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排序方式: 共有77条查询结果,搜索用时 32 毫秒
1.
De Riccardis F Di Filippo M Garrisi D Izzo I Mancin F Pasquato L Scrimin P Tecilla P 《Chemical communications (Cambridge, England)》2002,(24):3066-3067
The Na+ transporting properties of the first member of a new class of artificial ionophores, based on a C2-symmetric polyhydroxylated steroid dimer, are described. 相似文献
2.
We study theoretically mixed solutions of homopolymer and diblock copolymer chains. The solvent is a poor solvent for the homopolymers and a selective solvent for the copolymers. We find that the formation of copolymer micelles containing also the insoluble chains allows for an increased solubility of the homopolymers in the solution. In agreement with experiments, we find also that the solubilization power of the micelles, that is, the maximum amount of total homopolymer weight solubilized per unit weight of copolymers in solution, decreases strongly with the homopolymer index of polymerization. 相似文献
3.
The (17R,20S,22S,24S) C20-C29 segment of contignasterol has been stereoselectively prepared in 8 steps and 40% overall yield from (S)-carvone. Synthetic studies towards contignasterol's C/D ring functionalization/isomerization are also reported. 相似文献
4.
Dora Izzo 《Liquid crystals》2020,47(1):99-105
ABSTRACTWe use the Landau theory of phase transitions to describe the phase diagram of a liquid crystal displaying the isotropic (i), nematic (N), smectic-A and smectic-C phases. The order parameter of the smectic-C phase is defined as the projection of the director on the plane of the smectic layers, vanishing in the smectic-A phase. We present a detailed phase diagram that shows transition between any two of these phases, containing a triple point INA, a Lifshitz point NAC, a tricritical at the NA line, and a critical end point IAC. As one approaches the NC line from the smectic-C phase, the tilt angle approaches a nonzero value, but if the AC line is approached, the tilt angle vanishes according to the distance to the AC line to the power 1/2. 相似文献
5.
The enantioselective synthesis of 3(S)-hydroxy polygodial and its acetyl derivative is described. The construction of the 3-hydroxy drimane skeleton was based on the titanium-catalyzed radical cyclization of (10S)-10, 11-epoxy-farnesyl acetate. Only underivatized 3(S)-hydroxy polygodial showed activity in assays on VR1 vanilloid receptor in HEK cells transfected with the human VR1. 相似文献
6.
D. Izzo V. M. Becerra D. R. Myatt S. J. Nasuto J. M. Bishop 《Journal of Global Optimization》2007,38(2):283-296
We introduce and describe the Multiple Gravity Assist problem, a global optimisation problem that is of great interest in
the design of spacecraft and their trajectories. We discuss its formalization and we show, in one particular problem instance,
the performance of selected state of the art heuristic global optimisation algorithms. A deterministic search space pruning
algorithm is then developed and its polynomial time and space complexity derived. The algorithm is shown to achieve search
space reductions of greater than six orders of magnitude, thus reducing significantly the complexity of the subsequent optimisation.
This work was partially funded under the Ariadna scheme of the European Space Agency, contract number 18138/04/NL/MV. 相似文献
7.
Alexander J. Izzo 《Proceedings of the American Mathematical Society》2007,135(4):1065-1071
Let denote the open unit disc, and let denote the disc algebra. The subsets of such that the inclusion holds for every nonconstant continuous on , or the inclusion holds for every bounded harmonic nonholomorphic function on continuous on , are characterized. In the first case the condition is that has positive measure, and in the second case that has full measure in .
8.
Let E be a subset of the boundary of the open unit disc D, andlet A be the algebra of bounded holomorphic functions on D thatextend continuously to D E. It is shown that if f is a boundedharmonic function on D that extends continuously to D E andis not holomorphic, then the uniformly closed algebra A[f] generatedby A and f contains . This result contains as special cases a result on the disc algebradue to irka and a result on H(D due to Axler and Shields. Astronger form of the result, in which f is allowed to have discontinuitieson a small subset of E, is also established. 2000 MathematicsSubject Classification 46J10, 46J15, 30H05. 相似文献
9.
Marina Sicignano Dr. Rosaria Schettini Luisa Sica Giovanni Pierri Prof. Dr. Francesco De Riccardis Prof. Dr. Irene Izzo Dr. Bholanath Maity Dr. Yury Minenkov Prof. Dr. Luigi Cavallo Dr. Giorgio Della Sala 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(29):7131-7141
The first highly enantioselective arylogous Michael reaction (AMR) of 3-unsubstituted phthalides has been described. This phase-transfer methodology, which uses catalytic amounts of KOH/18-crown-6 catalyst in mesitylene in the presence of N,O-bis(trimethylsilyl)acetamide (BSA), gives access to a broad range of 3-monosubstituted phthalides with high levels of syn diastereoselectivity and good yields, starting from 3-unsubstituted derivatives and diverse α,β-unsaturated carbonyl compounds. The reaction also applies to unactivated 3-alkyl phthalides to afford 3,3-dialkyl derivatives. A plausible mechanism has been suggested. DFT analysis of possible transition states gives a rationale of the high syn diastereoselectivity observed and its correlation with the solvent's dielectric constant. 相似文献
10.
Prof. Francesca Caterina Izzo Matilde Kratter Dr. Austin Nevin Prof. Elisabetta Zendri 《ChemistryOpen》2021,10(9):904-921
Up to 70 % of the oil paintings conserved in collections present metal soaps, which result from the chemical reaction between metal ions present in the painted layers and free fatty acids from the lipidic binders. In recent decades, conservators and conservation scientists have been systematically identifying various and frequent conservation problems that can be linked to the formation of metal soaps. It is also increasingly recognized that metal soap formation may not compromise the integrity of paint so there is a need for careful assessment of the implications of metal soaps for conservation. This review aims to critically assess scientific literature related to commonly adopted analytical techniques for the analysis of metal soaps in oil paintings. A comparison of different analytical methods is provided, highlighting advantages associated with each, as well as limitations identified through the analysis of reference materials and applications to the analysis of samples from historical paintings. 相似文献