ECONOMICALLY OPTIMAL MARINE RESERVES WITHOUT SPATIAL HETEROGENEITY IN A SIMPLE TWO‐PATCH MODEL

Bioeconomic analyses of spatial fishery models have established that marine reserves can be economically optimal (i.e., maximize sustainable profit) when there is some type of spatial heterogeneity in the system. Analyses of spatially continuous models and models with more than two discrete patches have also demonstrated that marine reserves can be economically optimal even when the system is spatially homogeneous. In this note we analyze a spatially homogeneous two‐patch model and show that marine reserves can be economically optimal in this case as well. The model we study includes the possibility that fishing can damage habitat. In this model, marine reserves are necessary to maximize sustainable profit when dispersal between the patches is sufficiently high and habitat is especially vulnerable to damage.     

PARTICIPATION IN INTERNATIONAL ENVIRONMENTAL AGREEMENTS: THE ROLE OF TIMING AND REGULATION

ABSTRACT. We analyze the formation of self‐enforcing international environmental agreements under the assumption that countries announce their participation either simultaneously or sequentially. It is shown that a sequential formation process opens up possibilities for strategic behavior of countries that may lead to inferior outcomes in terms of global abatement and welfare. We then analyze whether and under which conditions a regulator like an international organization, even without enforcement power, can improve upon globally suboptimal outcomes through coordination and moderation, given that recommendations must be Pareto‐improving to all parties.     

Nuclear quantum effects in calculated NMR shieldings of benzene; a Feynman path integral study

The Feynman path integral Monte Carlo approach has been coupled to the gauge including atomic orbital formalism in order to analyse the absolute magnetic shieldings of the benzene nuclei under the conditions of thermal equilibrium. The Hamiltonian employed in the derivation of ensemble averaged NMR quantities is of the Hartree-Fock type. The basis set used is of 6–31G quality. The spatial delocalization of the atoms leads to a deshielding of both types of benzene nuclei relative to the shieldings experienced at the minimum of the potential energy surface. This deshielding has to be traced back to bond length elongations in thermal equilibrium. The influence of the nuclear fluctuations on the NMR parameters of benzene is quantum driven up to temperatures of 400 K; classical fluctuations are of minor importance in this low-temperature window.     

关于截断型分布族中估计的经验过程的渐近分布的进一步研究

但是,若分布 F 中含有未知参数θ,即 F=F(x;θ),那么为计算经验过程,就必须对θ进行适当的估计,把估计(?)_n 代入(2),(1)中,便得到一估计的经验过程(?)_n(t)。那么,这一估计的经验过程的渐近分布如何?Durbin 研究了这一问题。对一般的分布族 F(x;θ),θ∈(?),在一定的假设条件下(主要是所谓条件 A_2),他证明了这一估计的经验过程(?)(t)其渐近过程是一较复杂的正态过程,这个正态过程一般是依赖于 F 的,甚至依赖于未知参数θ的。但该文指出,当θ是位置、刻度参数时,渐近过程可与θ无关。尔后,Durbin,Schneider 等又具体地研究了指数分布族、Gamma 分布族,得到具体结果,     

An ab initio molecular orbital study of the electronically excited and cationic states of the ozone molecule and a comparison with spectral data

A number of valence and Rydberg, singlet and triplet excited states for ozone in the excitation energy range 1–12eV have been calculated by large scale CI methods preceded by MCSCF studies. A comparison of the theoretical intensity envelope with the VUV + EELS spectrum has been made. The present work supports the assignments for the Huggins + Hartley bands as having two electronic origins, 2 ¹A₁ and 1 ¹B₂. The experimental ～ 9.3eV and ～ 10.2eV bands of the VUV spectrum must have adventitious superposition of valence states on Rydberg transitions, because the high oscillator strengths of the valence states cannot be attributed to the 8.8eV broad band. A number of new valence and Rydberg states have been calculated, and these lead to the conclusion that the experimental 9–11 eV VUV spectral range in particular must yield more experimental states than the few so far identified. This suggests a major need for more sophisticated methods of experimental study for the excited state manifolds. The use of various MCSCF/CI studies of the vertical cationic states, supports the IP order as ²A₁ < ²B₂ < ²A₂. A re-analysis of the 12–13.4eV range of the UV-photoelectron band has been performed, with a view to determining the adiabatic IPs more accurately. The present work suggests that the adiabatic IP₂ lies at 12.86eV, slightly lower than has been assumed, with consequential effect on the analysis of the VUV spectrum near 9.4eV.