全文获取类型
收费全文 | 65篇 |
免费 | 3篇 |
国内免费 | 2篇 |
专业分类
化学 | 33篇 |
力学 | 9篇 |
数学 | 4篇 |
物理学 | 24篇 |
出版年
2022年 | 3篇 |
2021年 | 4篇 |
2019年 | 2篇 |
2018年 | 4篇 |
2016年 | 1篇 |
2014年 | 2篇 |
2013年 | 10篇 |
2012年 | 6篇 |
2011年 | 5篇 |
2010年 | 4篇 |
2008年 | 5篇 |
2007年 | 1篇 |
2005年 | 2篇 |
2003年 | 2篇 |
2002年 | 1篇 |
2001年 | 1篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1987年 | 3篇 |
1985年 | 1篇 |
1984年 | 1篇 |
排序方式: 共有70条查询结果,搜索用时 15 毫秒
1.
Nanocrystalline TiO2-HClO4,as newly reported catalyst,has been used as an efficient and reusable catalyst for the chemoselective N-Boc protection of amines.The clean,mild acidity condition, quantitative yields of products,short reaction time and low reaction temperature are attractive features of this reaction.In practice,this method is a combination of a satisfactory synthesis and more significantly easy product isolation and purification. 相似文献
2.
Ruthenium‐Catalyzed Reductive Methylation of Imines Using Carbon Dioxide and Molecular Hydrogen 下载免费PDF全文
Dr. Kassem Beydoun Ghazi Ghattas Katharina Thenert Prof. Dr. Jürgen Klankermayer Prof. Dr. Walter Leitner 《Angewandte Chemie (International ed. in English)》2014,53(41):11010-11014
The use of the well‐defined [Ru(triphos)(tmm)] catalyst, CO2 as C1 source, and H2 as reducing agent enabled the reductive methylation of isolated imines, as well as the direct coupling of amines with aldehydes and the subsequent reductive methylation of the in situ formed imines. The method, which afforded the corresponding N‐methyl amines in very good to excellent yields, was also used for the preparation of the antifungal agent butenafine in one step with no apparent waste, thus increasing the atom efficiency of its synthesis. 相似文献
3.
Hikmat S. Hilal Ghazi Y.M. Al-Nour Ahed Zyoud Muath H. Helal Iyad Saadeddin 《Solid State Sciences》2010,12(4):578-586
In search for safe techniques to manage waste pharmaceutical compounds drained in water, solar-driven degradation of phenazopyridine (a model drug) was investigated in aqueous media using different ZnO-based catalyst systems. Naked ZnO, CdS-sensitized ZnO (ZnO/CdS) and activated carbon-supported ZnO (AC/ZnO) have been studied. Both naked ZnO and AC/ZnO were highly efficient in mineralizing phenazopyridine, reaching complete removal in ~50 min, with AC/ZnO having the higher edge. The ZnO/CdS system showed lower efficiency, due to screening of light by CdS. Moreover, the tendency of CdS to leach out Cd2+ ions discouraged the use of CdS as sensitizer in this work. In both ZnO and AC/ZnO systems, the photo-degradation reaction was induced by the UV tail of the solar light. The visible region, with wavelength longer than 400 nm, failed to induce photo-degradation. The reaction was faster with higher catalyst loading, until a maximum efficiency was reached at a certain concentration. The rate of reaction increased with higher drug concentrations up to a certain limit. The effect of pH value was studied, and the catalysts showed highest efficiencies at pH close to 7. Stability of ZnO to degradation was studied. Both catalyst systems showed lowered efficiencies on recovery and reuse. The results suggest that complete mineralization of waste drugs, commonly dumped in sewage water, with direct solar light is a potentially feasible strategy using the AC/ZnO catalyst. 相似文献
4.
