Effects of alloying iron with nickel on edge dislocation motion resistance

Studies of microplastic strain in-Fe and in Fe-Ni solid solution have provided data on the concentration and temperature dependence of the edge-dislocation motion resistance arising from elastic interaction with alloying-element atoms.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 89–93, March, 1984.     

(Z)-3-p-tolylsulfinylacrylonitrile as a chiral dienophile: diels-alder reactions with furan and acyclic dienes

The behavior of (Z)-3-p-tolylsulfinylacrylonitrile (1) as a chiral dienophile has been evaluated from its reactions with furan and acyclic dienes. Electrostatic interactions of the cyano group with the sulfinyl one restrict the conformational mobility around the C-S bond, thus controlling the pi-facial selectivity, which is almost complete in all cases, the approach of the diene from the less-hindered face of the dienophile (that bearing the lone electron pair) in the predominant rotamer being the favored one. The regioselectivity is also completely controlled by the cyano group. Additionally, the reactivity of compound 1 as well as its endo-selectivity are both higher than those observed for the corresponding (Z)-3-sulfinylacrylates, thus proving the potential of sulfinylnitriles as chiral dienophiles.     

Narrow band quantitative and multivariate electroencephalogram analysis of peri-adolescent period

ABSTRACT: BACKGROUND: The peri-adolescent period is a crucial developmental moment of transition from childhood to emergent adulthood. The present report analyses the differences in Power Spectrum (PS) of the Electroencephalogram (EEG) between late childhood (24 children between 8 and 13 years old) and young adulthood (24 young adults between 18 and 23 years old). RESULTS: The narrow band analysis of the Electroencephalogram was computed in the frequency range of 0--20 Hz. The analysis of mean and variance suggested that six frequency ranges presented a different rate of maturation at these ages, namely: low delta, delta-theta, low alpha, high alpha, low beta and high beta. For most of these bands the maturation seems to occur later in anterior sites than posterior sites. Correlational analysis showed a lower pattern of correlation between different frequencies in children than in young adults, suggesting a certain asynchrony in the maturation of different rhythms. The topographical analysis revealed similar topographies of the different rhythms in children and young adults. Principal Component Analysis (PCA) demonstrated the same internal structure for the Electroencephalogram of both age groups. Principal Component Analysis allowed to separate four subcomponents in the alpha range. All these subcomponents peaked at a lower frequency in children than in young adults. CONCLUSIONS: The present approaches complement and solve some of the incertitudes when the classical brain broad rhythm analysis is applied. Children have a higher absolute power than young adults for frequency ranges between 0-20 Hz, the correlation of Power Spectrum (PS) with age and the variance age comparison showed that there are six ranges of frequencies that can distinguish the level of EEG maturation in children and adults. The establishment of maturational order of different frequencies and its possible maturational interdependence would require a complete series including all the different ages.     

Quantum many-body culling: production of a definite number of ground-state atoms in a bose-einstein condensate

We propose a method to produce a definite number of ground-state atoms by adiabatic reduction of the depth of a potential well that confines a degenerate Bose gas with repulsive interactions. Using a variety of methods, we map out the maximum number of particles that can be supported by the well as a function of the well depth and interaction strength, covering the limiting case of a Tonks gas as well as the mean-field regime. We also estimate the time scales for adiabaticity and discuss the recent observation of atomic number squeezing [Chuu, Phys. Rev. Lett. 95, 260403 (2005)10.1103/PhysRevLett.95.260403].     

Grain-boundary hardening in polycrystalline copper-based solid solutions

A study is made of the contribution of grain-boundary hardening to the overall hardening in a polycrystalline material on the basis of Ashby's model. Yield curves are used for copper-based solid solutions in polycrystalline and singlecrystal forms. It is shown that the contribution from statistically accumulated dislocations to the yield stress in a polycrystalline specimen reflects the behavior of the corresponding single crystal. The contribution from grain boundaries to the yield stress can be described in terms of the additional dislocation density due to the joint grain deformation in the aggregate up to high strains. At low strains, the main role in hardening of a polycrystalline material is played by the grain boundaries. This extends up to larger strains as the strain temperature is reduced and the alloy-element concentration increases.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 47–52, January, 1984.     

Test of calculations on dislocation blocking in copperbase solid solutions

The creep threshold =f(c) for deformation aging under load is examined for Cu-Al, Cu-Ge, and Cu-Ni solid solutions; in each case it is in good general agreement with the theoretical relation for dislocation blocking. The data provide support for theoretical calculations on the main dislocation-blocking factors.