Bacterial Reduction of Chromium

A mixed culture was enriched from surface soil obtained from an eastern United States site highly contaminated with chromate. Growth of the culture was inhibited by a chromium concentration of 12 mg/L. Another mixed culture was enriched from subsurface soil obtained from the Hanford reservation, at the fringe of a chromate plume. The enrichment medium was minimal salts solution augmented with acetate as the carbon source, nitrate as the terminal electron acceptor, and various levels of chromate. This mixed culture exhibited chromate tolerance, but not chromate reduction capability, when growing anaerobically on this medium. However, this culture did exhibit chromate reduction capability when growing anaerobically on TSB. Growth of this culture was not inhibited by a chromium concentration of 12 mg/L. Mixed cultures exhibited decreasing diversity with increasing levels of chromate in the enrichment medium. An in situ bioremediation strategy is suggested for chromate contaminated soil and groundwater.

     

A non-conforming finite element method with anisotropic mesh grading for the Stokes problem in domains with edges

The solution of the Stokes problem in three-dimensional domainswith edges has anisotropic singular behaviour which is treatednumerically by using anisotropic finite element meshes. Thevelocity is approximated by Crouzeix–Raviart (nonconformingP₁ ) elements and the pressure by piecewise constants. Thismethod is stable for general meshes (without minimal or maximalangle condition). Denoting by N_e the number of elements in themesh, the interpolation and consistency errors are of the optimalorder h N_e^–1/3 which is proved for tensor product meshes.As a by-product, we analyse also nonconforming prismatic elementswith P₁ [oplus ] span {x₃²} as the local space for the velocitywhere x₃ is the direction of the edge.     

Enhancement of persistent currents due to confinement in metallic samples

Confinement and surface roughness (SR) effects on the magnitude of the persistent current are analyzed for ballistic bidimensional metallic samples. Depending on the particular geometry, localized border states can show up at half-filling. These border states contribute coherently to the persistent current and its magnitude is enhanced with respect to their value in the absence of confinement. A linear scaling of the typical current I(typ) with the number of conduction channels M is obtained. This result is robust with respect to changes in the relevant lengths of the samples and to the SR. Possible links of our results to experiments are also discussed.     

Surfactant aggregation in solutions applied for track etching and its possible effect on the pore shape in track membranes

Surfactants are used for etching track membranes to form pores of peculiar geometries with the purpose of, e.g., producing membranes with enhanced performance. The knowledge of the state of surfactant molecules in process solutions, in particular, the regularities of their aggregation, is of importance for understanding the mechanisms of surfactant action on track etching processes. This work presents the data on sodium dodecyl( sulfophenoxy)benzene sulfonate and nonyl benzene deca(ethylene oxide) micellization in neutral and alkaline electrolyte solutions of different concentrations. The measurements are carried out using the small-angle neutron scattering. It is shown that cylindrical (ellipsoid) micelles are formed in the solutions. Characteristic sizes of micelles are determined as functions of surfactant and added electrolyte concentrations. The correlation of the data obtained with the geometry of track nanopores and the dynamics of their etching in surfactant-containing solutions is discussed.     

Currents along ring arms with quantum dots: Kondo and Aharonov–Bohm effects

Transport properties of a double-dot system in a ring structure threaded by a magnetic flux are studied. The Aharonov–Bohm effect combined with the charging effects of the dots in the Kondo regime determines the phases of the currents going through each arm of the ring. Depending upon the magnetic flux and the state of charge of the dots, controlled by gate potentials, current circulates around the ring.     

X-ray diffraction filters based on track membranes

The principle of operation of X-ray filters made of polymer track membranes with through cylindrical pores is described. The relationship between the transmission of track membranes and the parameters of pores and optical constants of the polymer matrix is established. The way in which the interface roughness improves the spectral selectivity of diffraction filters is recognized.     

