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排序方式: 共有537条查询结果,搜索用时 78 毫秒
1.
Inas A. Abdallah Sherin F. Hammad Alaa Bedair Mohamed A. Abdelaziz Neil D. Danielson Ahmed H. Elshafeey Fotouh R. Mansour 《Biomedical chromatography : BMC》2022,36(6):e5365
Favipiravir is a potential antiviral medication that has been recently licensed for Covid-19 treatment. In this work, a gadolinium-based magnetic ionic liquid was prepared and used as an extractant in dispersive liquid–liquid microextraction (DLLME) of favipiravir in human plasma. The high enriching ability of DLLME allowed the determination of favipiravir in real samples using HPLC/UV with sufficient sensitivity. The effects of several variables on extraction efficiency were investigated, including type of extractant, amount of extractant, type of disperser and disperser volume. The maximum enrichment was attained using 50 mg of the Gd-magnetic ionic liquid (MIL) and 150 μl of tetrahydrofuran. The Gd-based MIL could form a supramolecular assembly in the presence of tetrahydrofuran, which enhanced the extraction efficiency of favipiravir. The developed method was validated according to US Food and Drug Administration bioanalytical method validation guidelines. The coefficient of determination was 0.9999, for a linear concentration range of 25 to 1.0 × 105 ng/ml. The percentage recovery (accuracy) varied from 99.83 to 104.2%, with RSD values (precision) ranging from 4.07 to 11.84%. The total extraction time was about 12 min and the HPLC analysis time was 5 min. The method was simple, selective and sensitive for the determination of favipiravir in real human plasma. 相似文献
2.
Umie F.M. Haziz Rosenani A. Haque Shun-Ze Zhan Hassan H. Abdallah Mohd R. Razali 《应用有机金属化学》2020,34(10):e5818
The synthesis and characterizations for a series of dinuclear gold (I)-di-NHC complexes, 1–8 through the trans-metalation method of their respective silver (I)-di-NHC complexes, i–viii are reported (where NHC = N-heterocyclic carbene). The successful complexation of a series of unusual non-symmetrical and symmetrical di-NHC ligands, 3,3'-(ethane-1,2-diyl)-1-alkylbenzimidazolium-1'-butylbenzimidazolium (with alkyl = methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, benzyl) with the gold (I) ions are suggested by elemental analysis, Fourier transform-infrared, 1H- and 13C-NMR data. The 13C-NMR spectra of 1–8 show a singlet sharp peak in the range of 190.00–192.00 ppm, indicating the presence of a carbene carbon that bonded to the gold (I) ion. From single crystal X-ray diffraction data, the structure of complex 6 with the formula of [di-NHC-Au (I)]2·2PF6 is obtained [where NHC = 3,3'-(ethane-1,2-diyl)-1-hexylbenzimidazolium-1'-butylbenzimidazolium]. The photophysical study in solid state of 6 displays an intense photoluminescence with a strong emission maxima, λem = 480 nm, upon excitation at 340 nm at room temperature. Interestingly, the emission maximum at 77 K shows a structural character with a strong peak at 410 nm, a medium at 433 nm and a weak at 387 nm, accompanied by a tail band to about 500 nm. 相似文献
3.
The DELPHI Collaboration J. Abdallah et al. 《The European Physical Journal C - Particles and Fields》2003,27(2):153-172
A search for sleptons, neutralinos, charginos, sgoldstinos and heavy stable charged sleptons in the context of scenarios
where the lightest supersymmetric particle is the gravitino, is presented. Data collected during 2000 with the DELPHI detector
at centre-of-mass energies from 204 to 208 GeV were analysed and combined with all the data collected from 1995 to 1999 at
lower energies. No evidence for the production of sleptons, neutralinos and charginos has been found, therefore new limits
on the mass of these supersymmetric particles and on the model parameter space are set. The search for heavy stable charged
sleptons also updates the stable sleptons mass limit. The absence of evidence for sgoldstino production allows limits to be
set on its mass and on the scale of supersymmetry breaking.
Received: 6 November 2002 / Published online: 14 February 2003 相似文献
4.
Results are presented of an experimental investigation of vortex ring formation by a fluid drop contacting a free surface
with negligible velocity. The pool fluid is mixed with fluorescein dye, and a laser sheet is used to illuminate a plane of
the flow. A series of representative images is recorded by a CCD camera and speculation is made regarding specific sources
of vorticity flux through the free surface. Two scaling analyses previously presented by other investigators are demonstrated
to be equivalent under the assumptions of this experiment, and they provide the motivation for a series of test runs in which
the duration of the coalescence process, τ*, is related to variations in drop diameter L and fluid surface tension σ. Experimental results are in agreement with the analyses, showing τ*∼σ-1/2 and τ*∼L
3/2.
