Charge manipulation and imaging of the Mn acceptor state in GaAs by cross-sectional scanning tunneling microscopy

An individual Mn acceptor in GaAs is mapped by cross-sectional scanning tunneling microscopy (X-STM) at room temperature and a strongly anisotropic shape of the acceptor state is observed. An acceptor state manifests itself as a cross-like feature which we attribute to a valence hole weakly bound to the Mn ion forming the (Mn²⁺3d⁵+hole) complex. We propose that the observed anisotropy of the Mn acceptor wavefunction is due to the d-wave present in the acceptor ground state.     

Detection of genetically modified corn (Bt176) in spiked cow blood samples by polymerase chain reaction and immunoassay methods

The fate of DNA and protein transgenic sequences in products derived from animals fed transgenic crops has recently raised public interest. Sensitive molecular tests targeting the Bt176 genetic construct and the transgenic Cry1Ab protein were developed to determine whether plant sequences, especially transgenic sequences, are present in animal products. A protocol for total DNA extraction and purification from cow whole blood samples was first drawn up and assessed by spiking with known amounts of DNA from Bt176 maize. The limit of detection for transgenic sequences (35S promoter and Bt176-specific junction sequence) was determined by both the polymerase chain reaction-enzyme-linked immunosorbent assay (PCR-ELISA) and the 5'-nuclease PCR assay. Four additional PCR systems were built to substantiate the results. The first detects a mono-copy maize-specific sequence (ADH promoter). Two others target multi-copy sequences from plant nucleus (26S rRNA gene) and chloroplast (psaB gene). The last one, used as a positive control, targets a mono-copy animal sequence (alpha(s1)-casein gene). Both methods detected a minimum spiking at 25 copies of Bt176 maize/mL in 10 mL whole blood samples. The sandwich ELISA kit used detected down to 1 ng transgenic Cry1Ab protein/mL spiked whole blood.     

Oscillatory persistent currents in self-assembled quantum rings

We report the direct measurement of the persistent current carried by a single electron by means of magnetization experiments on self-assembled InAs/GaAs quantum rings. We measured the first Aharonov-Bohm oscillation at a field of 14 T, in perfect agreement with our model based on the structural properties determined by cross-sectional scanning tunneling microscopy measurements. The observed oscillation magnitude of the magnetic moment per electron is remarkably large for the topology of our nanostructures, which are singly connected and exhibit a pronounced shape asymmetry.     

Real-space measurement of the potential distribution inside organic semiconductors

We demonstrate that the soft nature of organic semiconductors can be exploited to directly measure the potential distribution inside such an organic layer by scanning-tunneling microscope (STM) based spectroscopy. Keeping the STM feedback system active while reducing the tip-sample bias forces the tip to penetrate the organic layer. From an analysis of the injection and bulk transport processes it follows that the tip height versus bias trace obtained in this way directly reflects the potential distribution in the organic layer.     

Spatial distribution of a hole localized on acceptor in deformed crystal

The influence of the host-crystal deformation on the acceptor wave-function in a cubic crystal is considered. The calculations are based on the numerical solution of the Luttinger Hamiltonian for a hole in a complex valence band. The deformation is taken into account using Bir-Pikus Hamiltonian for the deformation. The results can be used for the interpretation of the STM images in strained cubic crystals.     

High-throughput protein precipitation and hydrophobic interaction chromatography: salt effects and thermodynamic interrelation

Salt-induced protein precipitation and hydrophobic interaction chromatography (HIC) are two widely used methods for protein purification. In this study, salt effects in protein precipitation and HIC were investigated for a broad combination of proteins, salts and HIC resins. Interrelation between the critical thermodynamic salting out parameters in both techniques was equally investigated. Protein precipitation data were obtained by a high-throughput technique employing 96-well microtitre plates and robotic liquid handling technology. For the same protein-salt combinations, isocratic HIC experiments were performed using two or three different commercially available stationary phases-Phenyl Sepharose low sub, Butyl Sepharose and Resource Phenyl. In general, similar salt effects and deviations from the lyotropic series were observed in both separation methods, for example, the reverse Hofmeister effect reported for lysozyme below its isoelectric point and at low salt concentrations. The salting out constant could be expressed in terms of the preferential interaction parameter in protein precipitation, showing that the former is, in effect, the net result of preferential interaction of a protein with water molecules and salt ions in its vicinity. However, no general quantitative interrelation was found between salting out parameters or the number of released water molecules in protein precipitation and HIC. In other words, protein solubility and HIC retention factor could not be quantitatively interrelated, although for some proteins, regular trends were observed across the different resins and salt types.     

Complete characterisation of the customer delay in a queueing system with batch arrivals and batch service

Whereas the buffer content of batch-service queueing systems has been studied extensively, the customer delay has only occasionally been studied. The few papers concerning the customer delay share the common feature that only the moments are calculated explicitly. In addition, none of these surveys consider models including the combination of batch arrivals and a server operating under the full-batch service policy (the server waits to initiate service until he can serve at full capacity). In this paper, we aim for a complete characterisation—i.e., moments and tail probabilities - of the customer delay in a discrete-time queueing system with batch arrivals and a batch server adopting the full-batch service policy. In addition, we demonstrate that the distribution of the number of customer arrivals in an arbitrary slot has a significant impact on the moments and the tail probabilities of the customer delay.     

Delay analysis of two batch-service queueing models with batch arrivals: Geo X /Geo c /1

In this paper, we compute the probability generating functions (PGF’s) of the customer delay for two batch-service queueing models with batch arrivals. In the first model, the available server starts a new service whenever the system is not empty (without waiting to fill the capacity), while the server waits until he can serve at full capacity in the second model. Moments can then be obtained from these PGF’s, through which we study and compare both systems. We pay special attention to the influence of the distribution of the arrival batch sizes. The main observation is that the difference between the two policies depends highly on this distribution. Another conclusion is that the results are considerably different as compared to Bernoulli (single) arrivals, which are frequently considered in the literature. This demonstrates the necessity of modeling the arrivals as batches.     

Controlled charge switching on a single donor with a scanning tunneling microscope

The charge state of individually addressable impurities in semiconductor material was manipulated with a scanning tunneling microscope. The manipulation was fully controlled by the position of the tip and the voltage applied between tip and sample. The experiments were performed at low temperature on the (110) surface of silicon doped GaAs. Silicon donors up to 1 nm below the surface can be reversibly switched between their neutral and ionized state by the local potential induced by the tip. By using ultrasharp tips, the switching process occurs close enough to the impurity to be observed as a sharp circular feature surrounding the donor. By utilizing the controlled manipulation, we were able to map the Coulomb potential of a single donor at the semiconductor-vacuum interface.     

Inequalities for Quantum Skew Information

We study quantum information inequalities and show that the basic inequality between the quantum variance and the metric adjusted skew information generates all the multi-operator matrix inequalities or Robertson type determinant inequalities studied by a number of authors. We introduce an order relation on the set of functions representing quantum Fisher information that renders the set into a lattice with an involution. This order structure generates new inequalities for the metric adjusted skew informations. In particular, the Wigner–Yanase skew information is the maximal skew information with respect to this order structure in the set of Wigner–Yanase–Dyson skew informations.