Temperature dependence of the ESR spectra of Mn2+ in iron pyrite (FeS2)

The first observation of the ESR spectra of Mn²⁺, entering substitutionally for Fe²⁺ in the Van Vleck paramagnet FeS₂ (polycrystals), is reported. The data from 5 to 295 K fits the spin-Hamiltonian $\text{h}{}_{\mathrm{s}}\text{= gβ}\text{H}\text{·}\text{S}$ + $\text{[S}{}^{\mathrm{<mtext>2</mtext>}}{}_{\mathrm{z}}\text{?}\text{1}\text{3}\text{S(S + 1)] + A}\text{S}\text{·}\text{I}$, with g = 2.000 ± 0.001, A/β = ?95.0 ± 0.5 Oe and D/β varying from 50 Oe (5K) to 59 Oe (295 K). The temperature dependence of D can be described in terms of a single phonon-mode with frequency ? 145 cm^?1.     

Magnetic susceptibility of iron pyrite (FeS2) between 4.2 and 620 K

The magnetic susceptibilities (χ) of several natural single crystals of iron pyrite (FeS₂) have been measured between 4.2 and 620 K with a force magnetometer. The measured susceptibilities are shown to related to the magnetic impurities present in the samples. For a pure sample, χ = 1.7 × 10^?7 emu/g at room temperature, with a small monotonic increase of χ with temperature. The results for a pure sample are interpreted in terms of contributions from diamagnetism and Van Vleck paramagnetism.     

Electrical resistivity and band gap of marcasite (FeS2)

For a natural crystal of marcasite, an energy gap of 0.34 eV and an acceptor level at 0.052 eV are determined from temperature-dependent (53–370 K) electrical resistivity measurements. Magnetic susceptibilities and dielectric constants of marcasite and pyrite are compared in view of the large difference in their energy gaps.     

Dielectric constant of iron pyrite (FeS2)

The dielectric constant ?' of FeS₂ is measured at 297 K and 77 K and in the frequency range of 500 Hz-100 kHz using a capacitance bridge. A value of ?' = 10.9 ± 0.5 independent of frequency and temperature, is obtained. This value is consistent with the recent reflectivity measurements of Schlegel and Wachter.     

Investigations on order and width of RZ super Gaussian pulse in different WDM systems at 40 Gb/s using dispersion compensating fibers

In optical wavelength division multiplexed (WDM) systems the dispersion management is a key issue. In optical systems a lot of research is going on to reduce dispersion by selecting proper dispersion compensating techniques and proper modulation format for input data. One way to reduce dispersion is by using dispersion compensating fibers in the WDM systems. This paper analyzes the use of RZ super Gaussian pulse inputs for different WDM systems i.e. for conventional, dense and ultra dense WDM systems employing dispersion compensating fibers. The pulse width and the order of the RZ super Gaussian pulse was varied to evaluate the performance at 40 Gb/s. The experiment showed that to get minimum BER, pulse width of 7.5 ps and 10 ps along with third-order RZ super Gaussian pulse were found suitable and recommended to be used.     

Interface biquadratic coupling and magnon scattering in exchange-biased ferromagnetic thin films grown on epitaxial FeF2

The magnetic anisotropy of ferromagnetic (FM) Ni, Co, and Fe polycrystalline thin films grown on antiferromagnetic (AF) FeF(2)(110) epitaxial layers was studied, as a function of temperature, using ferromagnetic resonance. In addition to an in-plane anisotropy in the FM induced by fluctuations in the AF short-range order, a perpendicular (biquadratic) magnetic anisotropy, with an out-of-plane component, was found which increased with decreasing temperature above the AF Neél temperature (T(N) = 78.4 K). This is a surprising result given that the AF's uniaxial anisotropy axis was in the plane of the sample, but is consistent with prior experimental and theoretical work. The resonance linewidth had a strong dependence on the direction of the external magnetic field with respect to in-plane FeF(2) crystallographic directions, consistent with interface magnon scattering due to defect-induced demagnetizing fields. Below T(N), the exchange bias field H(E) measured via FMR for the Ni sample was in good agreement with H(E) determined from magnetization measurements if the perpendicular out-of-plane anisotropy was taken into account. A low field resonance line normally observed at H ≈ 0, associated with domain formation during magnetization in ferromagnets, coincided with the exchange bias field for T < T(N), indicating domain formation with the in-plane FM magnetization perpendicular to the AF easy axis. Thus, biquadratic FM-AF coupling is important at temperatures below and above T(N).     

Magnetic and high-pressure magnetotransport properties of cesium-substituted lanthanum calcium manganites

The nature of the double-exchange (DE) interaction in lanthanum manganites is studied through chemical substitutions, Cs for La, and high-pressure measurements. Static and high-frequency magnetic measurements and high-pressure electrical transport studies were carried out on bulk polycrystalline and radio-frequency sputtered thin films of La_0.7-xCs_xCa_0.3MnO₃ for x=0-0.1. The samples are found to be cubic. Curie temperature T_c measurements provide evidence for bond-length-related weakening of DE as x is increased from 0 to 0.03. For higher x, the bond-angle-related changes lead to an increase in the strength of DE. High-pressure mangetoresistance data indicate both bond length and bond-angle-related increase of 10–20 K/GPa in T_c with pressure, with the largest increase measured for x=0.03. The rate of increase in the Curie temperature with pressure decreases with increasing T_c. Anomalies are observed in the magnetic parameters for x=0.03. The Cs-concentration dependence of the low-temperature saturation magnetization shows a minimum close to x=0.03. Ferromagnetic resonance studies at x-band reveal a 5% decrease in the g-value for x=0.03 relative to the end members (x=0 and 0.1). The low-field magnetostriction for x=0.03 indicates a relatively strong electron–phonon spin coupling compared to neighboring compositions. Received: 15 May 2000 / Accepted: 24 July 2000 / Published online: 9 November 2000     

Critical-point anomaly in the EPR linewidth of two-dimensional antiferromagnets

Calculations are presented which satisfactorily explain the observed temperature and angular dependence of the EPR linewidth in the two-dimensional antiferromagnets Rb₂MnF₄ and K₂MnF₄ near T_N. These calculations are based on an earlier theory by Huber for the three-dimensional systems.