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1.
D. H. Armitage 《Journal of Approximation Theory》2002,118(2):225-234
For each compact subset K of
N let
(K) denote the space of functions that are harmonic on some neighbourhood of K. The space
(K) is equipped with the topology of uniform convergence on K. Let Ω be an open subset of
N such that 0Ω and
N\Ω is connected. It is shown that there exists a series ∑Hn, where Hn is a homogeneous harmonic polynomial of degree n on
N, such that (i) ∑Hn converges on some ball of centre 0 to a function that is continuous on Ω and harmonic on Ω, (ii) the partial sums of ∑Hn are dense in
(K) for every compact subset K of
N\Ω with connected complement. Some refinements are given and our results are compared with an analogous theorem concerning overconvergence of power series. 相似文献
2.
Ian R. Gould Jacques E. Moser Bruce Armitage Samir Farid 《Research on Chemical Intermediates》1995,21(7):793-806
The overall efficiencies of photoinduced electron transfer reactions in polar solvents are usually determined by the efficiency with which separated radical ions are formed from the initially formed geminate radical-ion pairs. These separation efficiencies are determined by the competition between retum electron transfer and separation within the geminate pairs. A method is described for determining whether variations in the quantum yields for formation of separated radical ions are due to changes in the reorganization parameters for the return electron transfer reactions, or to other factors. The use of the method is illustrated in studies of the effects of varying steric bulk and molecular size of the donors, and also in studies of the effect of using a charged sensitizer. 相似文献
3.
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5.
Bintinger D Kees KH Masek GE Miller ES Thompson JR Vernon W White JT Eisner AM Palmer DA Sullivan MK Armitage JC Buijs A Van Driel MA Erné FC Langeveld WG Paar HP Sens JC Timmer J Van Uitert B Cain MP Ko W Lander RL Maeshima K McNeil RR Pellett DE Smith JR Williams MC Caldwell DO Joshi UP Lu A Schwitkis KA Yellin SJ 《Physical review letters》1985,54(8):763-766
6.
The exchange of oxygen functional groups (--- OR, --- O --- and --- OCOMe) and sulphur functional groups (--- SR, --- S --- ) between R3M (M = Si, Ge, Sn and Pb) and R2M (M = Si, Sn) shows, in general, the heavier Group IV element to prefer sulphur. This supports the phenomenological rationalisation that the softness of the organometallic residue increase with the atomic weight of M, though germanium probably resembles silicon in its behaviour far more that it does tin. 相似文献
7.
Wijkens P Jastrzebski JT van Der Schaaf PA Kolly R Hafner A van Koten G 《Organic letters》2000,2(11):1621-1624
A general method for the functionalization of Si-Cl terminated carbosilane dendritic molecules via organolithium or organomagnesium reagents is described. Quantitative exchange of the bromine atoms of 4-bromophenyl-functionalized dendrimers affords polylithiated species that are valuable starting materials for further functionalization, e.g., into pyridyl alcohols. The latter were successfully applied as catalyst precursors in a ruthenium-mediated ring-closure metathesis reaction. 相似文献
8.
A guanine-rich PNA dodecamer having the sequence H-G4T4G4-Lys-NH2 (G-PNA) hybridizes with a DNA dodecamer of homologous sequence to form a four-stranded quadruplex (Datta, B.; Schmitt, C.; Armitage, B. A. J. Am. Chem. Soc. 2003, 125, 4111-4118). This report describes quadruplex formation by the PNA alone. UV melting curves and fluorescence resonance energy transfer experiments reveal formation of a multistranded structure stabilized by guanine tetrads. The ion dependency of these structures is analogous to that reported for DNA quadruplexes. Electrospray ionization mass spectrometry indicates that both dimeric and tetrameric quadruplexes are formed by G4-PNA, with the dimeric form being preferred. These results have implications for the use of G-rich PNA for homologous hybridization to G-rich targets in chromosomal DNA and suggest additional applications in assembling quadruplex structures within lipid bilayer environments. 相似文献
9.
Hybridization of PNA to structured DNA targets: quadruplex invasion and the overhang effect 总被引:4,自引:0,他引:4
Peptide nucleic acid (PNA) probes have been synthesized and targeted to quadruplex DNA. UV-vis and CD spectroscopy reveal that the quadruplex structure of the thrombin binding aptamer (TBA) is disrupted at 37 degrees C by a short PNA probe. The corresponding DNA probe fails to bind to the stable secondary structure at this temperature. Thermal denaturation experiments indicate surprisingly high thermal and thermodynamic stabilities for the PNA-TBA hybrid. Our results point to the nonbonded nucleobase overhangs on the DNA as being responsible for this stability. This "overhang effect" is found for two different PNA-DNA sequences and a variety of different overhang lengths and sequences. The stabilization offered by the overhangs assists the PNA in overcoming the stable secondary structure of the DNA target, an effect which may be significant in the targeting of biological nucleic acids, which will always be much longer than the PNA probe. The ability of PNA to invade a structured DNA target expands its potential utility as an antigene agent or hybridization probe. 相似文献
10.
Nicholas Douglas Charles J. Neef Robert A. Rogers Jake A. Stanley Jacob Armitage Ben Martin Todd W. Hudnall William J. Brittain 《Journal of Physical Organic Chemistry》2013,26(8):688-695
The synthesis and reactivity of a tetrahydrochromeno[2,3‐b]indoles are reported. Evidence for reversible ring‐opening is based on H/D exchange and trapping experiments. These compounds readily undergo reaction with tetra‐n‐butylammonium cyanide. The cyanide reaction is 10–100× faster when the solution is irradiated with 350 nm light. Reaction with trimethylsilyl cyanide occurs only with UV irradiation demonstrating photoreactivity. The rate of tetrahydrochromeno[2,3‐b]indole ring‐opening is greater for (i) Me substitution at the hemiaminal carbon (compared to Ph), and (ii) substitution of fluorine at the 9‐position of the indole. Under acidic conditions, the ring‐opened indolium ion is observed. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献