Isotope separation by laser-enhanced chemical reaction

Reactivity enhancement was studied using a reaction between a laser excited atomic beam and a molecular beam. This method was applied to lithium isotope separation, in which the excited Li isotopic atom reacts with CHCIF₂. It is found that the specified lithium isotope is enriched in the reaction product LiF, whereas LiCl has no selectivity.     

Nanoscale assemblies of gigantic molecular {Mo154}-rings: (dimethyldioctadecylammonium)20[Mo154O462H8(H2O)70

Clusters based on the mixed-valence gigantic inorganic ring [Mo154O462H14(H2O)70]14- ({Mo154}-ring) and dimethyldioctadecylammonium (DODA) were combined to form novel molecular assemblies of an inorganic-organic hybrid molecular system as Langmuir-Blodgett (LB) and cast films. (DODA)20[Mo154O462H8(H2O)70] (2) was prepared by cation exchange and was characterized by a combination of thermogravimetry, IR, UV-vis-NIR, 1H NMR, and XRD measurements. The salt 2 was soluble in common organic solvents, and the chemical stability of {Mo154}-ring encapsulated by DODA cationic surfactants in CHCl3 was found to be higher than that of the "native" sodium salt of the {Mo154}-ring in H2O. Uniform spherical vesicle-like molecular assemblies of (DODA)20[Mo154O462H8(H2O)70] were observed in dilute THF, whose average diameter of 95 nm and a normalized variance of 5.7% were confirmed by a X-ray small-angle scattering. Deposition of 2 as a cast film showed circular domains with a typical diameter of approximately 100 nm, indicating possible similarities between solution and surface-deposited structures. The resulting LB films of salt 2 were transferred from an acidic buffer subphase with pH = 1.5 onto mica, giving a two-dimensional film surface with a unity transfer ratio. Further, the electronic absorption spectra of the LB multilayer were consistent with the classic type II mixed-valence MoV/MoVI electronic state well know for molybdenum blue {Mo154}-ring systems, and it appears that on the surface the plane of the {Mo154}-ring is approximately parallel to the substrate surface, as indicated by polarized electronic spectra, while the alkyl chains of DODA were relatively normal to the substrate surface. Therefore, the layer between the {Mo154}-rings and DODA cations was alternately stacked along the direction of film propagation. Finally, it was found that the surface morphology of the cast and LB films was determined by the molecular assembly of (DODA)20[Mo154O462H8(H2O)70] in solution and the air-water interface, respectively.     

Direct observation of the differences between Raman scatering and population inversion transition for their emission frequencies and pulse waveforms

In FIR laser emissions optically by a CO₂ laser, it has been reported that there are two different process namely induced Raman scattering and population inversion transition.In this paper, we show that the two different process have clearly different characteristics in emission frequensies and pulse waveforms in the case of a TEA-CO₂ laser excitation.We used in this work an intra-cavity etalon for the study of the emission frequensies and also we used a MOM point contact diode for the detection of the wavaformes.Especially, we show that the FIR pulse waveformes are able to analyze numerically on the concept of rate equations.In conclusion, we indicate that molecules would be classified into two categories with regard to optically pumping by a TEA-CO₂ laser. One of them produce mainly Raman scattered emissions, and other produce only the FIR emissions from population inversion transition in spite of high power intensity excitation.