全文获取类型
收费全文 | 1750篇 |
免费 | 75篇 |
国内免费 | 16篇 |
专业分类
化学 | 1069篇 |
晶体学 | 34篇 |
力学 | 72篇 |
数学 | 286篇 |
物理学 | 380篇 |
出版年
2023年 | 11篇 |
2022年 | 27篇 |
2021年 | 47篇 |
2020年 | 47篇 |
2019年 | 59篇 |
2018年 | 56篇 |
2017年 | 61篇 |
2016年 | 81篇 |
2015年 | 58篇 |
2014年 | 76篇 |
2013年 | 178篇 |
2012年 | 126篇 |
2011年 | 154篇 |
2010年 | 93篇 |
2009年 | 102篇 |
2008年 | 111篇 |
2007年 | 112篇 |
2006年 | 74篇 |
2005年 | 66篇 |
2004年 | 52篇 |
2003年 | 45篇 |
2002年 | 40篇 |
2001年 | 12篇 |
2000年 | 12篇 |
1999年 | 6篇 |
1998年 | 9篇 |
1997年 | 8篇 |
1996年 | 15篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1993年 | 12篇 |
1992年 | 11篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 10篇 |
1983年 | 4篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1977年 | 2篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1970年 | 1篇 |
1967年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有1841条查询结果,搜索用时 972 毫秒
1.
Elnaz Marzi Khosrowshahi Behnaz Limuie Khosrowshahi Mir Ali Farajzadeh Abolghasem Jouyban Mustafa Tuzen Mohammad Reza Afshar Mogaddam Mahboob Nemati 《Biomedical chromatography : BMC》2022,36(7):e5371
A dispersive solid-phase extraction method based on a new sorbent has been performed on plasma and wastewater samples to determine metoprolol by high-performance liquid chromatography–tandem mass spectrometry. In this study, the analyte was adsorbed from the samples onto microcrystalline cellulose as a green and efficient sorbent and then eluted for use in the determination step. In the mass spectrometer, the analyte was detected in the positive mode and selectivity of the analysis was increased by sequential mass analysis through multiple reaction monitoring. All of the effective parameters in the extraction of metoprolol from plasma and wastewater were optimized. Under optimal conditions the method was linear in the ranges of 1–1,000 and 0.1–1,000 ng/ml in plasma and wastewater samples, respectively. The detection limits of the method were 0.30 and 0.03 ng/ml in plasma and wastewater samples, respectively. The data showed that the method provides low detection limit, wide linear range, good precision and high extraction recovery. Finally several plasma and wastewater samples were successfully analyzed using the method. The use of a small amount of a green and inexpensive sorbent and a low volume of plasma without the need for further pretreatment steps are the main advantages of the method. 相似文献
2.
3.
The electrochemical reduction of 1-([(4-halophenyl)imino]methyl)-2-naphthols on graphite electrodes was studied using cyclic voltammetry, chronoamperometry, constant-potential coulometry and preparative constant-potential electrolysis techniques. The data revealed that the reduction on graphite was irreversible and followed an EC mechanism. The diffusion coefficients and the number of electrons transferred were determined using the chronoamperometric Cottrell slope and the ultramicro disc Pt-electrode steady-state current. The number of electrons was also determined by bulk electrolysis. The compounds were subjected to constant-potential preparative electrolysis and the electrolysis products were purified and identified by spectroscopic methods. Based on these findings, a mechanism for the electro-reduction process is proposed. 相似文献
4.
The feasibility of using bis(delta2-2-imidazolinyl)-5,5'-dioxime (H2L) for the selective extraction of iron(III) from aqueous solutions was investigated by employing an solvent-extraction technique. The extraction of iron(III) from an aqueous nitrate solution in the presence of metal ions, such as cobalt(II), copper(II) and nickel(II), was carried out using H2L in binary and multicomponent mixtures. Iron(III) extraction has been studied as a function of the pH, equilibrium time and extractant concentration. From the extracted complex species in the organic phase, iron(III) was stripped with 2 M HNO3, and later determined using atomic-absorption spectrometry. The extraction was found to significantly depend on the aqueous solution pH. The extraction of iron(III) with H2L increases with the pH value, reaching a maximum in the zone of pH 2.0, remaining constant between 2 and 3.5 and subsequently decreasing. The quantitative extraction of iron(III) with 5 x 10(-30 M H2L in toluene is observed at pH 2.0. H2L was found to react with iron(III) to form ligand complex having a composition of 1:2 (Fe:H2L). 相似文献
5.
Mustafa Çelebier Ertan Şahin Nilgün Ancın Nurşen Altuntaş Öztaş Selma Gül Öztaş 《应用有机金属化学》2007,21(10):viii-viii
The article referenced above was first published online on 30 August 2007 with incorrect pagination; the pagination has now been corrected online and in print. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
6.
Mohamed Hilmy Elnagdi Ramadan Maawad Abdel-Motaleb Mona Mustafa Mohamed Foad Zayed Eman Moustafa Kamel 《Journal of heterocyclic chemistry》1987,24(6):1677-1681
The behaviour of several 2-amino-3-cyano-4H-pyran derivatives toward a variety of nucleophilic reagents is reported. 相似文献
7.
Ghulam Mustafa 《数学研究及应用》2003,23(3):413-421
本文引入了一种满足更一般的收缩不等式的多重函数类,并证明了属于该类的可测多重函数对的一些随机重合点定理。 相似文献
8.
Munshi G. Mustafa 《Pramana》2006,66(4):669-687
We briefly introduce the thermal field theory within imaginary time formalism, the hard thermal loop perturbation theory and
some of its applications to the physics of the quark-gluon plasma, possibly created in relativistic heavy-ion collisions 相似文献
9.
The synthesis of chiral oxazolidinedione derived bicalutamide analogs has been discussed. 相似文献
10.
E. Alper Yildirim Xiaofei Fan-Orzechowski 《Computational Optimization and Applications》2006,33(2-3):229-247
We study the maximum stable set problem. For a given graph, we establish several transformations among feasible solutions
of different formulations of Lovász's theta function. We propose reductions from feasible solutions corresponding to a graph
to those corresponding to its induced subgraphs. We develop an efficient, polynomial-time algorithm to extract a maximum stable
set in a perfect graph using the theta function. Our algorithm iteratively transforms an approximate solution of the semidefinite
formulation of the theta function into an approximate solution of another formulation, which is then used to identify a vertex
that belongs to a maximum stable set. The subgraph induced by that vertex and its neighbors is removed and the same procedure
is repeated on successively smaller graphs. We establish that solving the theta problem up to an adaptively chosen, fairly
rough accuracy suffices in order for the algorithm to work properly. Furthermore, our algorithm successfully employs a warm-start
strategy to recompute the theta function on smaller subgraphs. Computational results demonstrate that our algorithm can efficiently
extract maximum stable sets in comparable time it takes to solve the theta problem on the original graph to optimality.
This work was supported in part by NSF through CAREER Grant DMI-0237415. Part of this work was performed while the first author
was at the Department of Applied Mathematics and Statisticsat Stony Brook University, Stony Brook, NY, USA. 相似文献