全文获取类型
收费全文 | 90篇 |
免费 | 1篇 |
国内免费 | 2篇 |
专业分类
化学 | 40篇 |
力学 | 10篇 |
数学 | 24篇 |
物理学 | 19篇 |
出版年
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 1篇 |
2019年 | 2篇 |
2018年 | 4篇 |
2017年 | 1篇 |
2016年 | 7篇 |
2015年 | 5篇 |
2014年 | 9篇 |
2013年 | 5篇 |
2012年 | 2篇 |
2011年 | 6篇 |
2010年 | 5篇 |
2009年 | 3篇 |
2008年 | 5篇 |
2007年 | 3篇 |
2006年 | 8篇 |
2005年 | 3篇 |
2004年 | 2篇 |
2003年 | 3篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1974年 | 3篇 |
1973年 | 3篇 |
1965年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有93条查询结果,搜索用时 15 毫秒
1.
Interpretation of contact angle measurements on two different fluoropolymers for the determination of solid surface tension 总被引:2,自引:0,他引:2
Tavana H Simon F Grundke K Kwok DY Hair ML Neumann AW 《Journal of colloid and interface science》2005,291(2):497-506
Contact angle measurements with a large number of liquids on the semi-fluorinated acryl polymer EGC-1700 films are reported. The surface tension was determined to be gammasv=13.84 mJ/m2 from contact angles of octamethylcyclotetrasiloxane (OMCTS) and decamethylcyclopentasiloxane (DMCPS). Inertness of these two liquids makes them ideal for determination of surface tension of low-energy fluoropolymers. On the other hand, contact angles of many other liquids deviated somewhat from a smooth contact angle pattern that represents the EGC-1700 surface tension. It is argued that noninertness of the molecules of these liquids gives rise to specific interactions with the polymer film, causing the deviations. Furthermore, contact angles of a series of n-alkanes (n-hexane to n-hexadecane) showed systematic deviations from this curve, similar to the trend observed for n-alkanes/Teflon AF 1600 systems studied earlier. Adsorption of vapor of short-chain liquids onto the polymer film caused their contact angles to fall above the gammasv=13.84 mJ/m2 curve, and a parallel alignment of molecules of the long-chain n-alkanes in the vicinity of the solid was the explanation for the deviation of their contact angles below it. It is found that vapor adsorption effect is more significant in the case of Teflon AF 1600, while the alignment of liquid molecules close to the surface is more pronounced for EGC-1700. 相似文献
2.
Bounouri Yassine Berkani Madjid Zamouche Abdelmalek Dańczak Anna Chojnacka Ida Rycerz Leszek 《Journal of Thermal Analysis and Calorimetry》2018,134(3):1589-1597
Thixoforming involves heating different types of alloys to the semisolid state at high heating rates and forming in die-casting machines or conventional presses. At temperatures higher than the solidus and lower than the liquidus, the mush metal behaves like a high-viscosity thixotropic material. Therefore, determining the thermodynamic behavior of the solid-to-liquid transition is paramount to control thixoforming processes. This article describes a simple, novel experimental setup based on differential thermal analysis (DTA) for analyzing the phase transitions in an alloy heated using high heating rates typical of industrial applications. A365 alloy was chosen to demonstrate the effectiveness of the method as the phase transformations for this alloy in semisolid materials (SSM) processing are well understood. Samples were heated to 750 °C using constant linear heating rates of 5, 10, 15, 20, 25, 50, 75, 100 and 125 °C min in a Norax 25 kW 8 kHz induction furnace with an Omron E5CK temperature controller. AISI 316 austenitic stainless steel was used as the inert reference. Comparison of the results of DTA using the proposed method and the results of simulation with Thermo-Calc® indicates that the proposed in situ DTA device and its method is suitable for analyzing phase transitions when high heating rates are used. 相似文献
3.
4.
This paper proposes a new multi-criteria decision analysis (MCDA) model that uses a series of existing intuitive and analytical
methods to systematically capture both objective and subjective beliefs and preferences from a group of decision makers (DMs).