Bulk superconducting samples of type Tl0.5Pb0.5Sr1.6Ba0.4CaCu2−x
Ru
x
O7−δ, (Tl, Pb)/Sr-1212, with 0.0 ≤ x ≤ 0.525 were prepared by the conventional one-step solid-state reaction technique. The prepared samples were investigated
using X-ray powder diffraction, electrical resistivity and electron paramagnetic resonance (EPR) measurements. Enhancement
of the phase formation, superconducting transition temperature T
c and hole carriers concentration P was observed up to x = 0.075. For x > 0.075, a reverse trend was observed. EPR spectra were measured at different temperatures (120–290 K) for all prepared samples.
The number of spins N participating in the resonance and the paramagnetic susceptibility χ were calculated as a function of both Ru-content and
temperature. N and χ increased as the Ru-content increased. A linear relationship between logN and 1/T was established, from which the activation energy E
a was calculated as a function of the Ru-content. The temperature dependence of χ was fitted according to Curie–Weiss type
of magnetic behavior. Curie constant C, Curie temperature θ, the effective magnetic moment μ and the electronic specific heat γ were estimated as a function of the Ru-content. 相似文献
5.
Density functional calculations have been carried out to obtain low energy equilibrium geometries of anionic and neutral sodium clusters over a wide range of sizes 40 ≤ N ≤ 147, where N is the number of atoms. An exhaustive search for the low energy equilibrium geometries has been carried out. The density of states of the lowest energy geometries are compared with the experimental photoelectron spectra (Huber et al 2009 Phys. Rev. B 80 235425; Kostko et al 2007 Phys. Rev. Lett.98 043401) for N > 41. The agreement between theory and experiment is good for almost all the clusters and the changes in the spectrum with size correlate very well with the changes in the shapes as observed in the evolutionary trend of the ground state geometries. 相似文献
6.
7.
Abderrahim Aslimani Imad El Ghazi Mohamed El Kadiri Sabah Haddad 《Annali dell'Universita di Ferrara》2018,64(1):25-46
We study the existence and the regularity of the biharmonic Green kernel in a Brelot biharmonic space whose associated harmonic spaces have Green kernels. We show by some examples that this kernel does not always exist. We then introduce and study the adjoint of the given biharmonic space. This study was initiated by Smyrnelis, however, it seems that several results were incomplete and we clarify them here. 相似文献
8.
ABSTRACTBayfol (PC-PBT blend ?lm) is a class of polymeric solid-state nuclear track detector which has a lot of applications in several radiation detection ?elds. It is a bisphenol-A polycarbonate PC blended with polybutylene terephthalate PBT. Bayfol/Palladium (PC-PBT/Pd) nanocomposite films have been deposited using the molding technique. It is worth mentioning that this report is almost the first one dealing with the topic of the changes of physical properties of Bayfol/Pd nanocomposite due to laser exposure. Samples from PC-PBT/Pd (5?wt%) nanocomposite were exposed to IR-pulsed laser of 5-W power, capable of producing 2000 pulses per second with pulse duration of 200?ns at 904?nm. The laser fluences were in the range 2–25?J/cm2. The resultant modi?cations in the exposed nanocomposite samples have been studied as a function of fluence using different characterization techniques such as X-ray diffraction (XRD), UV spectroscopy and color difference studies. The results indicate the proper dispersion of Pd nanoparticles in the PC-PBT matrix that causes a strong intermolecular interaction between Pd and PC-PBT, resulted in an increase in refractive index and the amorphous phase. Also, it is found that the laser exposure reduces the optical energy gap that could be attributed to the increase in structural disorder of the exposed PC-PBT/Pd nanocomposites due to crosslinking. Further, the color intensity ΔE, which is the color difference between the exposed samples and the non-exposed one, was increased with increasing the laser fluence, convoyed by a significant increase in the green and yellow color components. 相似文献
9.
10.
Analysis of silicon light emission under breakdown condition using an indirect intraband model 总被引:1,自引:0,他引:1
The light emission from silicon (npn) emitter–base junctions under breakdown condition has been modelled. The model suggests an indirect intraband processes combined with self-absorption. Good agreement between simulated and measured electroluminescence (EL) spectra is shown which demonstrates that the model is simple and more consistent with fundamental physical device characteristics particularly in the spectral range studied (1.4–2 eV). 相似文献