Apolar 2‐alkoxyalkoxy‐substituted nematic liquid crystals

The synthesis is reported of a series of apolar nematic liquid crystals incorporating an alkoxyalkoxy chain attached in a terminal position to the molecular core. The dependence of the mesomorphism and phase transition temperatures on the nature of the terminal chain with one, two or three oxygen atoms was studied. Some compounds with a completely alicyclic molecular core and a terminal 2‐methoxyethoxy chain exhibit a nematic phase with a low melting point, birefringence and viscosity and a relatively high clearing point in the absence of smectic phases. They do not to absorb light in the near UV and may be useful as components of UV‐stable nematic mixtures for use in photoluminescent liquid crystal displays. The presence of the methoxyethoxy chain leads to a relatively large dipole moment perpendicular to the molecular long axis.     

Nematic Liquid Crystals with a Trifluoromethyl Group

Abstract

We have synthesised a new class of compounds incorporating a trifluoromethyl group in the terminal alkoxy or alkenyloxy chain. Compounds containing several aromatic rings were synthesised with a view to producing compounds of high birefringence. This also included the synthesis of compounds containing a carbon-carbon triple bond. Compounds with three 1,4-disubstituted rings were synthesised in order to produce materials with a high nematic clearing point and as low a melting point as possible. Laterally fluoro-substituted compounds were prepared to generate a high positive value of the dielectric anisotropy, a low melting point and no smectic mesophases. Substances containing a cyclohexyl ring, which tend to induce a lower viscosity and compounds incorporating a bicyclo[2.2.2]octane ring were also synthesised in order to produce a high nematic clearing point and to influence the elastic constants. The (E)-trifluorobut-2-enyloxy-compounds were prepared in attempts to produce compounds with appropriate elastic constants and a high birefringence.     

Competition among providers in loss networks

Communication networks are becoming ubiquitous and more and more competitive among revenue-maximizing providers, operating on potentially different technologies. In this paper, we propose to analyze thanks to game theory the competition of providers playing with access prices and fighting for customers. Considering a slotted-time model, the part of demand exceeding capacity is lost and has to be resent. We consider an access price for submitted packets, thus inducing a congestion pricing through losses. Customers therefore choose the provider with the cheapest average price per correctly transmitted unit of traffic. The model is a two-level game, the lower level for the distribution of customers among providers, and the upper level for the competition on prices among providers, taking into account what the subsequent repartition at the lower level will be. We prove that the upper level has a unique Nash equilibrium, for which the user repartition among different available providers is also unique, and, remarkably, efficient in the sense of social welfare (with a so-called price of anarchy equal to one). Moreover, even when adding a higher level game on capacity disclosure with a possibility of lying for providers, providers are better off being truthful, and the unique Nash equilibrium is thus unchanged.     

An Optimal Congestion and Cost-sharing Pricing Scheme for Multiclass Services

We study in this paper a social welfare optimal congestion-pricing scheme for multiclass queuing services which can be applied to telecommunication networks. Most of the literature has focused on the marginal price. Unfortunately, it does not share the total cost among the different classes. We investigate here an optimal Aumann–Shapley congestion-price which verifies this property. We extend the work on the Aumann–Shapley price for priority services, based on the results on the marginal price: instead of just determining the cost repartition among classes for given rates, we obtain the rates and charges that optimize the social welfare.     

Etude de l'energie des electrons ejectes au cours de l'ionisation penning de l'hydrogene moleculaire par les etats metastables 21S et 23S de l'helium

The authors report experiments on the Penning ionization of molecular hydrogen by metastable helium (2¹S and 2³S states). The vibrational structure of the H₂⁺ ion in the state X²Σ_g⁺ is resolved. The relative population of the three first vibrational levels is obtained. The authors also show that a continuum is superposed on the Penning ionization due to the autoionization process.     

