全文获取类型
收费全文 | 2720篇 |
免费 | 68篇 |
国内免费 | 20篇 |
专业分类
化学 | 1736篇 |
晶体学 | 90篇 |
力学 | 113篇 |
数学 | 330篇 |
物理学 | 539篇 |
出版年
2021年 | 14篇 |
2020年 | 29篇 |
2019年 | 26篇 |
2016年 | 44篇 |
2015年 | 41篇 |
2014年 | 32篇 |
2013年 | 120篇 |
2012年 | 112篇 |
2011年 | 168篇 |
2010年 | 79篇 |
2009年 | 84篇 |
2008年 | 123篇 |
2007年 | 141篇 |
2006年 | 127篇 |
2005年 | 141篇 |
2004年 | 110篇 |
2003年 | 82篇 |
2002年 | 96篇 |
2001年 | 40篇 |
2000年 | 44篇 |
1999年 | 39篇 |
1998年 | 31篇 |
1997年 | 36篇 |
1996年 | 37篇 |
1995年 | 26篇 |
1994年 | 30篇 |
1993年 | 28篇 |
1992年 | 38篇 |
1991年 | 41篇 |
1990年 | 50篇 |
1989年 | 33篇 |
1988年 | 35篇 |
1987年 | 35篇 |
1986年 | 34篇 |
1985年 | 48篇 |
1984年 | 45篇 |
1983年 | 39篇 |
1982年 | 33篇 |
1981年 | 39篇 |
1980年 | 31篇 |
1979年 | 36篇 |
1978年 | 37篇 |
1977年 | 30篇 |
1976年 | 36篇 |
1975年 | 40篇 |
1974年 | 22篇 |
1973年 | 40篇 |
1972年 | 22篇 |
1971年 | 14篇 |
1970年 | 21篇 |
排序方式: 共有2808条查询结果,搜索用时 156 毫秒
1.
Jerry Ray Dias 《Molecular physics》2020,118(12)
Cycloparaphenylene ([r]CPP) and cyclacene ([r]CA) series are models for short carbon nanotubes. It is shown that armchair edges in model cycloparaphenylenes possess greater aromaticity and cyclic conjugation than do zigzag edges in model cyclacenes. According to Aihara’s bond resonance energy (BRE) and Bosanac and Gutman energy effect (ef) measurements, cycloparaphenylenes are twice as aromatic as cyclacenes. The general solution of all eigenvalues of all members of the cycloparaphenylene series is given. The origin of the recurrence of some eigenvalues are determined. 相似文献
2.
A comprehensive study of the excited electronic states of HCl is reported. Using resonance enhanced multiphoton ionization ((2 + 1) REMPI) and time-of-flight mass spectrometry (TOFMS) over 120 band systems are analyzed. Supersonic jet techniques are used to prepare rotationally cold species for laser spectroscopy in the 77 000 to 96 000 cm−1 region. At least 50 new electronic states are characterized as well as several features only tentatively assigned previously. A long vibrational progression consisting of 29 vibrational levels of the deeply bound V1Σ+(0+) valence/ion-pair state is studied. We also extend the identification and analysis to high vibrational levels of low-lying Rydberg states. The assignments of [2Πi] Rydberg state complexes are evaluated in terms of spin-orbit coupling and united-atom calculations. In several band systems, the spectra exhibit anomalous rotational line intensities and broadened linewidths which are consistent with predissociation. Multiphoton ionization with mass spectrometry permits the investigation of isotope effects as well as the appearance of fragment species associated with repulsive potential curves. 相似文献
3.
4.
Zeolite A rods by self-assembly of zeolite A microcrystal were successfully synthesized by microwave-assisted hydrotherrnal synthesis. The average size of zeolite crystals consisting of self-assembling materials was about 300 nm and the length of zeolite rods was in the range of 15--30μm. 相似文献
5.
