水热法制备Mn掺杂ZnO及其光催化性能研究

ZnO是一类具有广阔应用前景的光催化材料,但是光生载流子复合率高等问题限制了其进一步应用.本研究使用水热法制备了Mn掺杂ZnO粉体,测试了该粉体的物相组成、孔隙结构、发光性质和光催化性能.结果表明,当Mn替代0.5;Zn时,Mn占据了ZnO晶格中Zn的位置,粉体粒度小、比表面积大,抑制了光生载流子的复合,降低了禁带宽度,拓宽了光的响应范围.在8 W、365 nm紫外光条件下光照70 min后,制备的Mn0.05 Zn0.95 O粉体对刚果红降解率达到了97.4;,COD去除率达到了76.34;;Mn0.05 Zn0.95 O对罗丹明B吸附最好,对亚甲基蓝降解最好;对刚果红连续降解4个循环后,降解率降低了6.6;.该研究成果为光催化降解有机废水提供了技术支撑.     

Compact high-power mode-locked Nd：YVO4 picosecond laser using multiple-pass cavity

A stable self-starting mode-locked Nd:YVO4 laser with a Herriott-type multiple-pass cavity(MPC) operating at 1 064 nm is demonstrated.An in-band 880-nm laser diode is used as an end-pump and a semiconductor saturable absorber mirror(SESAM) is used for passive mode locking(ML) and providing pulse durations of 14 ps.At a pump power of 26.4 W,the maximum average output power is as high as 10.5 W at a repetition rate of 22 MHz,which corresponds to a single pulse energy of 0.48 μJ.Optical-tooptical conversion efficiency is as high as 39.8% at the maximum output power with a slope efficiency of 55.2%.