Adsorption of nonionic surfactant on porous and nonporous poly(ethylene terephthalate) films

The application of surfactants in the chemical etching of track membranes enables one to control their pore shape. To find out the mechanism of the surfactant action on the track etching in the nanometer range of pore sizes, the adsorption of a nonionic surfactant (polyoxyethyelene-4-nonylphenyl ether) on porous and nonporous poly(ethylene terephthalate) films has been studied. The experimental results have been analyzed in comparison with the data previously obtained on the adsorption of an anionic surfactant on similar films. It has been concluded that the behaviors of anionic and nonionic surfactants in negatively charged pores about 100 nm in radius are strongly different due to the electrostatic exclusion of co-ions from the pores, which is of significance only for compounds dissociating into ions.     

Rate coefficients and mechanisms of the reaction of cl‐atoms with a series of unsaturated hydrocarbons under atmospheric conditions

Rate coefficients and/or mechanistic information are provided for the reaction of Cl‐atoms with a number of unsaturated species, including isoprene, methacrolein ( MACR ), methyl vinyl ketone ( MVK ), 1,3‐butadiene, trans‐2‐butene, and 1‐butene. The following Cl‐atom rate coefficients were obtained at 298 K near 1 atm total pressure: k(isoprene) = (4.3 ± 0.6) × 10^?10cm³ molecule^?1 s^?1 (independent of pressure from 6.2 to 760 Torr); k( MVK ) = (2.2 ± 0.3) × 10^?10 cm³ molecule^?1 s^?1; k( MACR ) = (2.4 ± 0.3) × 10^?10 cm³ molecule^?1 s^?1; k(trans‐2‐butene) = (4.0 ± 0.5) × 10^?10 cm³ molecule^?1 s^?1; k(1‐butene) = (3.0 ± 0.4) × 10^?10 cm³ molecule^?1 s^?1. Products observed in the Cl‐atom‐initiated oxidation of the unsaturated species at 298 K in 1 atm air are as follows (with % molar yields in parentheses): CH₂O (9.5 ± 1.0%), HCOCl (5.1 ± 0.7%), and 1‐chloro‐3‐methyl‐3‐buten‐2‐one (CMBO, not quantified) from isoprene; chloroacetaldehyde (75 ± 8%), CO₂ (58 ± 5%), CH₂O (47 ± 7%), CH₃OH (8%), HCOCl (7 ± 1%), and peracetic acid (6%) from MVK ; CO (52 ± 4%), chloroacetone (42 ± 5%), CO₂ (23 ± 2%), CH₂O (18 ± 2%), and HCOCl (5%) from MACR ; CH₂O (7 ± 1%), HCOCl (3%), acrolein (≈3%), and 4‐chlorocrotonaldehyde (CCA, not quantified) from 1,3‐butadiene; CH₃CHO (22 ± 3%), CO₂ (13 ± 2%), 3‐chloro‐2‐butanone (13 ± 4%), CH₂O (7.6 ± 1.1%), and CH₃OH (1.8 ± 0.6%) from trans‐2‐butene; and chloroacetaldehyde (20 ± 3%), CH₂O (7 ± 1%), CO₂ (4 ± 1%), and HCOCl (4 ± 1%) from 1‐butene. Product yields from both trans‐2‐butene and 1‐butene were found to be O₂‐dependent. In the case of trans‐2‐butene, the observed O₂‐dependence is the result of a competition between unimolecular decomposition of the CH₃CH(Cl)? CH(O?)? CH₃ radical and its reaction with O₂, with k_decomp/k_O2 = (1.6 ± 0.4) × 10¹⁹ molecule cm^?3. The activation energy for decomposition is estimated at 11.5 ± 1.5 kcal mol^?1. The variation of the product yields with O₂ in the case of 1‐butene results from similar competitive reaction pathways for the two β‐chlorobutoxy radicals involved in the oxidation, ClCH₂CH(O?)CH₂CH₃ and ?OCH₂CHClCH₂CH₃. © 2003 Wiley Periodicals, Inc. Int J Chem Kinet 35: 334–353, 2003     

Etching of polyvinylidene fluoride with an alkaline solution of potassium permanganate

Kinetics of polyvinylidene fluoride etching with a permanganate alkaline solution used in manufacture of track membranes from hydrogen-containing fluoropolymers, and also products formed in the process, were studied in relation to temperature and relative content of mixture components.