequent polymerization. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 77–87, 2006 相似文献
3.
Conidia of Aspergillus niger were immobilized in calcium alginate gel for the production of citric acid. First, the type of the preactivation medium,
together with the preactivation period, was investigated. It was found that A. niger requires a 2-d preactivation period at a 0.05 g/L NH4NO3 concentration. Second, preactivated cells were used to determine the effects of nitrogen concentration and the flow rate
of oxygen and air on the production of citric acid. Maximum citric acid production was attained with medium containing 0.01
g/L of NH4NO3. The rate of citric acid production in the nitrogenous medium was 33% higher when oxygen was used instead of air during the
production phase. This corresponds to an increase of 85% when compared to production when neither oxygen nor air was fed into
the system. In the nonnitrogenous medium citric acid concentration remained similar regardless of the use of air or oxygen.
However, in the nonnitrogenous production medium, citric acid production was not influenced considerably when oxygen was used
instead of air. The advantage of using immobilized cells is that production is achieved easily in the continuous system. Therefore,
citric acid production was also tested using a packed-bed bioreactor, and an increase in productivity by a factor of 22 was
achieved compared to the batch system. 相似文献
4.
We formulate a sufficient condition for the existence of a consistent price system (CPS), which is weaker than the conditional full support condition (CFS). We use the new condition to show the existence of CPSs for certain processes that fail to have the CFS property. In particular this condition gives sufficient conditions, under which a continuous function of a process with CFS admits a CPS, while the CFS property might be lost. 相似文献
5.
Mert Mehmet Selçuk Mert Hatice Hande Sert Merve 《Journal of Thermal Analysis and Calorimetry》2019,136(4):1551-1561
Journal of Thermal Analysis and Calorimetry - Thermal energy storage systems provide efficiency in order to have better utilization of energy sources while protecting the environment. Thermal... 相似文献
6.
The inhibition efficiency of 2-Pyrrolidin-1-yl-1,3-thiazole-5-carboxylic acid (PTCA) against mild steel (MS) corrosion was investigated in acidic solution by using quantum chemical calculations based on Density Functional Theory (DFT) method and electrochemical measurements. The electrochemical impedance spectroscopy (EIS), potentiodynamic, potential zero charge (pzc) analysis and electrochemical noise (EN) measurements at various concentrations (from 0.1 to 10 mM) and immersion times were utilized in experimental part. The surface analysis was achieved scanning electron microscope (SEM) and contact angle measurements in the absence and presence of 10 mM PTCA. According to DFT results, PTCA exhibited 3.737 eV band gap and 8.130 Debye dipole moment which were a signal of potentially convenient corrosion inhibitor properties. PTCA has a remarkable corrosion inhibition capability to mild steel, which inhibited both anodic and cathodic corrosion rates, relying on it's physically adsorption on the metal solution interface and protection ability was increased with increasing PTCA concentration. The obtained adsorption equilibrium constant was 11.11 × 103 M-1 and calculated standard free energy of adsorption was ?33.03 kJ mol?1. The determined activation energy values were 55.58 kJ mol?1 and 96.86 kJ mol?1 in 0.5 M HCl in the absence and presence of 10 mM PTCA, respectively. PTCA demonstrated a strong inhibition efficiency of 98.3%, after 168 h immersion, according to the EIS results. As a consequently, we recommend that PTCA is a convenient inhibitor in 0.1 M HCl for mild steel protection against corrosion. 相似文献
7.
Bayrakdar Alpaslan Mert Samet Kasımoğulları Rahmi Bangaru Sathya Manivannan Prasath 《Research on Chemical Intermediates》2022,48(5):2087-2109
Research on Chemical Intermediates - Trifluoromethyl group containing pyrazole-3-carboxamide derivative is synthesized and the structure of the molecule (E3N5PC) has been verified by using FT-IR,... 相似文献
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10.
Elgiz Bairamov Rukiye ?zturk Mert Zameddin Ismailov 《Journal of mathematical chemistry》2012,50(5):1100-1110
In this work, firstly in the Hilbert space of vector-functions all selfadjoint extensions of the minimal operator generated by linear singular symmetric differential expression with a selfadjoint operator coefficient A in any Hilbert space H, are described in terms of boundary values. Later structure of the spectrum of these extensions is investigated. 相似文献