软硬酸碱理论的发展和应用

从软硬酸碱理论的起源出发,简要介绍软硬酸碱理论的建立背景、发展过程,并对其可能的应用范围做了讨论.最后结合人们对于软硬酸碱理论的认识和应用现状,做出总结和评价.     

Development of mean-field electrical double layer theory

In order to understand the electric interfacial behavior, mean field based electric double layer(EDL) theory has been continuously developed over the past 150 years. In this article, we briefly review the development of the EDL model, from the dimensionless Gouy–Chapman model to the symmetric Bikerman–Freise model, and finally toward size-asymmetric mean field theory models. We provide the general derivations within the framework of Helmholtz free energy of the lattice–gas model, and it can be seen that the above-mentioned models are consistent in the sense that the interconversion among them can be achieved by reducing the basic assumptions.