排序方式: 共有37条查询结果,搜索用时 15 毫秒
1.
Ahmed SN Anthony AE Beier EW Bellerive A Biller SD Boger J Boulay MG Bowler MG Bowles TJ Brice SJ Bullard TV Chan YD Chen M Chen X Cleveland BT Cox GA Dai X Dalnoki-Veress F Doe PJ Dosanjh RS Doucas G Dragowsky MR Duba CA Duncan FA Dunford M Dunmore JA Earle ED Elliott SR Evans HC Ewan GT Farine J Fergani H Fleurot F Formaggio JA Fowler MM Frame K Fulsom BG Gagnon N Graham K Grant DR Hahn RL Hall JC Hallin AL Hallman ED Hamer AS Handler WB Hargrove CK Harvey PJ Hazama R Heeger KM Heintzelman WJ 《Physical review letters》2004,92(18):181301
The Sudbury Neutrino Observatory has precisely determined the total active (nu(x)) 8B solar neutrino flux without assumptions about the energy dependence of the nu(e) survival probability. The measurements were made with dissolved NaCl in heavy water to enhance the sensitivity and signature for neutral-current interactions. The flux is found to be 5.21 +/- 0.27(stat)+/-0.38(syst) x 10(6) cm(-2) s(-1), in agreement with previous measurements and standard solar models. A global analysis of these and other solar and reactor neutrino results yields Deltam(2)=7.1(+1.2)(-0.6) x 10(-5) eV(2) and theta=32.5(+2.4)(-2.3) degrees. Maximal mixing is rejected at the equivalent of 5.4 standard deviations. 相似文献
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R Bonfiglio RC King TV Olah K Merkle 《Rapid communications in mass spectrometry : RCM》1999,13(12):1175-1185
A post-column infusion system was developed in order to analyze suppression of electrospray ionization (ESI) tandem mass spectrometry response in the presence of endogenous plasma interferences. By enabling direct detection of these interfering components, this experimental system was used to analyze the ability of several common extraction procedures to remove endogenous plasma components that cause changes in the ESI response of model drug substances. Methyl-t-butyl ether (MTBE) liquid-liquid, Oasis and Empore solid-phase, and acetonitrile (ACN) protein precipitation sample preparation methods were tested using the post-column infusion system. In all cases, ACN protein precipitation samples showed the greatest amount of ESI response suppression while liquid-liquid extracts demonstrated the least. In addition, the three test compounds, phenacetin, caffeine, and a representative Merck compound, demonstrated that ESI response suppression is compound dependent. Suppression was greatest with caffeine, the most polar analyte, and the smallest for the Merck compound, the least polar analyte. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
3.
M. B. Rane K. Kondaiah A. R. Middleton G. T. Wernimont S. L. Archangelowa M. Stschigol N. Dubinski L. W. N. Godward A. M. Ward A. D. Worobjewa P. Wukolow A. Reich N. A. Tananajew F. P. Dwyer R. H. Bullard J. S. Knapper K. A. Craig G. C. Chandlee W. I. Kosakow L. Szebellédy M. Ajtai M. Uljanitschew M. S. Platonow N. F. Kriwoschlykow A. A. Marakajew M. J. Petrow K. M. Rauner 《Analytical and bioanalytical chemistry》1939,117(3-4):118-132
4.
Noah J. Tremblay Alon A. Gorodetsky Dr. Marshall P. Cox Theanne Schiros Dr. Bumjung Kim Rachel Steiner Zachary Bullard Aaron Sattler Woo‐Young So Dr. Yoshimitsu Itoh Dr. Michael F. Toney Dr. Hirohito Ogasawara Dr. Arthur P. Ramirez Prof. Ioannis Kymissis Dr. Michael L. Steigerwald Dr. Colin Nuckolls Prof. 《Chemphyschem》2010,11(4):742-742
5.
We discuss our experiences with exceptionally intense Mössbauer sources (of order 100 Ci) and their use in making precision determinations of line shape parameters. We review our measurements of interference and recoilless fraction using conventional transmission geometry. Fitting simultaneous sets of data with known constraints greatly improves the efficiency of line-shape determination. Measurements of interference have been made using a two-absorber technique first introduced by Mössbauer and coworkers. Our results indicate that the method can be useful for determining interference, but that incorrect line shape parameters are obtained if powder samples are used which do not comply well with the assumption of thickness uniformity in the absorber. 相似文献
6.
