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排序方式: 共有96条查询结果,搜索用时 15 毫秒
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Ramanan Krishnamoorti William W. Graessley Achim Zirkel Dieter Richter Nikos Hadjichristidis Lewis J. Fetters David J. Lohse 《Journal of Polymer Science.Polymer Physics》2002,40(16):1768-1776
The unperturbed chain dimensions (〈R2〉o/M) of cis/trans‐1,4‐polyisoprene, a near‐atactic poly(methyl methacrylate), and atactic polyolefins were measured as a function of temperature in the melt state via small‐angle neutron scattering (SANS). The polyolefinic materials were derived from polydienes or polystyrene via hydrogenation or deuteration and represent structures not encountered commercially. The parent polymers were prepared via lithium‐based anionic polymerizations in cyclohexane with, in some cases, a polymer microstructure modifier present. The polyolefins retained the near‐monodisperse molecular weight distributions exhibited by the precursor materials. The melt SANS‐based chain dimension data allowed the evaluation of the temperature coefficients [dln 〈R2〉o/dT(κ)] for these polymers. The evaluated polymers obeyed the packing length (p)‐based expressions of the plateau modulus, G = kT/np3 (MPa), and the entanglement molecular weight, Me = ρNanp3 (g mol?1), where nt denotes the number (~21) of entanglement strands in a cube with the dimensions of the reptation tube diameter (dt) and ρ is the chain density. The product np3 is the displaced volume (Ve) of an entanglement that is also expressible as pd or kT/G. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 1768–1776, 2002 相似文献
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Flash DSC crystallization study for blown film grade bimodal HDPE resins. I. Isothermal kinetics and its application of the blown film modeling 下载免费PDF全文
Cecilia D. Treviño‐Quintanilla Ramanan Krishnamoorti Jaime Bonilla‐Ríos 《Journal of Polymer Science.Polymer Physics》2016,54(23):2425-2431
Isothermal ultra‐cooling crystallization tests were conducted on three blown film grade bimodal HDPE resins using an ultrafast scanning calorimeter, the Flash DSC. Isothermal tests were performed to study the regime transition, the thermal nucleation and the spherulitical growth using the Hoffman‐Lauritzen theory in a range between 90 °C and 116 °C. Temperature profile estimations using such data were in good agreement with actual blown film process data. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 2425–2431 相似文献
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Ramanan Pitchumani Nishant Gupta GabrielM.H. Meesters Brian Scarlett 《Particle & Particle Systems Characterization》2003,20(5):323-326
Particle breakage can be characterised as attrition, chipping, fracture, abrasion and wear. All these types of breakage mechanisms are the effect of the damage caused to these particles. These mechanisms can be differentiated not just on the basis of magnitude and direction of the force but also by the damage caused to the particles. The damage is measured by change in the size distribution and the change in shape of the particles. In the current research, experiments were performed on the newly developed Repeated Impact Test. The unique feature of this test is that about hundred particles can be subjected simultaneously to a monitored number of impacts, without particle‐particle interactions at regulated velocities. The preliminary experiments were performed with single crystalline particles of different shapes and sizes. After fixed number of impacts, the images of the particles were taken. The volume and shape of the particles were determined by image analysis. It was observed that the rate of attrition was very high when the particles are irregular. The rate decreased as the particles became more spherical. 相似文献
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A general third-order dynamical system with polynomial right-hand sides of finite degrees in the dependent variables is analyzed to unravel the singularity structure of its solutions about a movable singular point. To that end, the system is first transformed to a second-order Briot–Bouquet system and a third auxiliary equation via a transformation, similar to one used earlier by R. A. Smith in 1973–1974 for a general second-order dynamical system. This transformation imposes some constraints on the coefficients appearing in the general third-order system. The known results for the second-order Briot–Bouquet system are used to explicitly write out Laurent or psi-series solutions of the general third-order system about a movable singularity. The convergence of the relevant series solutions in a deleted neighborhood of the singularity is ensured. The theory developed here is illustrated with the help of the May–Leonard system. 相似文献
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Generalized processor sharing has been proposed as a policy for distributing processing in a fair manner between different
data classes in high-speed networks. In this paper we show how recent results on the Skorokhod Problem can be used to construct
and analyze the mapping that takes the input processes into the buffer content. More precisely, we show how to represent the
map in terms of a Skorokhod Problem, and from this infer that the mapping is well defined (existence and uniqueness) and well
behaved (Lipschitz continuity). As an elementary application we present some large deviation estimates for a many data source
model.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
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We have measured the permeability of rhodamine-6G across Cx43 hemichannels reconstituted on a pipette tip. Cx43 hemichannels
were overexpressed in Sf9 cells, and affinity-purified. The hemichannels were reconstituted in a lipid bilayer on a pipette
tip by the tip-dip method. R6G in the pipette permeated across the channels into the bath. The permeability of R6G was quantified
by measuring R6G concentration in the bath after several hours by surface enhanced Raman spectroscopy (SERS) with 100 nm silver
colloid particles. The ratio of the permeability of dye to salt, as extracted by this combined electrical-SERS technique,
is compatible with similar ratios for other dyes across whole gap junction channels. The results for the permeability ratio
were further compared to fluorescence measurements. The novel combination of patch and SERS techniques can be extended to
quantifying the transport of biologically significant non-fluorescent molecules, such as cAMP and IP3, across 1 nm sized pores,
such as the gap junction channel. 相似文献