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Utpal Majumder 《Tetrahedron letters》2005,46(42):7209-7211
The scope and limitations of the Takai-Utimoto reagent to induce the cyclization of olefinic-esters is described. Critical is the steric environment about both the ester and the olefin. Mechanistically, these results support the hypothesis that cyclized product comes from an olefin metathesis, carbonyl-olefination sequence. 相似文献
3.
A. Mandal A. Koll A. Filarowski D. Majumder S. Mukherjee 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》1999,55(14):2861
A new orthohydroxy Schiff base, 7-ethylsalicylidenebenzylamine (ESBA) has been synthesised. The excited state intramolecular proton transfer (ESIPT) processes have been investigated by means of absorption, emission and nanosecond spectroscopy at room temperature and at 77 K in non polar solvents. The ESIPT is evidenced by a large Stokes shifted emission (11 000 cm−1) only at 77 K. From fluorescence and excitation spectra it is suggested that at least three different species are present in the excited state at room temperature. Our theoretical calculation at AM1 level confirm the cis-isomer to be the only viable form in the ground state. 相似文献
4.
Pyrimido[4,5-d]pyrimidine derivatives 4 have been prepared in an efficient and regioselective manner in water via multi-component reaction of isothiocyanate 1, aromatic aldehyde 2, N,N-dimethyl-6-amino uracil 3 in the presence of p-toluenesulfonic acid (p-TSA) as a Lewis acid catalyst. 相似文献
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The nearside distribution of particles at intermediate transverse momentum, associated with a high momentum trigger hadron produced in a high energy heavy-ion collision, is broadened in rapidity compared with the jet cone. This broadened distribution is thought to contain the energy lost by the progenitor parton of the trigger hadron. We show that the broadening can be explained as the final-state deflection of the gluons radiated from the hard parton inside the medium by soft, transversely oriented, turbulent color fields that arise in the presence of plasma instabilities. The magnitude of the effect is found to grow with medium size and density and diminish with increasing energy of the associated hadron. 相似文献
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H. -E. Swoboda F. A. Majumder V. G. Lyssenko C. Klingshirn L. Banyai 《Zeitschrift für Physik B Condensed Matter》1988,70(3):341-348
We investigate and analyze the time-integrated nonlinear optical behaviour of an electronhole plasma in CdS as a function of the temperature and the exciting intensity. The competition between the temperature dependences of the absorption tail and of the manyparticle effects leads with increasing temperature around 160 K to a turn-over from a red- to a blue-shift of the absorption edge under excitation. The frequency dependence of the absorption for high plasma concentrations is in good agreement with theoretical calculations. 相似文献
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M.?Jain S.B.?Majumder R.S.?Katiyar Email author S.B.?Desu 《Applied Physics A: Materials Science & Processing》2003,77(6):789-792
We have investigated the relations between microstructure and dielectric properties in order to fabricate sol-gel-derived highly (100) oriented Ba0.5Sr0.5TiO3 (BST 50/50) thin films with properties comparable to those of the bulk material. For the first time, we were able to fabricate BST thin films which exhibited the orthorhombic-to-tetragonal transition in addition to the commonly observed tetragonal-to-cubic transition. We were successful in explaining the commonly observed degradation of the dielectric behavior of BST thin films, when compared to that of the bulk material, in terms of grain size, compositional inhomogeneity (measured in terms of Sr/Ba ratio) between the grain bulk and grain boundary, and mechanical stresses. PACS 77.55.+f; 77.22Gm; 77.80.Bh; 77.80.Dj 相似文献
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Barun Majumder 《Physics letters. [Part B]》2011,701(4):384-387
Recently Ali et al. (2009) [13] proposed a Generalized Uncertainty Principle (or GUP) with a linear term in momentum (accompanied by Planck length). Inspired by this idea we examine the Wheeler-DeWitt equation for a Schwarzschild black hole with a modified Heisenberg algebra which has a linear term in momentum. We found that the leading contribution to mass comes from the square root of the quantum number n which coincides with Bekenstein?s proposal. We also found that the mass of the black hole is directly proportional to the quantum number n when quantum gravity effects are taken into consideration via the modified uncertainty relation but it reduces the value of mass for a particular value of the quantum number. 相似文献
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