End-to-end availability-dependent pricing of network services

We discuss how a new pricing scheme can be integrated within a communication network. The pricing scheme is based on the availability of end-to-end communications, and is an alternative to congestion pricing, which is not applicable when communication capacity is higher than demand (as happens in most communication backbone networks). We also investigate how, based on this scheme, an optimization algorithm for updating the network topology can be applied. The network update problem is modeled as a combinatorial optimization problem, which is approximately solved using a Genetic Algorithm. The good results obtained in a case study show that the method is robust and can be applied even when end-to-end availability measures can only be computed approximately (in this case, using a Monte Carlo method). This research is part of the PAIR associated research project, supported by the INRIA, France, and has also received the support of ECOS-Sud, under Action U03E02. The participation of Pablo Rodríguez was supported by the French Embassy in Uruguay as part of the French Ministère des Affaires étrangères scientific cooperation program; and by the “Programa de Jóvenes Investigadores” of CSIC, UDELAR, Uruguay.     

A fluid queue driven by a Markovian queue

We consider an infinite buffer fluid queue receiving its input from the output of a Markovian queue with finite or infinite waiting room. The input is characterized by a Markov modulated rate process. We derive a new approach for the computation of the stationary buffer content. This approach leads to a numerically stable algorithm for which the precision of the result can be given in advance. This revised version was published online in June 2006 with corrections to the Cover Date.     

Aromatic liquid crystals with a trifluoromethyl group in the terminal chain for use in nematic LC mixtures

A new class of compounds suitable for LCD applications has have synthesized, incorporating a trifluoromethyl group in the terminal alkoxy or alkenyloxy chain. These compounds fulfil many of the specifications for use in TN-LCDs. Compounds containing several aromatic rings were synthesized with a view to producing compounds of high birefringence. This aspect also included the synthesis of compounds containing a carbon-carbon triple bond. Materials with three phenyl rings were also prepared in an attempt to produce nematic liquid crystals with a high clearing point and a high birefringence. Molecules containing a lateral fluoro substituent were synthesized in order to generate a high positive value of the dielectric anisotropy, a low melting point and no smectic mesophases. A series of compounds incorporating a carbon-carbon double bond was prepared in an attempt to produce compounds with a high nematic clearing point and a high birefringence.     

Terminal trifluoromethyl-alkoxy and-alkenyloxy nematic liquid crystals for LCDs with active matrix addressing

We have synthesized a new class of compounds suitable for LCD applications, incorporating a trifluoromethyl group in the terminal alkoxy- or alkenyloxy-chain. These compounds appear to fulfil many of the requirements for use in TN-LCDs. Core units containing a cyclohexyl ring, which tend to induce a lower viscosity than that of the analogous aromatic materials, were synthesized. Systems containing several aromatic rings were also prepared with a view to producing compounds of high birefringence. Compounds containing a lateral fluorosubstituent as well as a polar substituent in a terminal position were synthesized in order to generate a high positive value of the dielectric anisotropy. Molecules incorporating a bicyclo[2.2.2]octane ring were also synthesized in order to produce a high nematic clearing point and to influence the elastic constants. Compounds with three 1,4-disubstituted rings were synthesized with a view to producing materials with a high nematic clearing point and as low a melting point as possible. A series of compounds with a carbon-carbon double bond in the terminal chain was prepared in an attempt to produce compounds with appropriate values and ratios of the elastic constants.     

Apolar 2-alkoxyalkoxy-substituted nematic liquid crystals

The synthesis is reported of a series of apolar nematic liquid crystals incorporating an alkoxyalkoxy chain attached in a terminal position to the molecular core. The dependence of the mesomorphism and phase transition temperatures on the nature of the terminal chain with one, two or three oxygen atoms was studied. Some compounds with a completely alicyclic molecular core and a terminal 2-methoxyethoxy chain exhibit a nematic phase with a low melting point, birefringence and viscosity and a relatively high clearing point in the absence of smectic phases. They do not to absorb light in the near UV and may be useful as components of UV-stable nematic mixtures for use in photoluminescent liquid crystal displays. The presence of the methoxyethoxy chain leads to a relatively large dipole moment perpendicular to the molecular long axis.