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排序方式: 共有99条查询结果,搜索用时 15 毫秒
1.
R. W. R. Darling 《Probability Theory and Related Fields》1988,77(2):211-229
Let Z
1, Z
2,... be a sequence of i.i.d. random transformations (possibly discontinuous) of a compact metric space M, and let E denote the space of normalized mass distributions on M. Given in E, let
n
denote the random measure °(Z
n
°...°Z
1)–1 (when well-defined). We construct the transition probability P of the E-valued Markov chain (
n
), and give a necessary and sufficient condition for P to have a unique invariant measure concentrated on the degenerate mass distributions. Convergence to statistical equilibrium of the associated discrete-time stochastic flow is investigated.Research supported by NSF grants INT-8420360 and DMS-8502802. This work was done while the author was visiting the Universities of Warwick and Minnesota 相似文献
2.
Stulz E Scott SM Ng YF Bond AD Teat SJ Darling SL Feeder N Sanders JK 《Inorganic chemistry》2003,42(20):6564-6574
The synthesis of linear multiporphyrin arrays with mono- and bisphosphine-substituted porphyrins as ligand donors and ruthenium(II) or rhodium(III) porphyrins as ligand acceptors is described. With appropriate amounts of the building blocks mixed, linear dimeric and trimeric arrays have been synthesized and analyzed by (1)H NMR and (31)P NMR spectroscopy. The Ru/Rh acceptor porphyrins can be located either at the periphery or in the center of the array. Likewise, the monophosphine porphyrins can be positioned at the periphery, thus allowing a high degree of freedom in the overall composition of the arrays. This way, both donor and acceptor porphyrins can act as chain extenders or terminators. One of the trimeric complexes with two nickel and one ruthenium porphyrin has also been analyzed by X-ray crystallography. Attempts have also been made to synthesize higher order arrays by mixing appropriate amounts of the porphyrins; however, from the NMR data it cannot be concluded if monodisperse five, seven, or nine porphyrin arrays are present or if the solutions are composed of a statistical mixture of smaller and larger arrays. 相似文献
3.
R. W. R. Darling 《Probability Theory and Related Fields》1984,65(4):563-572
Summary Suppose X is a semimartingale on a differential manifold M with a linear connection . The main purpose of this paper is to show that the Ito integral (with respect to ) of a differential form along the path of X is the limit in probability of certain Riemann sums, constructed in a natural way using the exponential map in differential geometry. For this, we study the deviation between the stochastic development of X in the tangent space at some point, and the image of X under the inverse of the exponential map at the point. 相似文献
4.
William H. McCarroll Cynthia Darling Gary Jakubicki 《Journal of solid state chemistry》1983,48(2):189-195
Fused salt electrolysis has been used to prepare a number of reduced oxides of molybdenum with lanthanum, neodymium, and yttrium in single crystal or oriented polycrystalline form. The average valence of molybdenum in the various compounds ranged from 5.67 to 3.50. Previously unreported compounds include La5Mo4O16 (triclinica = 5.64 Å,b = 20.7 0Å,c = 5.64 Å, α = 86.55°, β = 90.0°, γ = 93.45°); La2Mo2O7 (orthorhombic,a = 12.19 Å,b = 6.05 Å,c = 3.87 Å); LaMo2O5 (hexagonal,a = 8.378 Å,c = 19.26 Å). In addition, single crystal specimens have been prepared of Y2MoO5,Ln5Mo3O16(Ln =La, Nd) and metal atom cluster compounds of theA2Mo3O8 type (A = Mg, Co, Ni, Zn). 相似文献
5.
Consider a sequenceF
1,F
2,... of i.i.d. random transformations from a countable setV toV. Such a sequence describes a discrete-time stochastic flow onV, in which the position at timen of a particle that started at sitex isM
n(x), whereM
n
=F
n
F
n–1
F
1. We give conditions on the law ofF
1 for the sequence (M
n) to be tight, and describe the possible limiting law. an example called the block charge model is introduced. The results can be formulated as a statement about the convergence in distribution of products of infinite-dimensional random stochastic matrices. In practical terms, they describe the possible equilibria for random motions of systems of particles on a countable set, without births or deaths, where each site may be occupied by any number of particles, and all particles at a particular site move together. 相似文献
6.
