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排序方式: 共有67条查询结果,搜索用时 718 毫秒
1.
Murthy MB Daya Sagar BS Patil RL 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2003,59(6):1277-1280
The electronic absorption spectra of eight substituted acetic acids have been measured at room temperature in several solvents. The ground state dipole moments are evaluated experimentally for these molecules. These ground state values are used in conjunction with the spectral results to evaluate their first electronically excited state dipole moments. For all the molecules investigated here the dipole moments in the excited state are higher than their ground state values. 相似文献
2.
The use of grape tissue as a source of catalase for the determination of hydrogen peroxide is reported. A slice of grape tissue attached to the membrane of a Clark-type oxgen sensor was used to monitor the oxidation of hydrogen peroxide by catalase. At the steady state, the sensor responds linearly to hydrogen peroxide in the concentration range 1 × 10?5–5 × 10?4 M. The response time (T90) was of the order of 1 min for this sensor. No interference was observed from ethanol, amino acids, glucose and lactic acid. The long-term stability of the grape tissue sensor was much better than previously reported immobilized enzyme and liver tissue-based hydrogen peroxide sensors. 相似文献
3.
A novel azophenol-quinazoline dyad 1 has been designed, synthesized and demonstrated as an efficient reversible multichannel pH indicator through distinct signalling in aqueous media. Owing to the competence between highly fluorescent quinazoline moiety and a well known fluorescence quencher diazo group, dyad 1 is moderately fluorescent in nature. Under acidic conditions 1 displays diverse fluorogenic changes (blue emission at pH 4.25; green at pH 1.80) while under basic condition (pH 11.80) chromogenic changes were observed. 相似文献
4.
We study experimentally statistical properties of the opening times of knots in vertically vibrated granular chains. Our measurements are in good qualitative and quantitative agreement with a theoretical model involving three random walks interacting via hard-core exclusion in one spatial dimension. In particular, the knot survival probability follows a universal scaling function which is independent of the chain length, with a corresponding diffusive characteristic time scale. Both the large-exit-time and the small-exit-time tails of the distribution are suppressed exponentially, and the corresponding decay coefficients are in excellent agreement with theoretical values. 相似文献
5.
Yao Koutsawa El Mostafa Daya 《International Journal of Solids and Structures》2007,44(25-26):8735-8750
Static behavior and free vibration analysis of laminated glass beam on viscoelastic supports are performed. For the static case, an analytical way is developed for analyzing and optimization of laminated glass beam with general restraints at the boundaries. In the case of free linear vibrations, the modal properties of the glass are determined using a finite element method which is a powerful tool in the design of support damping treatment of a sandwich glass for passive vibration control. 相似文献
6.
Nearly repetitive structures can present at least two kinds of vibration modes: localized modes and modulated ones. In this Note, the multiple scale method is applied to characterize a packet of modulated modes. In this respect, only small size problems are to be solved: periodic problems posed on a few basic cells and amplitude equations, which define a sort of homogenized model for this type of modes. It is established that the influence of the non-repetitive part of the structure is accounted by a boundary condition. To cite this article: E.M. Daya et al., C. R. Mecanique 331 (2003). 相似文献
7.
El Mostafa Daya Bouazza Braikat Noureddine Damil Michel Potier-Ferry 《Comptes Rendus Mecanique》2002,330(5):333-338
By homogenization theory, one can predict the vibrations of long repetitive structures in the low frequency range. Beyond this range, many modes have a modulated shape. Based on a multiple scale analysis, a continuum model is presented, that is able to account for this class of modes. This model involves a real coefficient that can be computed from the finite element resolution of problems defined on a few basic cells. An application in 2D elasticity is presented. To cite this article: E.M. Daya et al., C. R. Mecanique 330 (2002) 333–338. 相似文献
8.
Pandey R Kumar P Singh AK Shahid M Li PZ Singh SK Xu Q Misra A Pandey DS 《Inorganic chemistry》2011,50(8):3189-3197
Binuclear zinc(II) and copper(II) complexes based on a new Schiff base ligand N,N'-bis(2-hydroxybenzilidene)-2,4,6-trimethylbenzene-1,3-diamine (H(2)L) have been synthesized. The ligand H(2)L and complexes under investigation have been characterized by elemental analyses, spectral (FT-IR, (1)H, (13)C NMR, ESI-MS, electronic absorption, emission), and electrochemical studies. The structures of H(2)L and complexes [{Zn(C(23)H(18)N(2)O(2))}(2)] (1) and [{Cu(C(23)H(18)N(2)O(2))}(2)]·H(2)O (2) have been determined crystallographically. Selective "On-Off-On" switching behavior of the fluorescent complex 1 has been studied. The fluorescence intensity of 1 quenches (turns-off) upon addition of Cu(2+), while enhances (turns-on) in the presence of Ag(+) ions. The mechanisms of "On-Off-On" signaling have been supported by (1)H NMR, ESI-MS, electronic absorption, and emission spectral studies. Job's plot analysis supported 1:1 and 1:2 stoichiometries for Cu(2+) and Ag(+) ions, respectively. Association and quenching constants have been estimated by the Benesi-Hildebrand method and Stern-Volmer plot. Moreover, 1 mimics a molecular keypad lock that follows correct chemical input order to give maximum output signal. 相似文献
9.
Gautam Pankaj Sahu Daya Ram Dixit Avinash Som Tanmoy 《Journal of Optimization Theory and Applications》2021,190(2):491-523
Journal of Optimization Theory and Applications - In this paper, the first-order forward–backward–half forward dynamical systems associated with the inclusion problem consisting of... 相似文献
10.
Focusing of electromagnetic waves into a uniaxial crystal 总被引:1,自引:0,他引:1
We derive integral representations suitable for studying the focusing of electromagnetic waves through a plane interface into a uniaxial crystal. To that end we start from existing exact solutions for the transmitted fields due to an arbitrary three-dimensional (3D) wave that is incident upon a plane interface separating two uniaxial crystals with arbitrary orientation of the optical axis in each medium. Then we specialize to the case in which the medium of the incident wave is isotropic and derive explicit expressions for the dyadic Green's functions associated with the transmitted fields as well as integral representations suitable for asymptotic analysis and efficient numerical evaluation. Relevant integral representations for focused 3D electromagnetic waves are also given. Next we consider the special case in which (i) the incident field is a two-dimensional (2D) TM wave and (ii) the optical axis in the crystal lies in the plane of incidence, implying that we have a 2D vectorial problem, and derive dyadic Green's functions, integral representations suitable for asymptotic and numerical treatment, and integral representations for focused TM fields. Numerical results for focused 2D TM fields based on these integral representations as well as corresponding experimental results will be presented in forthcoming papers. 相似文献