The ductile fracture of polycarbonate

The fracture of a known ductile polymer (polycarbonate) is investigated. It is shown that polycarbonate obeys the Dugdale model of ductile yielding by comparing measured plastic-zone sizes and displacements to the theoretical predictions. Strain-energy release rates are calculated and the critical value is shown to be one or two orders of magnitude higher than critical values for brittle polymers. Photoelastic photographs of the fracture process are presented and it is shown that the photoelastic effect definitely enhances the definition of the yield zone. Microscopic photoelastic photographs are also presented which are used to give a new interpretation to the photoplastic effect. Finally, suggestions for future work are presented.     

Depletion at solid/liquid interfaces: flowing hexadecane on functionalized surfaces

We present a neutron reflectivity study on interfaces in contact with flowing hexadecane, which is known to exhibit surface slip on functionalized solid surfaces. The single crystalline silicon substrates were either chemically cleaned Si(100) or Si(100) coated by octadecyl-trichlorosilane (OTS), which resulted in different interfacial energies. The liquid was sheared in situ and changes in reflectivity profiles were compared to the static case. For the OTS surface, the temperature dependence was also recorded. For both types of interfaces, density depletion of the liquid at the interface was observed. In the case of the bare Si substrate, shear load altered the structure of the depletion layer, whereas for the OTS covered surface no effect of shear was observed. Possible links between the depletion layer and surface slip are discussed. The results show that, in contrast to water, for hexadecane the enhancement of the depletion layer with temperature and interfacial energy reduces the amount of slip. Thus a density depletion cannot be the origin of surface slip in this system.     

Probing fission time scales with neutrons and GDR gamma rays

The time scales for nuclear fission have been explored using both pre-and postfission neutrons and GDR gamma rays. Four systems were investigated: 133-MeV ¹⁶O + ¹⁷⁶Yb and ²⁰⁸Pb and 104-MeV ⁴He + ¹⁸⁸Os and ²⁰⁹Bi. Fission fragments were measured in coincidence with PPACs. The neutrons were detected using eight detectors from the DEMON array, while gamma rays were measured using the US BaF2 array. The pre-and postfission gamma rays were determined using moving source fits parallel and perpendicular to the fission fragment emission directions. The time scales for fission for the neutrons were determined using the neutron clock technique. The gamma-ray data were fitted using a statistical model calculation based on the code CASCADE. The results of the fits from both data types were used to extract nuclear friction coefficients, γ, and fission time scales. The γ values ranged from 7 to 20, while the fission times were (31–105)×10^?21 s.     

Effective interactions for 208Pb + p reactions

RPA hole-particle wave functions for the lowest 2⁺ and 3^? states in ²⁰⁸Pb were used to test the validity of effective nucleon-nucleon interactions for (p, p') excitations. Excellent agreement with experiment was obtained for the long-range part of the Hamada-Johnston S-state potential. Equally good agreement was found for the elastic scattering from ²⁰⁸Pb and the (p, n) transition to the analog state. It was found to be important to include an imaginary part in the interaction. The transitions to the two excited states of ²⁰⁸Pb were found to be almost pure isoscalar, but the transitions are dominated by the neutron excitations.     

Classical microscopic calculation of fast heavy-ion collisions

We consider heavy-ion collisions with beam energies of a few hundred MeV/nucleon, because such collisions seem favorable for producing compressed nuclear matter. As an alternative to hydrodynamic ways of calculating such collisions, we are investigating a microscopic, rapid (and therefore economical) simulation method. There are two simplifications basic to this method: (i) using classical particle kinematics, and (ii) taking nucleonnucleon interactions into account via cross sections rather than explicit forces. Some other simplifications, concerning nuclear binding etc., are presently crude but will be improved. Even at normal density, nuclear matter is not so dilute; therefore our calculations show some sensitivity to details of the mechanism assume for nucleon-nucleon scattering. For head-on collision of two mass-235 nuclei, our present calculations yield maximum densities between 2 and 3 times that of normal nuclear matter.     

Copper and iron interactions with angiotensin-converting enzyme inhibitors. A study by fast-atom bombardment tandem mass spectrometry

Fast atom bombardment, combined with high-energy collision-induced tandem mass spectrometry, has been used to investigate gas-phase metal-ion interactions with captopril, enalaprilat and lisinopril, all angiotensin-converting enzyme inhibitors.Suggestions for the location of metal-binding sites are presented. For captopril, metal binding occurs most likely at both the sulphur and the nitrogen atom. For enalaprilat and lisinopril, binding preferably occurs at the amine nitrogen. Copyright 1999 John Wiley & Sons, Ltd.     

ESI‐MS/MS of expanded porphyrins: a look into their structure and aromaticity

Electrospray mass spectrometry/mass spectrometry was used to investigate the gas‐phase properties of protonated expanded porphyrins, in order to correlate those with their structure and conformation. We have selected five expanded meso‐pentafluorophenyl porphyrins, respectively, a pair of oxidized/reduced fused pentaphyrins (22 and 24 π electrons), a pair of oxidized/reduced regular hexaphyrins (26 and 28 π electrons) and a regular doubly N‐fused hexaphyrin (28 π electrons). The gas‐phase behavior of the protonated species of oxidized and reduced expanded porphyrins is different. The oxidized species (aromatic Hückel systems) fragment more extensively, mainly by the loss of two HF molecules. The reduced species (Möbius aromatic or Möbius‐like aromatic systems) fragment less than their oxidized counterparts because of their increased flexibility. The protonated regular doubly fused hexaphyrin (non‐aromatic Hückel system) shows the least fragmentation even at higher collision energies. In general, cyclization through losses of HF molecules decreases from the aromatic Hückel systems to Möbius aromatic or Möbius‐like aromatic systems to non‐aromatic Hückel systems and is related to an increase in conformational distortion. Copyright © 2016 John Wiley & Sons, Ltd.     

Multistep scattering in the 160 MeV208Pb(α, α′) reaction

New experimental data has been obtained for the²⁰⁸Pb(α, α′) reaction induced by 160 MeV alpha particles, for inelastic scattering to forward angles. We use these data to investigate the applicability of the multistep scattering theory of Feshbach, Kerman, and Koonin for describing this reaction. The mechanism we study, following the work of Gadioli et al. [1], is of the incident alpha particle remaining intact throughout the scattering process, exciting nucleon particle-hole pairs through multistep process. We conclude that this mechanism, combined with compound nucleus decay at low emission energies, can account for much of the observed data. However, there are indications that other processes also contribute at energies above the compound nucleus emission regime, and we outline future theoretical analyses that are needed.