排序方式: 共有48条查询结果,搜索用时 15 毫秒
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This paper reports the use of improved numerical approaches to modelling extraction profiles, and shows that the approach substantially reduces statistical prediction uncertainties compared to those obtained on the basis of a three-point extrapolation from the later part of the extraction curve. Numerical fitting of manually obtained polycyclic aromatic hydrocarbon extraction data to a spherical particle diffusion model showed uncertainties typically reduced by a factor of three (with extremes at 1.02 and 770). Application to pressurised fluid extraction study of pelletised poly(vinylchloride) containing 30 mass% di(2-ethylhexyl)phthalate also showed good improvements. However, this high precision data showed small but significant lack of fit resulting in residual correlation and visibly biased prediction (more so than simple extrapolation). Re-fitting and uncertainty estimation using a first-order autoregression approximation to the covariance matrix produced more realistic uncertainty estimates and closer parameter estimates and is accordingly recommended for treating residual correlation from other causes, but did not entirely alleviate the problem. Different shape models (spherical, plane sheet and cylindrical) were applied without accounting fully for fitting error, and particle size effects were eliminated by modelling a simple size distribution. However, an approximate model based on linearly concentration-dependent diffusion coefficient showed excellent fit, confirming concentration-dependence as the most likely cause. This semiempirical model led to an uncertainty in total extractable material, at 0.2% of the total extractable value (with allowance for correlation). This is potentially good enough for recovery estimation and correction in certification of reference materials for validation purposes. 相似文献
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We prove that a parabolic unitalU in a translation plane of orderq
2 with kernel containing GF(q) is a Buekenhout-Metz unital if and only if certain Baer subplanes containing the translation line of meetU in 1 moduloq points. As a corollary we show that a unital 16-03 in PG(2,q
2) is classical if and only if it meets each Baer subplane of PG(2,q
2) in 1 moduloq points. 相似文献
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S. G. Barwick 《Geometriae Dedicata》1994,52(2):175-180
We define Buekenhout unitals in derivable translation planes of dimension 2 over their kernel and provide a characterization of these unitals. We use this result to improve the characterization of classical unitals given by Lefèvre-Percsy [13] and Faina and Korchmáros [7]. 相似文献
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Barwick Vicki Ellison Stephen L. R. Gjengedal Elin Magnusson Bertil Molinier Olivier Patriarca Marina Sibbesen Lorens Vanlaethem Nicole Vercruysse Isabelle 《Accreditation and quality assurance》2017,22(5):253-263
Accreditation and Quality Assurance - Eurachem held a workshop on method validation in analytical sciences in Gent, Belgium, on 9–10 May 2016. A summary of the working group discussions is... 相似文献
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A multisecret threshold scheme is a system which protects a number of secret keys among a group of n participants. There is a secret sK associated with every subset K of k participants such that any t participants in K can reconstruct the secret sK, but a subset of w participants cannot get any information about a secret they are not associated with. This paper gives a construction for
the parameters t = 2, k = 3 and for any n and w that is optimal in the sense that participants hold the minimal amount of information.
Communicated by: P. Wild 相似文献
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Achterberg A Ackermann M Adams J Ahrens J Andeen K Atlee DW Bahcall JN Bai X Baret B Bartelt M Barwick SW Bay R Beattie K Becka T Becker JK Becker KH Berghaus P Berley D Bernardini E Bertrand D Besson DZ Blaufuss E Boersma DJ Bohm C Bolmont J Böser S Botner O Bouchta A Braun J Burgess C Burgess T Castermans T Chirkin D Christy B Clem J Cowen DF D'Agostino MV Davour A Day CT De Clercq C Demirörs L Descamps F Desiati P Deyoung T Diaz-Velez JC Dreyer J Dumm JP Duvoort MR Edwards WR Ehrlich R 《Physical review letters》2006,97(22):221101
On 27 December 2004, a giant gamma flare from the Soft Gamma-Ray Repeater 1806-20 saturated many satellite gamma-ray detectors, being the brightest transient event ever observed in the Galaxy. AMANDA-II was used to search for down-going muons indicative of high-energy gammas and/or neutrinos from this object. The data revealed no significant signal, so upper limits (at 90% C.L.) on the normalization constant were set: 0.05(0.5) TeV-1 m;{-2} s;{-1} for gamma=-1.47 (-2) in the gamma flux and 0.4(6.1) TeV-1 m;{-2} s;{-1} for gamma=-1.47 (-2) in the high-energy neutrino flux. 相似文献
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The strain and resonance energies in beta-sultam derivatives have been calculated by using a high-level ab initio method (G3/B3LYP) in order to resolve the question of the principal driving force affecting solvolysis of these new antibiotics. We found that only the combined effect of stabilizing (via amide or sulfonamide resonance interactions) and destabilizing (ring strain) influences can account for the observed rates of solvolysis in beta-lactams and beta-sultams. 相似文献
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