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排序方式: 共有108条查询结果,搜索用时 31 毫秒
1.
V. Hamplov A. Bubnov M. Ka par V. Novotn D. Pociecha M. Glogarov 《Liquid crystals》2003,30(5):627-631
A new series of chiral liquid crystalline materials having the same rigid core containing a keto group, and various numbers of ( S )-lactate groups in the chiral segment, has been synthesized and studied. All the compounds contain a branched terminal alkyl chain derived from ( S )-2-methylbutanol. The influence of the number of lactate units on mesogenic behaviour has been studied. All the compounds show the paraelectric SmA phase and the ferroelectric SmC * phase over rather wide temperature ranges. The antiferroelectric SmC * A phase was observed for the compound possessing two lactate groups. 相似文献
2.
par Jean-michel Vierfohd Yvette Mettey Line Mascrier-Demagny Marcel Miocque 《Tetrahedron letters》1981,22(13):1219-1222
An original one-pot ayntheais of 4,7-diazaindoles is achieved by metalation of methylpyrazines or methylquinoxaline wich are then condensed with an aromatic nitrile: an intermediate imine-enamine is formed which leads, by intramolecular cyclization, to diazaindoles. 相似文献
3.
Dusanka Ž. Obadović Anikó Vajda Maya Garić A. Bubnov Vera Hamplová M. Kašpar Katalin Fodor-Csorba 《Journal of Thermal Analysis and Calorimetry》2005,80(2):519-523
Summary Thermal properties of a homologous series of ferroelectric liquid crystals S-(-)-[4-(2-n-alkoxy-propionyloxy)]biphenyl-4'-[n-alkoxy-(3,5-dimethyl)]benzoate have been investigated by polarizing optical microscopy and differential scanning calorimetry.
The mesophases were identified and confirmed by X-ray too. Three binary mixtures were prepared from the individual homologues.
In one of the mixtures (Mix1), the ferroelectric SmC* phase has broadened and became enantiotropic. This mesophase remained
monotropic in the other two mixtures (Mix2, Mix3). The chiral nematic N* phase did not appear in Mix1, but remained monotropic
for the other two mixtures. Two molecular parameters, the layer spacing and the average intermolecular distance have been
calculated from the X-ray results for the homologues and their mixtures. An intercalated tail-to-tail packing of molecules
was found both in the single compounds and their mixtures resulting in the layer spacing about half of the molecular length
of the single compounds. 相似文献
4.
Oscillating Chemical Reactions. III. Effects of the Temperature and Chemical Composition on the ‘Induction Period’ of the BrO /Ce4+/Cyclohexanon and BrO /Ce4+/Cyclopentanon Systems A study of the influence of the temperature and composition of the BrO/Ce4+/cyclohexanon (S1) and BrO/Ce4+/cyclopentanon (S2) systems has shown a very particular behaviour for τind. for a given ratio α of concentrations: Moreover, for 0.27 ? α ? 0.32, log1/τind. is no longer a linear function of the inverse of the temperature: a break in the line log1/τind. = f(1/T) occurs. 相似文献
5.
Hajer Bahouri Clotilde Fermanian-Kammerer Isabelle Gallagher 《Comptes Rendus Mathematique》2012,350(7-8):393-397
We construct a Littlewood–Paley decomposition associated to a Rockland operator on graded Lie groups, which allows us to deduce refined Gagliardo–Nirenberg, Sobolev and Hardy inequalities. 相似文献
6.
New series of liquid crystals with an alkyl-lactate chiral chain and four aromatic rings in the mesogenic core and chloro-substitution were synthesized. For all the compounds studied, SmA and SmC* phases, existing over very broad temperature ranges, were detected and characterized. Mesomorphic properties were analysed with respect to the lengths of the chiral and/or non-chiral chains. 相似文献
7.
Věra Hamplová Alexej Bubnov Corresponding author Miroslav Kašpar Vladimíra Novotná Yveta Lhotáková Milada Glogarová 《Liquid crystals》2013,40(12):1463-1469
New chiral liquid crystalline materials containing a keto group and two lactate units attached to the mesogenic core have been synthesized and studied. All the new compounds show the paraelectric SmA, ferroelectric SmC* and antiferroelectric SmC*A phases each over rather broad temperature ranges. The properties of the phases were characterized by DSC, electro-optical and dielectric studies. The spontaneous polarization, tilt angle, helical pitch, and switching times were determined for the polar phases. 相似文献
8.
Vladimíra Novotná Věra Hamplová Miroslav Kašpar Milada Glogarová Karel Knížek Siegmar Diele 《Liquid crystals》2013,40(8):967-975
New mesogens composed of achiral bent molecules with thermally stable ester linkages, and laterally substituted by a methoxy group symmetrically near the central benzene ring, were synthesized. Texture, calorimetric, electro‐optical, X‐ray and dielectric measurements were performed. In most of studied compounds the antiferroelectric B2 phase was found on cooling from the isotropic phase, followed by the B7 phase at lower temperatures. Undulation of layers in the B7 phase was confirmed by precise synchrotron studies. 相似文献
9.
Alexey Bobrovsky Valery Shibaev Věra Hamplová Miroslav Kašpar Vladimira Novotna Milada Glogarová 《Liquid crystals》2013,40(9):989-997
A photoinduced phase transition and helix untwisting in a new liquid crystal forming the SmC* phase were studied in detail. The compound consists of a cinnamoyl photosensitive fragment with C?=?C double bond capable of photoisomerisation and photocycloaddition. It was shown that ultraviolet (UV) irradiation (365 nm) induces an extreme decrease in phase transitions temperatures (SmC*–SmA*, SmA*–N*, N*–I). Vertically aligned samples in the SmC* phase cause selective light reflection in the visible spectral range. The light action results in a noticeable helix untwisting that causes a shift in the selective light reflection peak to the long-wavelength spectral region. The temperature dependence of spontaneous polarisation P s was measured and it was found that UV irradiation induces a decrease in the values of P s. Photo-optical phenomena taking place in the liquid crystal are attributed to the formation of photoproducts having low anisometry, which disrupts mesophases. 相似文献
10.
The iron silicides samples were prepared by annealing of iron films evaporated onto silicon wafers and capped with amorphous silicon thin overlayers. Semiconducting FeSi2 phase is formed by annealing at the temperatures from 550°C to 850°C. The optical properties of the FeSi2 layers have been deduced from reflectance and transmittance measurements carried out in the temperature range of (77–380) K. The spectral dependence of the absorption coefficient favours direct allowed transitions with forbidden energy gap of 0.87eV at the room temperature. The application of a simple three-parameter semiempirical formula to the temperature dependence of the direct energy gaps leads to the following best fit parameters: the band gap at zero temperature E
g (0) = (0.895 ± 0.004)eV, the dimensionless coupling parameter S = 2.0 ± 0.3, and the average phonon energy <hw> = (46 ± 8)meV. By examining all the reported triplets of parameters for -FeSi2 fabricated by different techniques and thermal processes, an obvious discrepancy can be found for the lattice coupling parameter and average phonon energy, although the bandgaps at 0 K are very similar. Unlike the theoretical prediction and the earlier reported result, our results do not show any evidence of a particularly strong electron-phonon interaction, which would give the lower carrier mobilities. -FeSi2 seems to be an intriguing material where states with energies near the band edges permit ambiguous interpretation of the character of transitions. From optical model for the thin film-substrate system we found the index of refraction to be (5–5.9) in the photon energy interval from 0.65 to 1.15eV. There is also indication of an additional higher-energy absorption edge at l.05eV. 相似文献