基于空间结构内部锁相的光纤激光相干合成技术

介绍了本课题组近年来在基于空间结构内部锁相的光纤激光相干合成方面的研究工作,给出了空间结构内部锁相相干合成的基本原理,搭建了七路低功率光纤激光阵列实验系统,结果表明在内部相位噪声校正基础之上,可以稳定补偿外部相位差进而实现激光阵列同相位输出,验证了内部锁相方法的可行性。进一步介绍了空间结构内部锁相技术在目标在回路相干合成、阵列光束光场调控等方面的拓展应用,通过实验论证了空间结构内部锁相技术能够有效提升目标在回路相干合成系统的相位控制带宽,并在远场有效生成轨道角动量光束阵列,其拓扑荷数可从-1到+1切换。     

一类特殊二次规划最优解的性质

本文研究了一类特殊二次规划最优解的性质.利用凸分析的方法,得到了该类二次规划问题解的存在性,唯一性及其结构.文中结果推广了模松弛QP子问题的有关结论,并在更多的QP子问题中有着潜在的应用.     

异丙醇添加剂在钙钛矿太阳能电池中的应用

有机-无机混合铅卤钙钛矿由于其具有可溶液加工、强吸收、高迁移率等优点,近年来被广泛关注。引入异丙醇作为钙钛矿前驱液的添加剂用一步法旋涂制备出具有大晶粒尺寸的钙钛矿薄膜。用此方法制作钙钛矿太阳能电池并探究最优的异丙醇掺杂浓度。基于异丙醇体积分数为6%的钙钛矿电池性能最高,能量转换效率达到14.6%,比不使用添加剂的对比器件提高了40%。     

1.5kW全光纤线偏振激光器

报道了一台全光纤结构的1.5kW线偏振光纤激光器。激光器采用振荡器结合一级放大的主振荡功率放大器(MOPA)方案。振荡器中心波长为1080nm,工作时输出功率30 W,经放大器一级放大后实现近衍射极限输出,功率达到1.5kW,光-光效率81.5%,消光比13.8dB。这是目前线偏振光纤激光器输出功率的最高值。     

Passive Coherent Beam Combining Four Channels of Nanosecond Pulsed Laser Using All-Fiber Feedback Loop

We present an all-fber configuration of passive beam combining using an all-fber feedback loop and demonstrate passive coherent combining of a four-channel nanosecond pulsed laser. The output power, pulse characteristics, polarization extinction ratio and far field laser intensities of the combined output laser are investigated. The experimental results validate that passive phasing using an all-fiber feedback loop provides a simple while robust method for coherent beam combining of pulsed lasers. If replacing the fiber coupler used into a high power tapered fused bundle fiber combiner, this scheme ispromising to scale the output power up to the kW level.     

新试剂4,4′-二（4-苯偶氮苯氨基重氮基）二苯醚与镉（Ⅱ）的显色反应

研究了新显色剂4,4′-二（4-苯偶氮苯氨基重氮基）二苯醚（PPDPE）与镉（）的显色反应。在Triton X-100存在下,于pH10.22的硼砂-氢氧化钠缓冲溶液中,镉（）与4,4′-二（4-苯偶氮苯氨基重氮基）二苯醚形成摩尔比1∶2的红色络合物,试剂及络合物的最大吸收波长分别为400nm和530nm,表观摩尔吸光系数为2.05×105L.mol-1.cm-1,镉（）含量在0—10.0μg/25mL范围内符合比耳定律。方法用于废水中镉的测定,结果满意。     

Comparative study on the power scaling performance of three different coherent polarization beam combination system structures

Coherent polarization beam combination (CPBC) is a new kind of coherent beam combination configuration with high combining efficiency and excellent beam quality. In order to extend the CPBC system to a large scale, we provide a comparative study on the power scaling performance of three different coherent polarization beam combination system structures. It is found that the pairwise structure has high tolerance to aberrations and has the potential to extend to a large scale with high combining efficiency. In consideration of all the aberrations, the combining efficiency of the pairwise structure can be attained as high as 90% when the combined beams are more than 200. Some instructive suggestions are given to extend the CPBC system to a large scale.     

Conformation effects on the molecular orbitals of serine

This paper calculates the five most stable conformers of serine with Hartree--Fock theory, density functional theory (B3LYP), Moller--Plesset perturbation theory (MP4(SDQ)) and electron propagation theory with the 6-311++G(2d,2p) basis set. The calculated vertical ionization energies for the valence molecular orbitals of each conformer are in agreement with the experimental data, indicating that a range of molecular conformations would coexist in an equilibrium sample. Information of the five outer valence molecular orbitals for each conformer is explored in coordinate and momentum spaces using dual space analysis to investigate the conformational processes, which are generated from the global minimum conformer Ser1 by rotation of C₂--C₃ (Ser4), C₁--C₂ (Ser5) and C₁--O₂ (Ser2 and Ser3). Orbitals 28a, 27a and 26a are identified as the fingerprint orbitals for all the conformational processes.