ESI‐MS/MS of expanded porphyrins: a look into their structure and aromaticity

Electrospray mass spectrometry/mass spectrometry was used to investigate the gas‐phase properties of protonated expanded porphyrins, in order to correlate those with their structure and conformation. We have selected five expanded meso‐pentafluorophenyl porphyrins, respectively, a pair of oxidized/reduced fused pentaphyrins (22 and 24 π electrons), a pair of oxidized/reduced regular hexaphyrins (26 and 28 π electrons) and a regular doubly N‐fused hexaphyrin (28 π electrons). The gas‐phase behavior of the protonated species of oxidized and reduced expanded porphyrins is different. The oxidized species (aromatic Hückel systems) fragment more extensively, mainly by the loss of two HF molecules. The reduced species (Möbius aromatic or Möbius‐like aromatic systems) fragment less than their oxidized counterparts because of their increased flexibility. The protonated regular doubly fused hexaphyrin (non‐aromatic Hückel system) shows the least fragmentation even at higher collision energies. In general, cyclization through losses of HF molecules decreases from the aromatic Hückel systems to Möbius aromatic or Möbius‐like aromatic systems to non‐aromatic Hückel systems and is related to an increase in conformational distortion. Copyright © 2016 John Wiley & Sons, Ltd.     

Observation of long-lived vortex aggregates in rapidly rotating Bose-Einstein condensates

We study the formation of large vortex aggregates in a rapidly rotating dilute-gas Bose-Einstein condensate. When we remove atoms from the rotating condensate with a tightly focused, resonant laser, the density can be locally suppressed, while fast circulation of a ring-shaped superflow around the area of suppressed density is maintained. Thus a giant vortex core comprising 7 to 60 phase singularities is formed. The giant core is only metastable, and it will refill with distinguishable single vortices after many rotation cycles. The surprisingly long lifetime of the core can be attributed to the influence of strong Coriolis forces in the condensate. In addition we have been able to follow the precession of off-center giant vortices for more than 20 cycles.     

Vortex precession in Bose-Einstein condensates: observations with filled and empty cores

We have observed and characterized the dynamics of singly quantized vortices in dilute-gas Bose-Einstein condensates. Our condensates are produced in a superposition of two internal states of 87Rb, with one state supporting a vortex and the other filling the vortex core. Subsequently, the state filling the core can be partially or completely removed, reducing the radius of the core by as much as a factor of 13, all the way down to its bare value of the healing length. The corresponding superfluid rotation rates, evaluated at the core radius, vary by a factor of 150, but the precession frequency of the vortex core about the condensate axis changes by only a factor of 2.     

Study of DyFe12−xMx compounds by57Fe and161Dy Mössbauer spectroscopy

DyFe_12?xM_x (M=Si,Ti,Cr) were studied with⁵⁷Fe and¹⁶¹Dy Mössbauer spectroscopy. The deduced coupling constants J_RFe of these compounds are about equal. It is found that Si is substituting one particular Fe-site, while Cr is substituting Fe randomly. In DyFe₁₀Si₂ two Fe-sites favour a c-axis anisotropy, while the third one favours the basal plane.