Jerry P. Suits 《School science and mathematics》2004,104(6):248-257
A laboratory practical examination was used to compare the investigative skills developed in two different types of general‐chemistry laboratory courses. Science and engineering majors (SEM) in the control group used a traditional verification approach (SEM‐Ctrl), whereas those in the treatment group learned from an innovative, inquiry‐based approach (SEM‐Trt). A scoring rubric was developed from their examination sheets to assess six component investigative skills. Results indicated that SEM students in the SEM‐Trt group scored significantly higher than those in SEM‐Ctrl for all six skills. Furthermore, nursing and applied science majors (NonSEM) in the inquiry‐based group (NonSEM‐Trt) wrote significantly better discussions than did SEM students in SEM‐Ctrl group. Overall, competency at the mid‐range level of laboratory skills was attained by most SEM‐Trt students (72.5%) but by only 30.5% of SEM‐Ctrl and 28.6% of NonSEM‐Trt students. Apparently, during the semester students in the SEM‐Trt group were able to use the inquiry‐based method effectively to combine chemical tasks with writing tasks and postlaboratory discussions. One implication of this study for science instructors is that practical examinations can provide useful feedback regarding the quality of the laboratory experience. Another implication is that this study provides evidence for the use of the innovative inquiry‐based laboratory approach to support student learning of high‐level investigative skills. However, students' requisite background knowledge must match the level of these skills. 相似文献
6.
7.
The understanding of mesoscopic transport has now attained an ultimate simplicity. Indeed, orthodox quantum kinetics would seem to say little about mesoscopics that has not been revealed — nearly effortlessly — by more popular means. Such is far from the case, however. The fact that kinetic theory remains very much in charge is best appreciated through the physics of a quantum point contact. While discretization of its conductance is viewed as the exclusive result of coherent, single-electron-wave transmission, this does not begin to address the paramount feature of all metallic conduction: dissipation. A perfect quantum point contact still has finite resistance, so its ballistic carriers must dissipate the energy gained from the applied field. How do they manage that? The key is in standard many-body quantum theory, and its conservation principles. 相似文献
8.
A. G. Green S. Rideal Leonard P. Kinnicutt und John U. Nef 《Fresenius' Journal of Analytical Chemistry》1886,25(1):222-223
Ohne Zusammenfassung 相似文献
9.
Jerry Green 《International Journal of Game Theory》2005,33(2):159-180
This paper presents an axiomatic characterization of a family of solutions to two-player quasi-linear social choice problems. In these problems the players select a single action from a set available to them. They may also transfer money between themselves.The solutions form a one-parameter family, where the parameter is a non-negative number, t.The solutions can be interpreted as follows: Any efficient action can be selected. Based on this action, compute for each player a “best claim for compensation”. A claim for compensation is the difference between the value of an alternative action and the selected efficient action, minus a penalty proportional to the extent to which the alternative action is inefficient. The coefficient of proportionality of this penalty is t. The best claim for compensation for a player is the maximum of this computed claim over all possible alternative actions. The solution, at the parameter value t, is to implement the chosen efficient action and make a monetary transfer equal to the average of these two best claims. The characterization relies on three main axioms. The paper presents and justifies these axioms and compares them to related conditions used in other bargaining contexts. In Nash Bargaining Theory, the axioms analogous to these three are in conflict with each other. In contrast, in the quasi-linear social choice setting of this paper, all three conditions can be satisfied simultaneously.This work was supported by the Division of Research at the Harvard Business School. Thanks are due to the Cowles Foundation for Research in Economics at Yale University for its kind hospitality during the Spring of 2002. I have received helpful advice and comments from Youngsub Chun, Ehud Kalai, Herve Moulin, Al Roth, Ilya Segal, Adam Szeidl, Richard Zeckhauser, and other members of the Theory Seminars at Harvard, MIT, Princeton, Rice and Northwestern. 相似文献
10.
P.S. Ganas A.E.S. Green 《Journal of Quantitative Spectroscopy & Radiative Transfer》1981,25(3):265-275
An analytic atomic independent-particle-model is used to generate wave functions for the bound and ionization continuum states of O(I), O(II), O(III), O(IV), and O(V). These wave functions are used in conjunction with the Born approximation to generate continuum generalized oscillator strengths (GOS). From these GOS, we obtain secondary electron distributions, which we represent by smooth analytic functions. From the secondary electron distributions, we obtain electron impact ionization cross sections, which are compared to experiment. Finally, we compute the loss functions. 相似文献