Determination of germanium by AAS in chloride-containing matrices

Interference effects of NaCl on the ET-AAS determination of Ge have been studied. The use of several matrix modifiers to alleviate this problem such as Ni and Zn perchlorates and nitrates, nitric acid, ammonium nitrate are reported. The stabilizing effect of Zn and Ni perchlorates allows the use of high pretreatment temperatures. NaCl is thus thermally volatilized from the atomizer by employing pretreatment temperatures higher than 1500 degrees C resulting in an improved sensitivity. Germanium levels in zinc plant slag samples, have been determined and compared to those obtained for the same samples spiked with NaCl with platform and wall atomization using nickel perchlorate as a matrix modifier. The results were compared with those from a hydride generation system equipped with a liquid nitrogen trap. The recoveries for germanium have been almost complete and amount to 99% for the original slag samples and 80% for 15% (w/w) NaCl containing spiked samples.     

Performance Analysis of a Diagonal MHD Accelerator for Space Propulsion

The performance of a diagonal magnetohydrodynamic (MHD) accelerator has been numerically investigated. Studies were carried out using air plasma as a working gas in an equilibrium condition based on the MHD Augmented Propulsion Experiment channel designed by NASA. The MacCormack scheme is employed in order to solve the set of differential equations with MHD approximations. The fundamental performance of a diagonal MHD accelerator considering both flow performance along the channel and propulsion performance has been evaluated under various applied input currents and magnetic fields. The optimum performance is dominated by ${bf j} times {bf B}$ Lorentz body force acceleration, while it is increased with Joule heating and the ${bf u} times {bf B}$ term's contribution, which are detrimental to the propulsion performance. Moreover, friction forces resist the flow performance, particularly near the channel exit.      

A note on Stone join-semilattices

Characterizations for a pseudocomplemented modular join-semilattice with 0 and 1 and its ideal lattice to be a Stone lattice are given.     

Determination of germanium by AAS in chloride-containing matrices

Interference effects of NaCl on the ET-AAS determination of Ge have been studied. The use of several matrix modifiers to alleviate this problem such as Ni and Zn perchlorates and nitrates, nitric acid, ammonium nitrate are reported. The stabilizing effect of Zn and Ni perchlorates allows the use of high pretreatment temperatures. NaCl is thus thermally volatilized from the atomizer by employing pretreatment temperatures higher than 1500°C resulting in an improved sensitivity. Germanium levels in zinc plant slag samples, have been determined and compared to those obtained for the same samples spiked with NaCl with platform and wall atomization using nickel perchlorate as a matrix modifier. The results were compared with those from a hydride generation system equipped with a liquid nitrogen trap. The recoveries for germanium have been almost complete and amount to 99% for the original slag samples and 80% for 15% (w/w) NaCl containing spiked samples.