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1.
2, 3, 4-Trimethoxybenzaldehyde, -acetophenone and -benzoic acid give the corresponding 2, 3-dihydroxy-4-methoxy compounds in good yield on treatment with BCl3. 相似文献
2.
Aurelia Visa Nicoleta Plesu Bianca Maranescu Gheorghe Ilia Ana Borota Luminita Crisan 《Molecules (Basel, Switzerland)》2021,26(1)
The inhibition effect of N,N′-phosphonomethylglycine (PMG) and vinyl phosphonic acid (VPA) on the 3% NaCl acidic solution corrosion of carbon steel iron was studied at different immersion times by potentiodynamic polarization, electrochemical impedance spectroscopy, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, and computational methods. It is found from the polarization studies that PMG and VPA behave as mixed-type inhibitors in NaCl. Values of charge transfer resistance (Rct) and double layer capacitance (Cdl) in the absence and presence of inhibitors are determined. The PMG and VPA inhibitors were capable of inhibiting the corrosion process up to ≈91% and ≈85%, respectively. In the presence of PMG, the synergic effect of chlorine ions was observed. Density functional theory (DFT) was engaged to establish the adsorption site of PMG, VPA, and their deprotonated states. For studied compounds, the resulted values of ELUMO, EHOMO, energy gap (∆E), dipole moment (μ), electronic hardness (η), global softness (σ), electrophilic index (ω), and the electronic potential map are in concordance with the experimental data results regarding their corrosion inhibition behavior and adsorption on the metal surface. 相似文献
3.
Smaranda Iliescu Lavinia Macarie Adriana Popa Aurelia Visa Bianca Maranescu 《Phosphorus, sulfur, and silicon and the related elements》2014,189(7-8):992-1003
AbstractTwo new series of solid polymer electrolytes (SPEs) based on phosphorus containing (co)polyesters (PPE) and Lithium triflate were obtained. PPEs are composed of phosphonate moeties (cyclohexyldichlorophosphonate (CHDP)) as linking agent and two diols: PEG (6000) and poly(tetramethylene glycol) (PTMG) in PPE I, and PEG (6000) and 4,4′-cyclohexylidenebisphenol (bisphenol Z, BZ) in PPE II. Polycondensation was carried out in solution in the presence of triethylamine (TEA) as scavenger of HCl side product (PPE I–IIa) and in the absence of any acid acceptor (PPE I–IIb). The Limiting Oxygen Index (LOI) and thermal analysis were performed both on polymers and membranes. The ionic conductivity of SPE membranes based on PPE-salt complexes, with various salt concentrations, was investigated at different temperature and ionic transference numbers were determined. Optimum composition was obtained for the polymer which contains in structure only alkyl units and 15% Lithium triflate. 相似文献
4.
We prove the Cartan and Choquet properties for the fine topology on a complete metric space equipped with a doubling measure supporting a p-Poincaré inequality, 1 < p < ∞. We apply these key tools to establish a fine version of the Kellogg property, characterize finely continuous functions by means of quasicontinuous functions, and show that capacitary measures associated with Cheeger supersolutions are supported by the fine boundary of the set. 相似文献
5.
Gheorghe Ilia Smaranda Iliescu Adriana Popa Aurelia Visa Bianca Maranescu Vasile Simulescu 《高分子科学杂志,A辑:纯化学与应用化学》2016,53(1):49-54
This paper presents for the first time the synthesis of poly(alkylene-H-phosphonate)s by one-pot tandem reaction of hypophosphorous acid and ethylene glycol. Zirconium oxychloride was used as esterification catalyst, Nickel vinylphosphonate, Nickel sulfate, Nickel chloride hexahydrate were used as transfer hydrogenation catalyst. Nickel vinylphosphonate was synthesized in our laboratory and used for the first time as catalyst in this process. The compounds were characterized by 1H-NMR, 13C-NMR and 31P-NMR spectroscopy. Molar masses were determined by SEC-MALLS technique and depend on the catalyst used. The obtained poly(alkylene-H-phosphonate)s have molar masses between 1.50 and 11.85 kDa, higher than those obtained by other methods mentioned in the literature. 相似文献
6.
We prove Harnack's inequality for first eigenfunctions of the p-Laplacian in metric measure spaces. The proof is based on the famous Moser iteration method, which has the advantage that it only requires a weak (1,p)-Poincaré inequality. As a by-product we obtain the continuity and the fact that first eigenfunctions do not change signs in bounded domains. 相似文献
7.
Sirkka-Liisa Eriksson Marko Kotilainen Visa Latvala 《Advances in Applied Clifford Algebras》2007,17(3):425-436
Harmonic functions with respect to the Poincare metric on the unit ball are called hyperbolic harmonic functions. We establish
the weak formulation of hyperbolic harmonic functions and use it in the study of hyperbolic harmonic function spaces. In particular,
we give the Carleson measure characterization for the whole spectrum of spaces, whose analytic counterparts include among
else Bloch spaces, Bergman-spaces, Besov-spaces, and Qp-spaces.
The second author was supported by the Finnish Cultural Foundation. 相似文献
8.
Visa Latvala 《Arkiv f?r Matematik》2003,41(1):95-104
The continuity of weak solutions of elliptic partial differential equations
is considered under minimal structure assumptions. The main result guarantees the continuity at the pointx
0 for weakly monotone weak solutions if the structure ofA is controlled in a sequence of annuli
with uniformly bounded ratioR
j
/r
j
such that lim
j→∞
R
j
=0. As a consequence, we obtain a sufficient condition for the continuity of mappings of finite distortion. 相似文献
9.
In this article, we describe the different methods to simulate Multi-Conjugate Adaptive Optics (MCAO) systems. First, analytical (error-budget type) and semi-analytical (Fourier) methods are described. We then describe the different modules required to make end-to-end (Monte Carlo) simulations of these systems. Finally, we present some of the computational challenges associated with the simulation of MCAO on Extremely Large Telescopes (ELTs). To cite this article: M. Le Louarn et al., C. R. Physique 6 (2005). 相似文献
10.
B. Maranescu A. Visa G. Ilia 《Phosphorus, sulfur, and silicon and the related elements》2014,189(7-8):1004-1012
AbstractThe synthesis of a new metal phosphonate and the influence of pH on its crystallinity is presented. Cobalt styrylphosphonate was synthesized by 2 methods (75°C, 180°C) at pH 1.5, 2, 2.4, 2.8, and 3.2, and its crystallinity was confirmed by X-ray powder diffraction. 相似文献