Aharmim B Ahmed SN Amsbaugh JF Anthony AE Banar J Barros N Beier EW Bellerive A Beltran B Bergevin M Biller SD Boudjemline K Boulay MG Bowles TJ Browne MC Bullard TV Burritt TH Cai B Chan YD Chauhan D Chen M Cleveland BT Cox-Mobrand GA Currat CA Dai X Deng H Detwiler J DiMarco M Doe PJ Doucas G Drouin PL Duba CA Duncan FA Dunford M Earle ED Elliott SR Evans HC Ewan GT Farine J Fergani H Fleurot F Ford RJ Formaggio JA Fowler MM Gagnon N Germani JV Goldschmidt A Goon JT Graham K Guillian E 《Physical review letters》2008,101(11):111301
The Sudbury Neutrino Observatory (SNO) used an array of 3He proportional counters to measure the rate of neutral-current interactions in heavy water and precisely determined the total active (nu_x) 8B solar neutrino flux. This technique is independent of previous methods employed by SNO. The total flux is found to be 5.54_-0.31;+0.33(stat)-0.34+0.36(syst)x10(6) cm(-2) s(-1), in agreement with previous measurements and standard solar models. A global analysis of solar and reactor neutrino results yields Deltam2=7.59_-0.21;+0.19x10(-5) eV2 and theta=34.4_-1.2;+1.3 degrees. The uncertainty on the mixing angle has been reduced from SNO's previous results. 相似文献
7.
The electroosmotic behavior of the rutile polymorph of titanium dioxide was explored as a function of the crystallographic orientation. Atomic force microscopy (AFM) was employed to make high-resolution force spectroscopy measurements between a silica sphere attached to a traditional, contact-mode AFM cantilever and TiO2(110), TiO2(100), and TiO2(001) surfaces in aqueous solutions. Measurements were taken in multiple solution conditions across a broad range of pH values, and the resultant force-distance curves were used to deduce relative behaviors of each orientation of rutile, with particular interest in changes of the isoelectric point (iep). Differences in the iep as a function of orientation are explained in terms of differences in both the coordination number and density of acidic and basic sites on the surface. The results were supported by angle-resolved X-ray photoelectron spectroscopy (XPS) measurements of a nominal monolayer of palladium metal deposited on each of the three orientations studied. The palladium monolayer served as a means of probing the relative electron affinities of the three surfaces studied, which were exhibited in shifts of the palladium XPS peak that corresponded to differences in the binding energy as a function of the substrate orientation. The correlation between the rutile orientation and the shift in the palladium binding energy corresponded directly to the relationship between the isoelectric point and the orientation, with the surface of lowest isoelectric point exhibiting the highest Pd binding energy. 相似文献
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Atomic force microscopy (AFM) has been used to characterize the structural evolution of the MoO3(010) surface during the initial stage of Li+ intercalation. Lithiation was observed in situ using model cells comprised of a single crystal MoO3 cathode, a dilute propylene carbonate (PC)-based electrolyte, and an Li metal anode. The insertion of Li+ into MoO3 results in the topotactic nucleation and growth of acicular LixMoO3 (x0.25) precipitates at the (010) surface. Because the interlayer spacing of LixMoO3 (d=7.88 Å) is greater than that of MoO3 (d=b/2=6.93 Å), the LixMoO3 precipitates expand out of the (010) surface as they grow into the MoO3 crystal along 010. The local strain associated with this expansion causes the LixMoO3 precipitates to crack parallel to the MoO3001 and 010 axes once their height exceeds approximately 20 nm. With continued Li+ intercalation, cracking becomes more prominent, and the (010) surface begins to fragment and disintegrate. Anisotropies in Li+ ion uptake and the influence of surface morphology on LixMoO3 precipitation and crack propagation are described. 相似文献
10.
Bullard JW 《Journal of colloid and interface science》2004,276(1):188-196
A thermodynamic model is developed of the free energy of gas-filled voids formed within cavities on solid surfaces covered by a liquid. Capillary effects are assumed to be the only important contributions to the free energy, and expressions are derived for the free energy of the system as a function of the void size, the relative surface free energy densities involved, and the geometry of the cavity. The results of the model are (1) construction of a stability diagram that maps the most stable void configuration versus the wetting properties of the various solid surfaces involved, and (2) rough estimates of the work required to liberate a void of a given size and position. The model can give qualitative insight into the stability of coating defects on uneven surfaces, and also can be used to prescribe possible surface treatments for reducing the work required to remove voids from the system. 相似文献