条件泛函及其导数非参数估计的强一致收敛速度

研究了条件泛函及其导数的非参数估计,对随机与固定设计的条件泛函,分别利用核估计和非参数加权估计,在核函数及权函数满足一定条件下,证明了估计一致强收敛于待估函数的速度可达到最优。从而进一步推广和发展了Hrdle,etal.(1988)、Severini,etal.(1992)的许多结果。     

拟似然非线性模型的某些渐近推断:几何方法

Abstract. A modified Bates and Watts geometric framework is proposed for quasi-likelihoodnonlinear models in Euclidean inner product space. Based on the modified geometric framework,some asymptotic inference in terms of curvatures for quasi-likelihood nonlinear models is stud-ied. Several previous results for nonlinear regression models and exponential family nonlinearmodels etc. are extended to quasi-likelihood nonlinear models.     

非线性纵向数据模型中自相关性和随机效应的存在性检验

刻画纵向数据协方差结构有三种可能因素 ,即序列相关 (特别是一阶自相关 )、随机效应和常规的随机误差 (Diggleetal,2 0 0 2 ) .本文研究非线性纵向数据模型的自相关性和随机效应存在性的单个和联合检验 ,得到了检验的score统计量 ,并利用血浆药物渗透数据 (Davidian&Gilinan ,1 995)说明检验方法的应用 .     

Separation and concentration of sulfonylurea herbicides in milk by ionic‐liquid‐based foam flotation solid‐phase extraction

The ultrasound‐assisted ionic liquid foam flotation solid‐phase extraction of sulfonylurea herbicides in milk was developed and validated. The proteins and lipids were isolated from the sample matrix by adding salt and adjusting the pH value. The target analytes eluted from the solid‐phase extraction cartridge were determined by high‐performance liquid chromatography. Some experimental parameters, including the pH value of sample solution, amount of NaCl, ionic liquid type, extraction time, flow rate of carrier gas, flotation time, and solid‐phase extraction cartridge type were investigated and optimized. Under the optimized experimental conditions, the limits of detection for metsulfuron, pyrazosulfuron, chlorimuron‐ethyl, and nicosulfuron were 1.3, 0.6, 0.7, and 1.1 μg/L, respectively. When the present method was applied to the analysis of milk samples the recoveries of the analytes ranged from 84.3 to 105.2% and relative standard deviations were >5.7%.     

用过剩压法生长金刚石过程石墨再结晶现象的研究

 描述了在过剩压驱动下金刚石晶种外延生过程中，大量伴生的石墨再结晶现象。再结晶石墨抑制了金刚石的自发成核；它们分布于合成腔触媒金属的低温区，结晶数量多，晶粒片状分层，尺寸大，但出现乱层晶体结构；同时产生一定数量的无定形碳。分析认为，这与长时间的低过剩压驱动，触媒金属内有足够的碳源供给，并具备在高温高压下石墨充分结晶但又达不到完全石墨化条件有关。还讨论了在低过剩压驱动下，促进金刚石晶体外延生长的碳源可能是活化的碳原子，而不是具有乱层结构特征的再结晶石墨。     

Hyperchaos,quasi-period and coexisting behaviors in second-order-memristor-based jerk circuit

The European Physical Journal Special Topics - This paper generalizes a second-order-memristor-based jerk circuit, which is achieved by substituting the first-order memristor contained diode-bridge...     

Numerical analyses and breadboard experiments of twin attractors in two-neuron-based non-autonomous Hopfield neural network

This paper investigates twin attractors in a two-neuron-based non-autonomous Hopfield neural network (HNN) through numerical analyses and hardware experiments. Stability analysis of the DC equilibrium point is executed and an unstable saddle-focus is found in the parameter region of interest. The stimulus-associated dynamical behaviors are numerically explored by bifurcation diagrams and dynamical map in two-dimensional parameter-space, from which coexisting twin attractors behavior can be observed with the variations of two stimulus-associated parameters. Moreover, breadboard experiment investigations are carried out, which effectively verify the numerical simulations.     

非线性再生散度模型的渐近性质

对非线性再生散度模型,给出了类似于Ｆａｈｒｍｅｉｒ＆Ｋａｕｆｍａｎｎ（１９８５）和Ｗｅｉ（１９９８）的正则条件．基于这些正则条件,证明了最大似然估计的存在性、强相合性和渐近正态性,推广了已有文献的工作．     

Bayes局部影响分析<英>

本文从Bayes观点出发,利用Kullback-Leibler距离和微分几何方法,系统地讨论了微小扰动对于Bayes统计推断的局部影响,给出了Bayes局部影响分析的一般公式作为应用,具体讨论了线性回归模型的Bayes估计和Bayes预测的局部影响问题,数值计算的结果表明,本文的方法是比较有效的。     

吖啶酯标记的化学发光免疫分析优化参数评价

以睾酮-3-羧甲氧基肟-牛血清白蛋白为免疫原,免疫家兔产生抗血清,10-甲基吖啶-9-羧酸[4-(N-睾酮-3-羧甲氧基肟)-氨乙基]苯酯为示踪化合物,采用平衡法建立睾酮化学发光免疫分析,数据用四参数Logistic函数处理。方法学考核标准曲线稳定,R为0.9967;ED50为82.15ng/L;批内和批间CV分别为5.78%和3.3%;平均回收率为107.28%;可测范围为19.3～264.6ng/L,与雌酮、雌二醇、雌三醇和孕酮的交叉反应率均小于1.35%;非特异结合率为9.64%.“桥效应”分析表明同位点、“桥”结构相同亲和力最大.