首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   32252篇
  免费   1679篇
  国内免费   851篇
化学   22044篇
晶体学   261篇
力学   679篇
综合类   66篇
数学   5645篇
物理学   6087篇
  2023年   258篇
  2022年   264篇
  2021年   557篇
  2020年   665篇
  2019年   642篇
  2018年   735篇
  2017年   668篇
  2016年   1323篇
  2015年   1091篇
  2014年   1193篇
  2013年   2189篇
  2012年   2341篇
  2011年   2415篇
  2010年   1527篇
  2009年   1383篇
  2008年   2020篇
  2007年   2007篇
  2006年   1776篇
  2005年   1573篇
  2004年   1411篇
  2003年   1040篇
  2002年   898篇
  2001年   626篇
  2000年   561篇
  1999年   448篇
  1998年   298篇
  1997年   283篇
  1996年   355篇
  1995年   248篇
  1994年   277篇
  1993年   238篇
  1992年   234篇
  1991年   209篇
  1990年   207篇
  1989年   179篇
  1988年   161篇
  1987年   156篇
  1986年   146篇
  1985年   215篇
  1984年   213篇
  1983年   136篇
  1982年   138篇
  1981年   150篇
  1980年   149篇
  1979年   106篇
  1978年   103篇
  1977年   109篇
  1976年   87篇
  1975年   93篇
  1973年   75篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
Enhancement of axial magnetic anisotropy is the central objective to push forward the performance of Single-Molecule Magnet (SMM) complexes. In the case of mononuclear lanthanide complexes, the chemical environment around the paramagnetic ion must be tuned to place strongly interacting ligands along either the axial positions or the equatorial plane, depending on the oblate or prolate preference of the selected lanthanide. One classical strategy to achieve a precise chemical environment for a metal centre is using highly structured, chelating ligands. A natural approach for axial-equatorial control is the employment of macrocycles acting in a belt conformation, providing the equatorial coordination environment, and leaving room for axial ligands. In this review, we present a survey of SMMs based on the macrocycle belt motif. Literature systems are divided in three families (crown ether, Schiff-base and metallacrown) and their general properties in terms of structural stability and SMM performance are briefly discussed.  相似文献   
3.
Meccanica - In this work we study, from the numerical point of view, a one-dimensional thermoelastic problem where the thermal law is of type III. Quasi-static microvoids are also assumed within...  相似文献   
4.
Central European Journal of Operations Research - Sustainability practice within supply chains remains in an early development phase. Enterprises still need tools that support the integration of...  相似文献   
5.
Set-Valued and Variational Analysis - In a Hilbert framework ℌ, we study the convergence properties of a Newton-like inertial dynamical system governed by a general maximally monotone...  相似文献   
6.
7.
氧化铝晶体是一种优良的光学透明窗口材料,更是地球内部的重要组成物质.利用气炮加载结合冲击光谱测量,不仅能够获得其发光特征,并且根据光谱分布特征得到高压结构相变信息.在自主搭建的冲击光谱动态测试平台上,结合多通道辐射高温计以及ICCD瞬态光谱测试技术在40~120 GPa的压力区间,研究了c切向氧化铝晶体的辐射发光效应.在可见光波段400~700 nm区间获得了氧化铝晶体的发光光谱和辐射温度结果,证实了光谱的结构特征和表观温度值与该压力下氧化铝的结构相变存在明显的关联性.  相似文献   
8.
9.
A sensitive, specific and reproducible HPLC method has been developed and validated for the quantitative determination of 6‐methylcoumarin (6MC) in plasma and other tissues in Wistar rats. A C18 column was used with UV detection at 321 nm and a gradient system consisting of methanol‐deionized water was used as mobile phase. The retention time for 6MC was 14.921 min and no interfering peaks were observed for any of the matrices. Linear relationships (r2 > 0.997) were obtained between the peak height ratios and the corresponding biological sample concentrations over the range 0.4–12.8 µg/mL. Precision and accuracy were evaluated; the coefficient of variation and the relative error for all of the organs were <2 and 7%, respectively. The limit of quantitation was 0.20 µg/mL for the heart and 0.30 µg/mL for the other tissues evaluated. This HPLC method was successfully used in the determination of 6MC in the biodistribution study after administration of 200 mg/kg of both 6MC‐free and 6MC‐loaded polymeric microparticles. In this study, extensive 6MC was found, in both free and microencapsulated forms, in all the organs tested. The 6MC‐free showed a range of between 1.7 and 11.5 µg/g, while the microencapsulated 6MC showed concentrations of between 6.35 and 17.7 µg/g, suggesting that 6MC improved absorption rate. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
10.
Enantiopure β‐amino acids represent interesting scaffolds for peptidomimetics, foldamers and bioactive compounds. However, the synthesis of highly substituted analogues is still a major challenge. Herein, we describe the spontaneous rearrangement of 4‐carboxy‐2‐oxoazepane α,α‐amino acids to lead to 2′‐oxopiperidine‐containing β2,3,3‐amino acids, upon basic or acid hydrolysis of the 2‐oxoazepane α,α‐amino acid ester. Under acidic conditions, a totally stereoselective synthetic route has been developed. The reordering process involved the spontaneous breakdown of an amide bond, which typically requires strong conditions, and the formation of a new bond leading to the six‐membered heterocycle. A quantum mechanical study was carried out to obtain insight into the remarkable ease of this rearrangement, which occurs at room temperature, either in solution or upon storage of the 4‐carboxylic acid substituted 2‐oxoazepane derivatives. This theoretical study suggests that the rearrangement process occurs through a concerted mechanism, in which the energy of the transition states can be lowered by the participation of a catalytic water molecule. Interestingly, it also suggested a role for the carboxylic acid at position 4 of the 2‐oxoazepane ring, which facilitates this rearrangement, participating directly in the intramolecular catalysis.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号