Commensurate dynamic magnetic correlations in La2Cu0.9Li0.1O4

When sufficient numbers of holes are introduced into the two-dimensional CuO2 square lattice, dynamic magnetic correlations become incommensurate with underlying lattice in all previously investigated La(2-x)A(x)Cu(1-z)B(z)O(4+y) ( A = Sr or Nd, B = Zn) including high T(c) superconductors and insulators, and in bilayered superconducting YBa2Cu3O6.6 and Bi2Sr2CaCu2O8. Magnetic correlations also become incommensurate in structurally related La2NiO4 when doped with Sr or O. We report an exception to this so-far well-established experimental "rule" in La(2)Cu(1-z)Li(z)O4 in which magnetic correlations remain commensurate.     

Zener double exchange from local valence fluctuations in magnetite

Magnetite (Fe3O4) is a mixed valent system where electronic conductivity occurs on the B site (octahedral) iron sublattice of the spinel structure. Below T(V)=123 K, a metal-insulator transition occurs which is argued to arise from the charge ordering of 2+ and 3+ iron valences on the B sites (Verwey transition). Inelastic neutron scattering measurements show that optical spin waves propagating on the B site sublattice (approximately 80 meV) are shifted upwards in energy above T_{V} due to the occurrence of B-B ferromagnetic double exchange in the mixed valent phase. The double exchange interaction affects only spin waves of Delta(5) symmetry, not all modes, indicating that valence fluctuations are slow and the double exchange is constrained by short-range electron correlations above T(V).     

Stabilization of charge ordering in La1/3Sr2/3FeO3-delta by magnetic exchange

The magnetic exchange energies in charge ordered La1/3Sr2/3FeO3-delta (LSFO) and its parent compound LaFeO3 (LFO) have been determined by inelastic neutron scattering. In LSFO, the measured ratio of ferromagnetic exchange between Fe3+-Fe5+ pairs (JF) and antiferromagnetic exchange between Fe3+-Fe3+ pairs (JAF) fulfills the criterion for charge ordering driven by magnetic interactions (|JF/JAF|>1). The 30% reduction of JAF as compared to LFO indicates that doped holes are delocalized, and charge ordering occurs without a dominant influence from Coulomb interactions.     

Ba(1-x)K(x)Mn2As2: an antiferromagnetic local-moment metal

The compound BaMn2As2 with the tetragonal ThCr2Si2 structure is a local-moment antiferromagnetic insulator with a Néel temperature T(N)=625 K and a large ordered moment μ=3.9μ(B)/Mn. We demonstrate that this compound can be driven metallic by partial substitution of Ba by K while retaining the same crystal and antiferromagnetic structures together with nearly the same high T(N) and large μ. Ba(1-x)K(x)Mn2As2 is thus the first metallic ThCr2Si2-type MAs-based system containing local 3d transition metal M magnetic moments, with consequences for the ongoing debate about the local-moment versus itinerant pictures of the FeAs-based superconductors and parent compounds. The Ba(1-x)K(x)Mn2As2 class of compounds also forms a bridge between the layered iron pnictides and cuprates and may be useful to test theories of high T(c) superconductivity.