The Stability of Mononuclear and Binuclear Complexes of Silver(I) with Thiosemicarbazide in an Aqueous Solution

Moscow University Chemistry Bulletin - The complexation process of silver(I) ions with thiosemicarbazide (Tsc) in a wide range of concentrations of silver(I) and thiosemicarbazide at T =...     

Deuteron electromagnetic form factors and tensor polarization observables in the framework of the hard-wall AdS/QCD model

We study the electromagnetic form factors and tensor polarization observables of the deuteron in the framework of the hard-wall AdS/QCD model. We find a profile function for the bulk twist \begin{document}$\tau=6$\end{document} vector field, which describes the deuteron on the boundary and fix the infrared boundary cut-off of AdS space in accordance with the ground state mass of the deuteron. We obtain the deuteron charge monopole, quadrupole, and magnetic dipole form factors and tensor polarization observables from the bulk Lagrangians for the deuteron and photon field interactions. We plot the momentum transfer dependence of the form factors and tensor polarization observables and compare our numerical results with those in the soft-wall model and experimental data.     

Ultrasound-assisted dynamic extraction of valuable compounds from aromatic plants and flowers as compared with steam distillation and superheated liquid extraction

A method for the extraction of valuable compounds from plants and flowers (viz. laurel, rosemary, thyme, oregano and tuberose) is proposed. The dynamic approach allows go-and-backward circulation of the extractant (ethanol) through the solid sample subjected to the action of an ultrasound probe (thus reducing sample amount and avoiding overpressure). A multivariate optimisation study and application of the optimum values of the variables to kinetics studies show that 10 min is sufficient to obtain extraction efficiencies that greatly surpass those provided by steam distillation for essential oils or superheated liquid extraction for these oils and other valuable compounds, with lower costs and higher quality of the extract. The extraction time of the proposed method is 176–165 min shorter than steam distillation and 31–20 min shorter than superheated liquid extraction, depending on the target compound.     

Structural Bases for Hesperetin Derivatives: Inhibition of Protein Tyrosine Phosphatase 1B,Kinetics Mechanism and Molecular Docking Study

In the present study, we investigated the structure-activity relationship of naturally occurring hesperetin derivatives, as well as the effects of their glycosylation on the inhibition of diabetes-related enzyme systems, protein tyrosine phosphatase 1B (PTP1B) and α-glycosidase. Among the tested hesperetin derivatives, hesperetin 5-O-glucoside, a single-glucose-containing flavanone glycoside, significantly inhibited PTP1B with an IC₅₀ value of 37.14 ± 0.07 µM. Hesperetin, which lacks a sugar molecule, was the weakest inhibitor compared to the reference compound, ursolic acid (IC₅₀ = 9.65 ± 0.01 µM). The most active flavanone hesperetin 5-O-glucoside suggested that the position of a sugar moiety at the C-5-position influences the PTP1B inhibition. It was observed that the ability to inhibit PTP1B is dependent on the nature, position, and number of sugar moieties in the flavonoid structure, as well as conjugation. In the kinetic study of PTP1B enzyme inhibition, hesperetin 5-O-glucoside led to mixed-type inhibition. Molecular docking studies revealed that hesperetin 5-O-glucoside had a higher binding affinity with key amino residues, suggesting that this molecule best fits the PTP1B allosteric site cavity. The data reported here support hesperetin 5-O-glucoside as a hit for the design of more potent and selective inhibitors against PTP1B in the search for a new anti-diabetic treatment.     

Study of Silver(I) Complex Formation with Some Thiourea Derivatives in Aqueous Solution

Russian Journal of General Chemistry - The equilibrium processes of the formation of mononuclear and some binuclear silver(I) complexes with thiourea, N-acetylthiourea, thiosemicarbazide,...     

Gas-chromatographic fatty-acid fingerprints and partial least squares modeling as a basis for the simultaneous determination of edible oil mixtures

Partial least squares modeling and gas-chromatographic fatty-acid fingerprints are reported as a method for the simultaneous determination of cottonseed, olive, soybean and sunflower edible oil mixtures. In this work, two sets of three- and four-component combinations of oils were prepared, hydrolyzed and the obtained free fatty acids analyzed by gas chromatography (GC) without any further derivatization. The normalized percentages of the myristic (14:0), palmitic (16:0), palmitoleic (16:1), stearic (18:0), oleic (18:1), linoleic (18:2) and linolenic (18:3) acids were chromatographically measured in samples and used for constructing calibration matrix. The cross-validation method was used to select the number of factors and the proposed methods were validated by using two sets of synthetic oil mixture samples. The relative standard error for each oil in mixture samples was less than 10%. This approach allows determining possible adulteration in each of the four edible oils.     

Nucleus-acoustic solitary waves in white dwarfs

The formation of nucleus-acoustic solitary waves (NASWs), and their basic properties in white dwarfs containing non-relativistically or ultra-relativistically degenerate electrons, non-relativistically degenerate light nuclei, and stationary heavy nuclei have been theoretically investigated. The reductive perturbation method, which is valid for small but finite amplitude NASWs, is used. The NASWs are, in fact, associated with the nucleus acoustic (NA) waves in which the inertia is provided by the light nuclei, and restoring force is provided by the degenerate pressure of electrons. On the other hand, stationary heavy nuclei maintain the background charge neutrality condition. It has been found that the presence of the heavy nuclei significantly modify the basic features (polarity, amplitude, width, and speed) of the NASWs. The basic properties are also found to be significantly modified by the effects of ultra-relativistically degenerate electrons and relative number densities of light and heavy nuclei. The implications of our results in white dwarfs are pinpointed.     

Ion-Acoustic Shock Waves in Nonextensive Multi-Ion Plasmas

The nonlinear propagation of ion-acoustic (IA) shock waves (SHWs) in a nonextensive multi-ion plasma system (consisting of inertial positive light ions as well as negative heavy ions, noninertial nonextensive electrons and positrons) has been studied. The reductive perturbation technique has been employed to derive the Burgers equation. The basic properties (polarity, amplitude, width, etc.) of the IA SHWs are found to be significantly modified by the effects of nonextensivity of electrons and positrons, ion kinematic viscosity, temperature ratio of electrons and positrons, etc. It has been observed that SHWs with positive and negative potential are formed depending on the plasma parameters. The findings of our results obtained from this theoretical investigation may be useful in understanding the characteristics of IA SHWs both in laboratory and space plasmas.     

Determination of attenuation coefficients of single mode optical fiber standards to be used in OTDR calibrations

The subject of this paper is the determination of attenuation coefficients of single mode optical fiber standards used in both loss and distance scales calibrations of OTDR instruments by applying “cut-back” method, and “loop transit time” measurements. In cut-back measurements a modified radiometer with InGaAs having 5 mm diameter active area, cooled to 77 K, was constructed and used. To derive attenuation coefficients after the completion of cut-back measurements, the loop transit time measurements were performed for standard fibers. Total expanded uncertainty was calculated as 3.30×10^-3 for determination of attenuation coefficients.