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排序方式: 共有68条查询结果,搜索用时 234 毫秒
1.
Helmut Quast Josef Christ Yvonne Görlach Wolfgang von der Saal 《Tetrahedron letters》1982,23(36):3653-3656
The 2,6-dicyano-1,5-dimethylsemibullvalene (2d) synthesized via the bicyclo[3.3.0]octanedione 7 exists as a classical ground state which is lower in energy by less than 5 kcal/mole than the homoaromatic transition of the Cope rearrangement of 2d. 相似文献
2.
In this paper, an accurate model of the spin-coating process is presented and investigated from the analytical point of view. More precisely, the spin-coating process is being described as a one-phase free boundary value problem for Newtonian fluids subject to surface tension and rotational effects. It is proved that for T > 0 there exists a unique, strong solution to this problem in (0, T) belonging to a certain regularity class provided the data and the speed of rotation are small enough in suitable norms. The strategy of the proof is based on a transformation of the free boundary value problem to a quasilinear evolution equation on a fixed domain. The keypoint for solving the latter equation is the so-called maximal regularity approach. In order to pursue in this direction one needs to determine the precise regularity classes for the associated inhomogeneous linearized equations. This is being achieved by applying the Newton polygon method to the boundary symbol. 相似文献
3.
Jörgen Metsik Kristjan Saal Uno Mäeorg Rünno Lõhmus Silver Leinberg Hugo Mändar Margus Kodu Martin Timusk 《Journal of Polymer Science.Polymer Physics》2014,52(8):561-571
Transparent [90% transmittance at 550 nm at a sheet resistance (Rs) of 279 Ω sq?1] poly(3,4‐ethylenedioxythiophene) (PEDOT) films with electrical conductivities up to 1354 S cm?1 are prepared using base‐inhibited vapor phase polymerization at atmospheric pressure. The influence of reaction conditions, such as temperature and growth time, on the film formation is investigated. A simple and convenient two‐electrode method is used for the in situ measurement of resistance, enabling to investigate the growth mechanism of polymer films and the influence of different parameters (relative humidity and the amount of oxidant) on the film growth. Low humidity exerts a detrimental effect on film growth and conductivity. In situ Rs measurements suggest that a large structural change occurs upon washing the PEDOT‐oxidant film. © 2014 Wiley Periodicals, Inc. J Polym Sci Part B: Polym. Phys. 2014 , 52, 561–571 相似文献
4.
Dzmitry M. Zubrytski Gbor Zoltn Elek Margus Lopp Dzmitry G. Kananovich 《Molecules (Basel, Switzerland)》2021,26(1)
Oxidative fragmentation of tertiary cyclopropanols with phenyliodine(III) dicarboxylates in aprotic solvents (dichloromethane, chloroform, toluene) produces mixed anhydrides. The fragmentation reaction is especially facile with phenyliodine(III) reagents bearing electron-withdrawing carboxylate ligands (trifluoroacetyl, 2,4,6-trichlorobenzoyl, 3-nitrobenzoyl), and affords 95−98% yields of the corresponding mixed anhydride products. The latter can be straightforwardly applied for the acylation of various nitrogen, oxygen and sulfur-centered nucleophiles (primary and secondary amines, hydroxylamines, primary alcohols, phenols, thiols). Intramolecular acylation yielding macrocyclic lactones can also be performed. The developed transformation has bolstered the synthetic utility of cyclopropanols as pluripotent intermediates in diversity-oriented synthesis of bioactive natural products and their synthetic congeners. For example, it was successfully applied for the last-stage modification of a cyclic peptide to produce a precursor of a known histone deacetylase inhibitor. 相似文献
5.
A new general method for the synthesis of enols of cyclic 3-alkynyl-substituted 1,2-diketones is developed. Sonogashira cross-coupling of silyl enolates of cyclic 3-bromo-cyclopentane- and 3-bromo-cyclohexane-1,2-diones with variety of substituted acetylenes afforded enols of cyclic 3-alkynyl-1,2-diones with good yields (up to 93%) in a short reaction time. The starting 3-bromo-1,2-diones are easily obtainable by direct bromination of 1,2-diones with NBS. 相似文献
6.
The real and quaternionic charge conjugation operators invariant under the infinite-dimensional Clifford algebra, or compatible with the Fermi algebra, are determined. There results a maze of inequivalent irreducible charged representations, all of which are non-Fock. The representation vectors and their charges admit two interpretations besides those of spinors or states of quantum fields: as wavelets on the circle, with charge conjugations acting via ordinary complex conjugation; and as infinite-dimensional numbers, with charge conjugations acting by automorphisms. 相似文献
7.
A cosmological scenario with two branes (A and B) moving in a 5-dimensional bulk is considered. As in the case of ecpyrotic and born-again braneworld models it is possible that the branes collide. The energy-momentum tensor is taken to describe a perfect barotropic fluid on the A-brane and a phenomenological time-dependent cosmological constant on the B-brane. The A-brane is identified with our Universe and its cosmological evolution in the approximation of a homogeneous and isotropic brane is analysed. The dynamics of the radion (a scalar field on the brane) contains information about the proper distance between the branes. It is demonstrated that the deSitter type solutions are obtained for late time evolution of the braneworld and accelerative behaviour is anticipated at the present time. 相似文献
8.
Different chiral cyclic amino acid alkali metal and ammonium salts were used as catalysts for the asymmetric Michael addition of aldehydes to nitrostyrene. The reaction yield and stereoselectivity depend slightly on the salt cation. The highest yield of the reaction (up to 100%) was obtained with (S)-morpholine-3-carboxylic acid salts, which gave moderate to good enantioselectivities (up to 72% ee) and diastereoselectivities (dr up to 89:11) whereas the highest selectivity was obtained with proline sodium salt (ee 88%). 相似文献
9.
Yoshikazu Giga Katsuya Inui Alex Mahalov Shin’ya Matsui Jürgen Saal 《Archive for Rational Mechanics and Analysis》2007,186(2):177-224
We prove time local existence and uniqueness of solutions to a boundary layer problem in a rotating frame around the stationary
solution called the Ekman spiral. We choose initial data in the vector-valued homogeneous Besov space for 2 < p < ∞. Here the L
p
-integrability is imposed in the normal direction, while we may have no decay in tangential components, since the Besov space
contains nondecaying functions such as almost periodic functions. A crucial ingredient is theory for vector-valued homogeneous
Besov spaces. For instance we provide and apply an operator-valued bounded H
∞-calculus for the Laplacian in for a general Banach space . 相似文献
10.
Indrek ReileAnne Paju Aleksander-Mati MüüriseppTõnis Pehk Margus Lopp 《Tetrahedron》2011,67(33):5942-5948
The asymmetric oxidation of 3-alkyl-cyclopentane-1,2-diones with the Ti(OiPr)4/tartaric ester/t-BuOOH complex, which gives, in a cascade process, highly enantiomerically enriched γ-lactone acids, was studied by 18O isotopic labeling in the substrate and in the oxidant. The path of the labeled atoms was followed by 13C NMR spectroscopy. It was found that the oxidative ring cleavage of 1,2-dione proceeds via a Baeyer-Villiger-type oxidation mechanism. 相似文献