Alves GA Amato S Anjos JC Appel JA Astorga J Bracker SB Cremaldi LM Dagenhart WD Darling CL Dixon RL Errede D Fenker HC Gay C Green DR Jedicke R Karchin PE Kennedy C Kwan S Lueking LH de Mello Neto JR Metheny J Milburn RH de Miranda JM da Motta Filho H Napier A Passmore D Rafatian A dos Reis AC Ross WR Santoro AF Sheaff M Souza MH Spalding WJ Stoughton C Streetman ME Summers DJ Takach SF Wallace A Wu Z 《Physical review letters》1996,77(12):2388-2391
7.
Tailoring the structure of water at a metal surface: a structural analysis of the water bilayer formed on an alloy template 总被引:1,自引:0,他引:1
Recent studies show that structures based on the traditional "icelike" water bilayer are not stable on flat transition metal surfaces and, instead, more complex wetting layers are formed. Here we show that an ordered bilayer can be formed on a SnPt(111) alloy template and determine the structure of the water layer by low energy electron diffraction. Close agreement is found between experiment and the structure calculated by density functional theory. Corrugation of the alloy surface allows only alternate water molecules to chemisorb, stabilizing the H-down water bilayer by reducing the metal-hydrogen repulsion compared to a flat surface. 相似文献
8.
Fogg AM Claridge JB Darling GR Rosseinsky MJ 《Chemical communications (Cambridge, England)》2003,(12):1348-1349
The synthesis of Li(x)BC (x > 0.5) by high temperature Li deintercalation from LiBC is demonstrated by refinement of X-ray and neutron powder diffraction data--contrary to theoretical expectation no superconductivity above 2K is observed in these materials. 相似文献
9.
Aitala EM Amato S Anjos JC Appel JA Ashery D Banerjee S Bediaga I Blaylock G Bracker SB Burchat PR Burnstein RA Carter T Carvalho HS Copty NK Cremaldi LM Darling C Denisenko K Devmal S Fernandez A Fox GF Gagnon P Gobel C Gounder K Halling AM Herrera G Hurvits G James C Kasper PA Kwan S Langs DC Leslie J Lundberg B Magnin J Massafferri A MayTal-Beck S Meadows B de Mello Neto JR Mihalcea D Milburn RH de Miranda JM Napier A Nguyen A d'Oliveira AB O'Shaughnessy K Peng KC Perera LP Purohit MV 《Physical review letters》2001,86(5):770-774
From a sample of 1172 +/- 61 D(+)-->pi(-)pi(+)pi(+) decays, we find gamma(D(+)-->pi(-)pi(+)pi(+))/gamma(D(+)-->K-pi(+)pi(+)) = 0.0311 +/- 0.0018(+0.0016)(-0.0026). Using a coherent amplitude analysis to fit the Dalitz plot of these decays, we find strong evidence that a scalar resonance of mass 478(+24)(-23) +/- 17 MeV/c(2) and width 324(+42)(-40) +/- 21 MeV/c(2) accounts for approximately half of all decays. 相似文献
10.
Matthias Meier Dr. Julia Kennedy‐Darling Se Hoon Choi Eric M. Norstrom Dr. Sangram S. Sisodia Prof. Dr. Rustem F. Ismagilov Prof. Dr. 《Angewandte Chemie (International ed. in English)》2009,48(8):1487-1489
Small with control : For miniaturization of protein aggregation experiments the interfacial chemistry must be controlled to avoid protein aggregation caused by interfacial adsorption. Plug‐based microfluidics with defined surface chemistry (see schematic picture) can then be used to perform hundreds of aggregation experiments with volume‐limited samples, such as cerebrospinal fluid from mice.