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1.
Formation of porous polymer morphology by microsyneresis during divinylbenzene polymerization 下载免费PDF全文
Libuše Hanková Ladislav Holub Karel Jeřábek 《Journal of Polymer Science.Polymer Physics》2015,53(11):774-781
This article describes the investigation of the importance of various reaction conditions on microsyneretic pore formation during polymerization of divinylbenzene (DVB) under so‐called “solvothermal” conditions. To induce microsyneretic pore formation, the most important parameter is an unusually high dilution of monomers with a “good” porogen solvating the polymer chains. High dilution and solvation of the growing poly(DVB) chains promote the prolongation of the polymer chains rather than their interconnection by crosslinking. Consequently, when the polymer gel density reaches the point where syneresis starts, the polymer network is geometrically too extensive to be broken up into precipitating entities and, instead, porogen droplets are formed within the continuous polymer gel. The pore geometry created by microsyneresis offers high surface area in wide mesopores and hence, high capacity for supporting functional groups or reactions with much better accessibility than narrow pores between polymer microspheres produced by macrosyneresis in conventional styrenic polymer supports. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 774–781 相似文献
2.
We characterize cardinalsκ such that 2λ = 2κ wheneverκ ≦λ < 2κ using ideals in small algebras of sets satisfying certain completeness and saturation conditions.
Research of this author was supported by an NSF Grant. 相似文献
3.
4.
Guido Momerency Karel Van Cauwenberghe Ernst A. De Bruijn Allan T. Van Oosterom Martin S. Highley Peter G. Harper 《Journal of separation science》1994,17(9):655-661
A method is described for the determination of the antitumor agent iphosphamide and seven of its metabolites in the plasma of cancer patients by multiple ion monitoring (MIM) GC-MS, mainly using the electron capture chemical ionization mode, of stable methyl and/or trifluoroacetyl derivatives. The metabolites determined were 2- and 3-dechloroethyliphosphamide, 4-ketoiphosphamide, carboxyiphosphamide, iphosphamide mustard, and two previously undetected metabolites, chloroethylamine and 1,3-oxazolidine-2-one. The isolation of the acidic and neutral metabolites was performed by solid phase extraction on to C18 adsorbent at pH 4. The weakly acidic iphosphamide mustard, isolated under these conditions with a yield of ca 50%, was measured as a stable methyltrifluoroacetyl derivative, in contrast to the corresponding phosphoramide mustard of the isomer cyclophosphamide which decomposes during derivatization. Chloroethylamine and 1,3-oxazolidine-2-one were isolated with high yield by liquid extraction with ethyl acetate at pH 10. Selective measurement of several metabolite derivatives with similar retention times was performed by multiple ion monitoring MS of specific ion masses, using a methyl phenyl siloxane capillary column previously employed in the study of cyclophosphamide metabolites. Quantitation of metabolites in patient plasma samples could be performed in the concentration range 3 ng to 20 μg per ml of original plasma. 相似文献
5.
František Toman Ludvík Beneš 《Journal of inclusion phenomena and macrocyclic chemistry》2007,59(3-4):231-236
Differential molar adsorption enthalpies (DMAE) were determined by gas chromatographic measurements of specific retention
volume of vapors on the surface of two forms of Mg–Al hydrotalcite. A linear dependence of the DMAE on the number of the carbon
atoms in hydrocarbons was observed for both form of hydrotalcite. The dependence of the differential molar adsorption enthalpies
on the number of chlorine atoms in organic molecules is discussed. A linear dependence of DMAE on the molecular weight of
chloroderivatives of methane and ethylene on the basic form in an order monochloromethane < dichloromethane < trichloromethane
or vinylidene chloride < 1,1-dichloroethylene < trichloroethylene was found. 相似文献
6.
7.
Jan Andres Karel Pastor Pavla Šnyrychová 《Journal of Fixed Point Theory and Applications》2007,2(1):153-170
A multivalued version of Sharkovskiĭ’s theorem is formulated for M-maps on linear continua and, more generally, for triangular M-maps on a Cartesian product of linear continua. This improves the main result of [AP1] in the sense that our multivalued
analogue holds with at most two exceptions. A further specification requires some additional restrictions. For instance, 3-
orbits of m-maps imply the existence of k-orbits for all
k ? \mathbbNk \in {\mathbb{N}}
, except possibly for
k ?k \in
{4, 6}. It is also shown that, on every connected linearly ordered topological space, an M-map with orbits of all periods can always be constructed. This demonstrates that Baldwin’s classification of linear continua
in terms of admissible periods [Ba] is useless for multivalued maps. 相似文献
8.
Spectra of isobutylene with SnCl4 were studied at the temperature of 113°K in the dark and under illumination. Radical-cations of isobutylene are formed by irradiation of the isobutylene–SnCl4 mixture in n-heptane substantially more slowly than in the isobutylene–TiCl4 mixture. Polymerization of isobutylene occurs after increasing the temperature up to the melting point of this mixture. The yield of polymer depends on the duration of preirradiation, while the molecular weight of polyisobutylene (M η) does not depend on the preirradiation of reaction mixture. 相似文献
9.
Jeremy P. Scott Deborah C. Hammond Elizabeth M. Beck Karel M.J. Brands Antony J. Davies Ulf-H. Dolling Derek J. Kennedy 《Tetrahedron letters》2004,45(17):3345-3348
The efficient preparation of 4-aryl-4-phenylsulfonyl cyclohexanones, containing a quaternary sulfone-bearing carbon centre, is described. Their synthesis proceeds in 38-78% overall yield by way of three steps: (i) sulfinate alkylation; (ii) methylenation; and (iii) regioselective Diels-Alder condensation with 2-trimethylsiloxybutadiene. The scope and limitations of the one-pot Mannich-type methylenation described were examined. 相似文献
10.
Karel Macek 《Trends in analytical chemistry : TRAC》1981,1(2):35-39
Chromatographic methods are the most popular ones used in biomedical sciences. However, their full potential as investigative and diagnostic tools in this important area is only now being realized. 相似文献