Large magnetic field effect on back electron transfer from uncharged radical to its cationic partner in anionic micelle

The magnetic field effect (MFE) on the radical pair (RP) generated by photoexcitation of the acetyl derivative of phenyl pyrylium ion (APP⁺) in the presence of biphenyl, an electron donor, has been investigated. The escape yield at 3.5 T is more than ten times the zero-field value. The MFE reaches near-saturation twice, once at fields of the order of 10mT and again at about 3.5 T. The low-field variation of the MFE conforms to the pattern expected for the isotropic HFC mechanism, and the high-field variation to that expected for the relaxation mechanism. In this particular system two types of radical pair are generated, one by electron transfer from the donor to the acceptor and another by H-abstraction from the micelle. The MFEs on the two types of ³RP have been compared.     

Nonplanar ion-acoustic shocks in electron–positron–ion plasmas: Effect of superthermal electrons

Ion-acoustic shock waves (IASWs) in a homogeneous unmagnetized plasma, comprising superthermal electrons, positrons, and singly charged adiabatically hot positive ions are investigated via two-dimensional nonplanar Kadomstev–Petviashvili–Burgers (KPB) equation. It is found that the profiles of the nonlinear shock structures depend on the superthermality of electrons. The influence of other plasma parameters such as, ion kinematic viscosity and ion temperature, is discussed in the presence of superthermal electrons in nonplanar geometry. It is also seen that the IASWs propagating in cylindrical/spherical geometry with transverse perturbation will be deformed as time goes on.     

Effect of nonthermal distributed electrons and temperature on phase shifts during the collision of inward and outward ion-acoustic solitary waves in nonplanar geometry

Interaction of nonplanar ion-acoustic solitary waves is an important source of information for studying the nature and characteristics of ion-acoustic solitary waves (IASWs). The head-on collision between two cylindrical/spherical IASWs in un-magnetized plasmas comprising of nonthermal distributed electrons and warm ions is investigated using the extended version of Poincaré–Lighthill–Kuo (PLK) perturbation method. How the interactions are taking place in cylindrical and spherical geometries are shown numerically. Analytical phase shifts are derived for nonplanar geometry. The effects of the ion to electron temperature parameter and the nonthermal electrons parameter on the phase shift are studied. It is shown that the properties of the interaction of IASWs in different geometries are very different.     

Relativistic models of a class of compact objects

A class of general relativistic solutions in isotropic spherical polar coordinates which describe compact stars in hydrostatic equilibrium are discussed. The stellar models obtained here are characterized by four parameters, namely, ??, k, A and R of geometrical significance related to the inhomogeneity of the matter content of the star. The stellar models obtained using the solutions are physically viable for a wide range of values of the parameters. The physical features of the compact objects taken up here are studied numerically for a number of admissible values of the parameters. Observational stellar mass data are used to construct suitable models of the compact stars.     

Quantitative assessment of target dependence of pion fluctuation in hadronic interactions – estimation through erraticity

Event-to-event fluctuation pattern of pions produced by proton and pion beams is studied in terms of the newly defined erraticity measures χ(p, q), $\chi_q^{\prime}$ and $\mu_q^{\prime}$ proposed by Cao and Hwa. The analysis reveals the erratic behaviour of the produced pions signifying the chaotic multiparticle production in high-energy hadron–nucleus interactions (π ^???–AgBr interactions at 350 GeV/c and p–AgBr interactions at 400 GeV/c). However, the chaoticity does not depend on whether the projectile is proton or pion. The results are compared with the results of the VENUS-generated data for the above interactions which suggests that VENUS event generator is unable to reproduce the event-to-event fluctuations of spatial patterns of final states. A comparative study of p–AgBr interactions and p–p collisions at 400 GeV/c from NA27, with the help of a quantitative parameter for the assessment of pion fluctuation, indicates conclusively that particle production process is more chaotic for hadron–nucleus interactions than for hadron–hadron interactions.     

Rapidity dependence of multiplicity fluctuations and correlations in high-energy nucleus–nucleus interactions

The multiplicity fluctuations of the produced pions were studied using scaled variance method in ¹⁶O–AgBr interactions at 2.1 AGeV, ²⁴Mg–AgBr interactions at 4.5 AGeV, ¹²C–AgBr interactions at 4.5 AGeV, ¹⁶O–AgBr interactions at 60 AGeV and ³²S–AgBr interactions at 200 AGeV at two different binning conditions. In the first binning condition, the rapidity interval was varied in steps of one centring about the central rapidity until it reached 14. In the second case, the rapidity interval was increased in steps of 1.6 up to 14.4. Multiplicity distributions and their scaled variances were presented as a function of the dependence on the rapidity width for both the binning conditions. Multiplicity fluctuations were found to increase with the increase of rapidity interval and later found to saturate at larger rapidity window for all the interactions and in both the binning conditions. Multiplicity fluctuations were found to increase with the energy of the projectile beam. The values of the scaled variances were found to be greater than one in all the cases in both the binning conditions indicating the presence of correlation during the multiparticle production process in high-energy nucleus–nucleus interactions. Experimental results were compared with the results obtained from the Monte Carlo simulated events for all the interactions. The Monte Carlo simulated data showed very small values of scaled variance suggesting very small fluctuations for the simulated events. Experimental results obtained from ¹⁶O–AgBr interactions at 60 AGeV and ³²S–AgBr interactions at 200 AGeV were compared with the events generated by Lund Monte Carlo code (FRITIOF model). FRITIOF model failed to explain the multiplicity fluctuations of pions emitted from ¹⁶O–AgBr interactions at 60 AGeV for both the binning conditions. However, the experimental data agreed well with the FRITIOF model for ³²S–AgBr interactions at 200 AGeV.     

Quantum effects at low-energy atom–molecule interface

The effects of quantum interference in inter-conversion between cold atoms and diatomic molecules are analysed in this study. Within the framework of Fano’s theory, continuum-bound anisotropic dressed state formalism of atom–molecule quantum dynamics is presented. This formalism is applicable in photo- and magneto-associative strong-coupling regimes. The significance of Fano effect in ultracold atom–molecule transitions is discussed. Quantum effects at low-energy atom–molecule interface are important for exploring coherent phenomena in hitherto unexplored parameter regimes.     

Adsorption of Hydrazoic Acid on Pristine Graphyne Sheet: A Computational StudySCI北大核心CSCD

Herein we have investigated the interaction between hydrazoic acid(HN3) and a pristine graphyne system based on density functional theory(DFT) method using generalized gradient approximation. The van der Waals dispersion correction is also considered for predicting the possibility of using the graphyne system for detection of hydrazoic acid. Pristine graphyne has a band gap of 0.453 eV, which decreases to 0.424 eV when HN3 is adsorbed on graphyne. The electrical conductivity of HN3-adsorbed graphyne is greater than that of its pristine counterpart. Charge transfer analysis reveals that the HN3-adsorbed graphyne system behaves as an n-type semiconductor; however, its pristine analogue acts as an intrinsic semiconductor. Pristine graphyne has zero dipole moment; however, its interaction with HN3 increases its dipole moment. The electronic properties of graphyne is significantly influenced by the presence of HN3, leading to the possibility of designing graphyne-based sensors for HN3 detection.