Bis(2-hydroxyacetophenone)ethylenediimine as a neutral carrier in a coated-wire membrane electrode for lead(II).

A coated-wire ion-selective electrode (CWISE), based on a Schiff base as a neutral carrier, was successfully developed for the detection of Pb(II) in aqueous solution. CWISE exhibited a linear response with a Nernstian slope of 29.4 +/- 0.5 mV/decade within the concentration range of 1.0 x 10(-5) - 1.0 x 10(-1) M lead ion. CWISE has shown detection limits of 5.0 x 10(-6) M. The electrode exhibited good selectivity over a number of alkali, alkaline earth, transition and heavy metal ions. This sensor yielded a steady potential within 10 to 20 s at a linear dynamic range. The electrode was suitable for use in aqueous solutions in a pH range of 2.0 to 5.0. Applications of this electrode for the determination of lead in real samples and as indicator electrode for potentiometric titration of Pb2+ ion using K2CrO4 are reported.     

Droplet formation in quickly stretched liquid filaments

Film splitting necessarily occurs in roll coating and unwanted droplets can occur at high machine speeds when the resulting filaments break up. To study this ‘misting’ problem, an apparatus was designed and built to simulate filament fluid mechanics. The device creates a filament by elongating a liquid bridge and stretches the filament at a high and constant rate of acceleration to mimic coating machine kinematics. Filament breakup was observed using a high-speed video camera and the images were analyzed to yield droplet size and number. With Newtonian fluids, a single droplet formed at Ohnesorge (Oh) numbers less than 0.1 and more and smaller droplets were produced at Oh numbers above 0.1. Associative polymer solutions, prepared as weakly elastic fluids to represent industrial coatings, produced even more and smaller droplets, but only for Ohnesorge numbers in the range of 0.01 to 0.1.     

BPS Quivers and Spectra of Complete {\mathcal{N} = 2} Quantum Field Theories

We study the BPS spectra of ${\mathcal{N}=2}$ N = 2 complete quantum field theories in four dimensions. For examples that can be described by a pair of M5 branes on a punctured Riemann surface we explain how triangulations of the surface fix a BPS quiver and superpotential for the theory. The BPS spectrum can then be determined by solving the quantum mechanics problem encoded by the quiver. By analyzing the structure of this quantum mechanics we show that all asymptotically free examples, Argyres-Douglas models, and theories defined by punctured spheres and tori have a chamber with finitely many BPS states. In all such cases we determine the spectrum.     

A kinetic study of the electron-transfer in the reaction of tribenzylchlorotin with[CoW_(12)O_(40)]~(5-)

A kinetic study of the electron-transfer in the reaction of tribenzylchlorotin with potassium 12-tungsto cobalt(Ⅲ) ate ion, K_5[CoW_(12)O_(40)],abbreviated as Co(Ⅲ)W,has been performed in different solvents.The studies were carried out in methanol, ethanol,acetonitrile and acetic acid/water.The rate constants,reaction rates and activation parameters were calculated. Our findings show that the rate of disappearance of the Co(Ⅲ) is pseudo-first order.The kinetic data is strongly affected by used solvents.T...     

Anomaly driven signatures of new invisible physics at the Large Hadron Collider

Many extensions of the Standard Model (SM) predict new neutral vector bosons at energies accessible by the Large Hadron Collider (LHC). We study an extension of the SM with new chiral fermions subject to non-trivial anomaly cancellations. If the new fermions have SM charges, but are too heavy to be created at LHC, and the SM fermions are not charged under the extra gauge field, one would expect that this new sector remains completely invisible at LHC. We show, however, that a non-trivial anomaly cancellation between the new heavy fermions may give rise to observable effects in the gauge boson sector that can be seen at the LHC and distinguished from backgrounds.