A defuzzification method that combines entropy and the theory of displaced ideal synthesizes crisp values from the DMs’ subjective
judgments. This approach assists the DMs in their selection process by plotting alternatives in a four quadrant graph and
considering their Euclidean distance from the “ideal” choice. A pilot study illustrates the details of the proposed method.
The DMs were a group of graduate students from the University of Paderborn in Germany. The pilot study concerned the addition
of new members into the European Union (EU), a decision that has profound economic and political effects on both the entering
and existing members of the Union. The DMs were required to consider a large number of internal strengths and weaknesses and
external opportunities and threats in assessing the decision to enlarge the EU. Although the pilot study was not performed
by actual DMs from the EU, it was an excellent platform for testing the proposed model. 相似文献
5.
6.
The emission of electrons from hot silicon surfaces is reviewed in an effort to present a summary of the state of research in this field. The theoretical aspect of the problem is outlined briefly, and experimental results covering the temperature and field dependence of the saturation current density, as well as the anisotropy and the energy distribution of the emission are presented. 相似文献
7.
8.
9.
Madjid Hadioui Med Oimar Mecherri Rastislav Šípoš Yan Yvon Patrick Sharrock 《Chemical Papers》2011,65(6):855-862
Glycidoxypropyltriethoxysilane (GPS) was used as a reactive silane to graft metal- complexing ligands onto silica gel in aqueous
media under mild conditions. The synthesis entailed the reaction of GPS with silica gel, followed by grafting polyamine onto
the epoxy functional group. GPS was added to silica gel in ethanol with 5 vol. % water and the mixture was air-dried for 24
h. Subsequently, excess amounts of polyamines: triethylenetetramine, tetraethylenepentamine, and pentaethylenehexamine were
individually added to the silanised silica, followed by solvent evaporation and ovendrying at 60°C. The ligand-grafted silica
gel particles showed a rapid heavy metal uptake in batch or flow-through experiments with capacities reaching 0.1 mmol g−1 for copper, zinc, cadmium, or lead ions. Columns packed with the modified particles could be readily regenerated by acid-washing
with only a small decrease in activity. The particles could be used for the colourimetric detection of heavy metal pollution
or for pre-concentration for analytical purposes. Competition between Cu2+, Zn2+, Pb2+, and Cd2+ ions for the three synthesised silica showed that Cu2+ ions were adsorbed more strongly than the other metal ions. The general method developed can be applied to graft other molecules
with terminal amino groups for other purposes. 相似文献
10.
H. Khosroabadi A. Tavana M. Akhavan 《The European Physical Journal B - Condensed Matter and Complex Systems》2006,51(2):161-165
Ab initio total energy calculations have been performed for superconducting
GdBa2Cu3O7 and insulating PrBa2Cu3O7 using the
full-potential linear augmented plane-wave method in the local density
approximation (LDA) and generalized gradient approximation (GGA). The
comparison of the calculated unit cell volume and lattice parameters with
the experimental data indicates the improvement of these parameters in the
GGA relative to LDA. LDA and GGA give the equilibrium unit cell volume about
6% smaller and 1.25% larger than the experimental data, respectively
for both systems. Thus frozen phonon calculations have been performed to
determine the eigenvalues and eigenvectors of the k=0 Ag modes of the
two systems in equilibrium structure have been obtained in GGA. The
calculated frequencies in the GGA are in good agreement with the other LDA
calculations for similar systems. Comparison of computational data with
experimental data indicates that calculations determine the frequencies
about ten percent below the experimental data. Even by improving LDA to GGA
in these calculations, the calculated phonon frequencies have remained
almost ten percent below the experimental data, even though the calculated
unit cell volumes are nearly equal to the experimental data. So, applying
GGA has not considerably decreased the difference between the computational
and experimental data. The effect of Pr doping on the eigenvalues and
eigenvectors have also been investigated. 相似文献