铬与健康

对铬与人体健康的关系进行了综述，主要内容包括：三价铬的作用、六价铬的作用和环境中的铬。     

Synthesis and Structure of(NH4)_2 [V2O_4(OCH_2COO)_2]

ＳｙｎｔｈｅｓｉｓａｎｄＳｔｒｕｃｔｕｒｅｏｆ（ＮＨ４）２［Ｖ２Ｏ４（ＯＣＨ２ＣＯＯ）２］ＺＨＯＵＺｈａｏ－ｈｕｉ，ＷＡＮＧＪｉｎｚｈｉ，ＷＡＮＨｕｉ－ｌｉｎａｎｄＴＳＡｌＫｈｉ－ｒｕｉ（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｓｔｒｙ，ＸｉａｍｅｎＵｎｉ...     

Synthesis,spectroscopic characterisation and structure of the first chiral heteroleptic bis(phthalocyaninato) rare earth complexes

Treatment of MIII(Pc)(acac) (M = Sm, Eu, Gd; Pc = phthalocyaninate; acac = acetylacetonate), generated in situ, with 3-(3-pentyloxy)phthalonitrile in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in n-pentanol affords racemic mixtures of the chiral double-deckers MIII(Pc)[Pc(OC5H11)4] [Pc(OC5H11)4 = 1,8,15,22-tetrakis(3-pentyloxy)phthalocyaninate], which have been spectroscopically and structurally characterised.     

石墨氮化碳光催化剂的制备及其改性研究进展

石墨氮化碳(g-C3 N4)是一种可见光响应的非金属半导体材料.g-C3 N4具有廉价易得,物理化学性质稳定,无毒无污染等优点,在环境净化和能源催化领域具有良好的应用前景.然而,体相g-C3 N4存在比表面积小,可见光吸收能力差,光生电子和空穴复合效率高等缺点,从而严重限制了其在实际中的应用.本文在概述了g-C3 N4的结构、特性及制备方法的基础上,着重归纳了g-C3 N4的改性方法,其中包括元素掺杂、形貌调控、贵金属沉积等改性手段的研究进展.最后,本文探讨了g-C3 N4光催化反应机理,以及对g-C3 N4在水体环境净化领域的研究进行了展望.     

Burst synchronization transitions in a neuronal network of subnetworks

In this paper, the transitions of burst synchronization are explored in a neuronal network consisting of subnetworks. The studied network is composed of electrically coupled bursting Hindmarsh-Rose neurons. Numerical results show that two types of burst synchronization transitions can be induced not only by the variations of intra- and intercoupling strengths but also by changing the probability of random links between different subnetworks and the number of subnetworks. Furthermore, we find that the underlying mechanisms for these two bursting synchronization transitions are different: one is due to the change of spike numbers per burst, while the other is caused by the change of the bursting type. Considering that changes in the coupling strengths and neuronal connections are closely interlaced with brain plasticity, the presented results could have important implications for the role of the brain plasticity in some functional behavior that are associated with synchronization.     

正规Cayley图

综述了自１９９０年以来１２－传递图研究的一些新成果，正规Ｃａｙｌｅｙ图的相关结论。     

线性系统模态控制及其时滞补偿

对线性系统模态控制及其时滞补偿进行研究。模态控制分控制全部模态和控制有限模态两种情况 ,时滞补偿采用移相补偿。最后结合算例对两种控制模态下的控制效果和控制有限模态时的时滞补偿进行了数值计算和结果对比     

Twist Character of the Fourth Order Resonant Periodic Solution

In this paper, we will give, for the periodic solution of the scalar Newtonian equation, some twist criteria which can deal with the fourth order resonant case. These are established by developing some new estimates for the periodic solution of the Ermakov–Pinney equation, for which the associated Hill equation may across the fourth order resonances. As a concrete example, the least amplitude periodic solution of the forced pendulum is proved to be twist even when the frequency acroses the fourth order resonances. This improves the results in Lei et al. (2003). Twist character of the least amplitude periodic solution of the forced pendulm. SIAM J. Math. Anal. 35, 844–867.Dedicated to Professor Shui-Nee Chow on the occasion of his 60th birthday.     

具有连续变量的非线性偏差分方程振动准则

本文研究具有连续变量的非线性变系数偏差分方程A(x+a,y) +Q(x,y) A(x,y+a) - R(x,y) A(x,y) +∑mi=1hi(x,y,A(x-σi,y-τi) ) =0其中 ,Q(x,y) ,R(x,y)∈ C(R+ × R+ - { 0 } ) ,hi(x,y,u)关于 u单调非减 ,且 hi(x,y,u) pi(x,y) u,(u>0 ) ;hi(x,y,u) pi(x,y) u,(u<0 )其中 ,pi(x,y)∈ C(R+ × R+ ,R+ - { 0 } ) ,i=1,2 ,… ,m,a,σi,τi∈ R+ ,得到了保证方程的所有解都具有振动生的若干充分条件     

Utilization of 3'-carboxy-containing tyrosine derivatives as a new class of phosphotyrosyl mimetics in the preparation of novel non-phosphorylated cyclic peptide inhibitors of the Grb2-SH2 domain

A new class of phosphotyrosyl (pTyr) mimetics, distinct from the conventional pTyr mimetic design of adding non-hydrolyzable acidic functionalities to the 4'-position of phenylalanine, was created by introducing carboxy-containing groups to the 3'-position of tyrosine. The effect of the chain length of the carboxy substituent was examined. Reported herein is the chiral pool synthesis of the new pTyr mimetics, and their first use in a novel non-phosphorylated Grb2-SH2 domain binding motif with the 5-amino-acid sequence Xx1-Leu-(3'-substituted-Tyr)-Ac6c-Asn. The highest affinity was exhibited by the 3-L-(2-carboxyethyl)tyrosine-containing sulfoxide-cyclized peptide , with an IC50 = 1.1 microM, providing a promising new template for further development of potent Grb2-SH2 domain inhibitors with reduced charge and peptidic nature, but improved selectivity and bioavailability.