Received: 22 December 1995 / Accepted: 15 October 1996 相似文献
5.
6.
A. Gharib H. Rahimi H. Pyrovan N. J. Raoffi H. Taherpoor 《Journal of Radioanalytical and Nuclear Chemistry》1985,89(1):31-44
This work is part of a project with the IAEA, in a coordinated program on Trace Elements in Human and Bio-Environmental Systems to evaluate their nutritional requirements, interrelations and the role of trace elements in health, metabolism, etc. Cow's milk being regarded as one of the most important and nutritious foodstuffs consumed by people. Hence as a first step, an elemental analysis for milk was carried out for this purpose; a few samples of pasteurized milk and local sample were investigated for essential and toxic trace elements. The secondary aim of this project was the assessment of various analytical techniques involved. However, in the present work, the methods involved were AAS, PIXE and NAA. The latter method was applied both instrumentally and radiochemically. Although the results pertaining to the various methods employed are not in good agreement. there is, however, some justification to clarify this internal inconsistency. The precision of NAA and AAS allows a greater degree of acceptance. Although PIXE is very fast and rather routine, the technique for trace element analysis needs certain adaptations and development. 相似文献
7.
A. G. Gharib S. G. Mohseni M. Mohajer M. Gharib 《Journal of Radioanalytical and Nuclear Chemistry》2006,270(1):209-215
Summary Bioavailability and/or homeostasis of some essential trace elements such as zinc, iron, etc., in the presence of phytate,
fiber and calcium are subject to alteration. These factors were measured in this study for Iranian diets in a frame of a Coordinated
Research Project (CRP). However, the most prominent dietary factor in this regard is phytate. The phytate effect on zinc homeostasis
is a chemical phenomenon dependent physiologically on pH in the gastrointestinal tract at or near the sites of absorption.
Calcium is a synergistic coprecipitating factor in the complexation of zinc by phytate. Fiber has also a tendency to absorb
insoluble compounds in gastrointestinal tract including zinc, iron and many other trace elements. One of the most known clinical
observations regarding zinc deficiency was found in the rural area of the Fars province of Iran in the late 1950s at Shiraz
University. However, the molar ratio of [phytate] : [zinc] and [calcium] [phytate] : [zinc] in Iranian Diets in a recent study
are 7-17 and 150-800, respectively. The critical ratios of [phytate] : [zinc] of 10 or less will provide adequate zinc to
sustain homeostasis. 相似文献
8.
Abdallah Aissa Michel Gruselle René Thouvenot Rainer Traksmaa 《Journal of solid state chemistry》2007,180(8):2273-2278
The reaction between phenyl phosphonic dichloride (C6H5P(O)Cl2) and synthetic calcium hydroxy- and fluorapatite has been investigated. The presence of mono- or polymeric (C6H5PO) fragment bound to hydroxyapatite was evidenced by IR, and solid-state 31P NMR spectroscopy. X-ray powder analysis has shown that the apatitic structure remains unchanged during the reaction. In contrast, no reaction was found using fluorapatite. According to the results found for these two different apatites a mechanism was proposed for the formation of covalent P-O-P bonds as the result of a reaction between the C6H5P(O)Cl2 organic reagent and (HPO4)− and/or OH− ions of the hydroxyapatite. 相似文献
9.
Three pyochelin analogues and their methyl esters all containing a thiazole ring have been synthesised from the same Weinreb amide key intermediate. One of these analogues called HPTT-COOH, a molecule released in the course of pyochelin and yersiniabactin biosynthesis, was efficiently synthesised using a new base induced conversion of the key compound 2′-(2-hydroxyphenyl)-2′-thiazoline-4′-(N-methoxy,N-methyl) carboxamide into 2′-(2-hydroxyphenyl)-2′-thiazole-4′-(N-methoxy,N-methyl) carboxamide. 相似文献
10.
An energy-transport model is rigorously derived from the Boltzmann transport equation of semiconductors under the hypothesis that the energy gain or loss of the electrons by the phonon collisions is weak. Retaining at leading order electron-electron collisions and elastic collisions (i.e., impurity scattering and the elastic part of phonon collisions), a rigorous diffusion limit of the Boltzmann equation can be carried over, which leads to a set of diffusion equations for the electron density and temperature. The derivation is given in both the degenerate and nondegenerate cases. 相似文献